#------------------------------------------------------------------------------ #$Date: 2016-02-21 00:03:34 +0000 (Sun, 21 Feb 2016) $ #$Revision: 176798 $ #$URL: svn://www.crystallography.net/cod/cif/2/23/88/2238838.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2238838 loop_ _publ_author_name 'Wink, Christoph' 'Schollmeyer, Dieter' 'Detert, Heiner' _publ_section_title ; (E)-N,N-Diethyl-2,6-diisopropyl-4-[2-(4-nitrophenyl)ethenyl]aniline ; _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1785 _journal_page_last o1786 _journal_paper_doi 10.1107/S1600536813030948 _journal_volume 69 _journal_year 2013 _chemical_formula_iupac 'C24 H32 N2 O2' _chemical_formula_moiety 'C24 H32 N2 O2' _chemical_formula_sum 'C24 H32 N2 O2' _chemical_formula_weight 380.52 _chemical_melting_point 408 _chemical_name_systematic (E)-N,N-Diethyl-2,6-diisopropyl-4-[2-(4-nitrophenyl)ethenyl]aniline _space_group_IT_number 2 _symmetry_cell_setting triclinic _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _audit_creation_method SHELXL-97 _cell_angle_alpha 104.642(8) _cell_angle_beta 92.414(8) _cell_angle_gamma 90.793(7) _cell_formula_units_Z 4 _cell_length_a 7.3477(7) _cell_length_b 15.4143(14) _cell_length_c 20.3747(19) _cell_measurement_reflns_used 12450 _cell_measurement_temperature 193(2) _cell_measurement_theta_max 27.5 _cell_measurement_theta_min 2.6 _cell_volume 2230.0(4) _computing_cell_refinement 'X-AREA (Stoe & Cie, 2011)' _computing_data_collection 'X-AREA (Stoe & Cie, 2011)' _computing_data_reduction 'X-RED (Stoe & Cie, 2011)' _computing_molecular_graphics 'PLATON (Spek, 2009)' _computing_publication_material 'PLATON (Spek, 2009)' _computing_structure_refinement 'SHELXL97 (Sheldrick, 2008)' _computing_structure_solution 'SIR97 (Altomare et al., 1999)' _diffrn_ambient_temperature 193(2) _diffrn_detector_area_resol_mean 6.67 _diffrn_measured_fraction_theta_full 0.987 _diffrn_measured_fraction_theta_max 0.987 _diffrn_measurement_device '2-circle goniometer' _diffrn_measurement_device_type 'Stoe IPDS 2T' _diffrn_measurement_method 'rotation method' _diffrn_radiation_monochromator 'plane graphite' _diffrn_radiation_source 'sealed X-ray tube, 12 x 0.4 mm long-fine focus' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0855 _diffrn_reflns_limit_h_max 9 _diffrn_reflns_limit_h_min -9 _diffrn_reflns_limit_k_max 19 _diffrn_reflns_limit_k_min -20 _diffrn_reflns_limit_l_max 26 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_number 21656 _diffrn_reflns_theta_full 28.00 _diffrn_reflns_theta_max 28.00 _diffrn_reflns_theta_min 2.66 _exptl_absorpt_coefficient_mu 0.072 _exptl_absorpt_correction_type none _exptl_crystal_colour yellow _exptl_crystal_density_diffrn 1.133 _exptl_crystal_density_method 'not measured' _exptl_crystal_description needle _exptl_crystal_F_000 824 _exptl_crystal_size_max 0.60 _exptl_crystal_size_mid 0.10 _exptl_crystal_size_min 0.05 _refine_diff_density_max 0.245 _refine_diff_density_min -0.240 _refine_ls_extinction_coef 0.0087(11) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_extinction_method 'SHELXL97 (Sheldrick, 2008)' _refine_ls_goodness_of_fit_ref 0.790 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 518 _refine_ls_number_reflns 10640 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 0.790 _refine_ls_R_factor_all 0.1559 _refine_ls_R_factor_gt 0.0567 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0886P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_obs 0.1328 _refine_ls_wR_factor_ref 0.1739 _reflns_number_gt 3887 _reflns_number_total 10640 _reflns_threshold_expression I>2\s(I) _iucr_refine_instructions_details ; TITL cw190 in P -1 CELL 0.71073 7.3477 15.4143 20.3747 104.642 92.414 90.793 ZERR 4.00 0.0007 0.0014 0.0019 0.008 0.008 0.007 REM Gitterkonstanten aus 12450 Reflexen mit 2.6-27.5 Grad V=2230.0(4) REM Gelbe Nadel Rint=0.087 LATT 1 SFAC C H N O UNIT 96 128 8 8 FMAP 2 PLAN -20 .5 -.5 L.S. 4 TEMP -80.00 ACTA CONF BOND $H SIZE 0.05 0.1 0.6 WGHT 0.088600 EXTI 0.008699 FVAR 0.38380 C1 1 0.494892 0.303480 0.278774 11.00000 0.03635 0.04488 = 0.04054 0.01608 0.00363 -0.00095 0.00033 0.00017 0.00012 0.00133 0.00146 0.00134 0.00115 0.00108 0.00110 C2 1 0.594781 0.266566 0.221483 11.00000 0.04238 0.03914 = 0.04760 0.01500 0.00647 0.00476 0.00035 0.00017 0.00013 0.00144 0.00139 0.00147 0.00117 0.00118 0.00112 AFIX 43 H2 2 0.633894 0.206509 0.213992 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C3 1 0.637751 0.315790 0.175506 11.00000 0.03994 0.04280 = 0.04231 0.01398 0.00374 0.00193 0.00035 0.00017 0.00013 0.00138 0.00146 0.00139 0.00116 0.00111 0.00112 C4 1 0.580079 0.404089 0.185894 11.00000 0.03724 0.04479 = 0.03997 0.01738 0.00373 -0.00215 0.00034 0.00017 0.00012 0.00134 0.00145 0.00133 0.00113 0.00107 0.00109 C5 1 0.483183 0.444219 0.244379 11.00000 0.03952 0.04314 = 0.04186 0.01252 0.00131 0.00145 0.00035 0.00017 0.00013 0.00138 0.00144 0.00137 0.00115 0.00112 0.00111 C6 1 0.443064 0.391985 0.288558 11.00000 0.04210 0.04376 = 0.04231 0.01347 0.00395 0.00169 0.00036 0.00017 0.00013 0.00143 0.00148 0.00139 0.00117 0.00115 0.00113 AFIX 43 H6 2 0.376848 0.418085 0.327425 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C7 1 0.442248 0.253627 0.327326 11.00000 0.04101 0.04807 = 0.04249 0.01637 0.00514 0.00145 0.00035 0.00018 0.00013 0.00142 0.00157 0.00140 0.00118 0.00114 0.00115 AFIX 43 H7 2 0.380980 0.285949 0.365751 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C8 1 0.471408 0.167275 0.323245 11.00000 0.03863 0.05220 = 0.04010 0.01595 0.00599 -0.00068 0.00035 0.00018 0.00013 0.00139 0.00165 0.00135 0.00118 0.00110 0.00118 AFIX 43 H8 2 0.536618 0.135556 0.285684 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C9 1 0.413304 0.116343 0.370662 11.00000 0.03389 0.04784 = 0.04276 0.01786 0.00352 0.00046 0.00033 0.00017 0.00013 0.00131 0.00153 0.00137 0.00117 0.00109 0.00110 C10 1 0.331823 0.156211 0.431648 11.00000 0.05581 0.05044 = 0.04736 0.01856 0.00765 0.00624 0.00039 0.00019 0.00014 0.00172 0.00165 0.00155 0.00132 0.00132 0.00134 AFIX 43 H10 2 0.317211 0.219312 0.444294 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C11 1 0.272511 0.104856 0.473586 11.00000 0.05731 0.06755 = 0.04704 0.02340 0.01057 0.00480 0.00042 0.00021 0.00015 0.00183 0.00205 0.00158 0.00148 0.00137 0.00150 AFIX 43 H11 2 0.217377 0.132179 0.514843 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C12 1 0.294548 0.013615 0.454665 11.00000 0.04050 0.06435 = 0.04691 0.03134 0.00231 -0.00222 0.00036 0.00020 0.00014 0.00146 0.00188 0.00151 0.00139 0.00120 0.00129 C13 1 0.375883 -0.028479 0.395305 11.00000 0.05042 0.05248 = 0.05648 0.02377 0.00574 0.00220 0.00039 0.00020 0.00015 0.00166 0.00167 0.00172 0.00140 0.00138 0.00132 AFIX 43 H13 2 0.391289 -0.091532 0.383191 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C14 1 0.433842 0.024333 0.354312 11.00000 0.04723 0.04929 = 0.05044 0.02224 0.00904 0.00684 0.00037 0.00018 0.00014 0.00156 0.00163 0.00155 0.00130 0.00126 0.00125 AFIX 43 H14 2 0.489895 -0.003493 0.313367 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C15 1 0.751932 0.273536 0.115548 11.00000 0.05165 0.04742 = 0.04595 0.01813 0.01358 0.00186 0.00038 0.00018 0.00013 0.00162 0.00158 0.00148 0.00125 0.00125 0.00126 AFIX 13 H15 2 0.740506 0.311398 0.082390 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C16 1 0.952007 0.275441 0.138548 11.00000 0.05112 0.07732 = 0.06550 0.01845 0.01656 0.01103 0.00041 0.00023 0.00017 0.00182 0.00224 0.00195 0.00167 0.00152 0.00159 AFIX 137 H16A 2 0.990740 0.337060 0.161702 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H16B 2 1.025450 0.253576 0.098936 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H16C 2 0.968684 0.236912 0.169820 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C17 1 0.688100 0.178940 0.078591 11.00000 0.08798 0.06174 = 0.06310 -0.00167 0.02765 -0.01434 0.00052 0.00022 0.00017 0.00254 0.00208 0.00201 0.00163 0.00186 0.00181 AFIX 137 H17A 2 0.705834 0.139066 0.108804 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H17B 2 0.758732 0.157735 0.038127 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H17C 2 0.558570 0.179016 0.065011 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 N18 3 0.618613 0.451264 0.135538 11.00000 0.04537 0.04518 = 0.04557 0.02330 0.00126 -0.00525 0.00030 0.00014 0.00011 0.00125 0.00123 0.00119 0.00100 0.00099 0.00098 C19 1 0.464416 0.468562 0.093644 11.00000 0.05853 0.06058 = 0.04925 0.02508 -0.00206 0.00006 0.00041 0.00020 0.00015 0.00180 0.00183 0.00157 0.00140 0.00137 0.00145 AFIX 23 H19A 2 0.509845 0.496432 0.058508 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 H19B 2 0.383815 0.511743 0.122404 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C20 1 0.354961 0.384165 0.059324 11.00000 0.05384 0.07574 = 0.05777 0.01634 -0.00318 -0.00474 0.00043 0.00022 0.00016 0.00181 0.00220 0.00180 0.00161 0.00147 0.00159 AFIX 137 H20A 2 0.433533 0.341534 0.030149 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H20B 2 0.253618 0.399221 0.031710 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H20C 2 0.306878 0.357106 0.093897 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C21 1 0.760704 0.521528 0.152352 11.00000 0.04964 0.05095 = 0.06351 0.02368 0.00205 -0.00658 0.00039 0.00020 0.00015 0.00164 0.00166 0.00179 0.00141 0.00139 0.00130 AFIX 23 H21A 2 0.829885 0.517568 0.194210 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 H21B 2 0.703508 0.580904 0.161430 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C22 1 0.891363 0.513514 0.095147 11.00000 0.06677 0.07325 = 0.08264 0.03562 0.02067 -0.00507 0.00047 0.00024 0.00018 0.00215 0.00224 0.00232 0.00187 0.00184 0.00174 AFIX 137 H22A 2 0.948131 0.454768 0.086004 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H22B 2 0.985987 0.560893 0.108537 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H22C 2 0.824035 0.519727 0.054097 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C23 1 0.422590 0.540563 0.260725 11.00000 0.05041 0.04745 = 0.05094 0.01784 0.00738 0.00285 0.00038 0.00018 0.00014 0.00161 0.00159 0.00155 0.00128 0.00128 0.00127 AFIX 13 H23 2 0.463457 0.567680 0.223953 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C24 1 0.215633 0.544832 0.261185 11.00000 0.06109 0.06064 = 0.10622 0.03207 0.02030 0.01915 0.00045 0.00023 0.00021 0.00206 0.00206 0.00278 0.00195 0.00194 0.00165 AFIX 137 H24A 2 0.172300 0.521687 0.298482 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H24B 2 0.162411 0.508368 0.217917 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H24C 2 0.179045 0.607187 0.267454 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C25 1 0.510641 0.595375 0.327794 11.00000 0.10304 0.04730 = 0.06010 0.01153 0.00058 -0.00324 0.00055 0.00021 0.00016 0.00278 0.00179 0.00193 0.00150 0.00188 0.00177 AFIX 137 H25A 2 0.477339 0.568537 0.364529 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H25B 2 0.467750 0.657022 0.337133 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H25C 2 0.643407 0.595785 0.324810 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 N26 3 0.230019 -0.041346 0.498183 11.00000 0.04785 0.08062 = 0.06550 0.04302 -0.00171 -0.00726 0.00035 0.00021 0.00015 0.00145 0.00206 0.00172 0.00157 0.00128 0.00135 O27 4 0.246464 -0.122630 0.480174 11.00000 0.09483 0.07460 = 0.08942 0.05043 0.01339 -0.00719 0.00037 0.00018 0.00013 0.00188 0.00171 0.00177 0.00145 0.00146 0.00141 O28 4 0.160434 -0.003037 0.551676 11.00000 0.07323 0.10967 = 0.05937 0.04378 0.01476 -0.00384 0.00033 0.00018 0.00012 0.00158 0.00195 0.00139 0.00138 0.00123 0.00139 C30 1 -0.008351 0.051715 0.277937 11.00000 0.03781 0.04341 = 0.04265 0.01327 0.00013 -0.00037 0.00034 0.00017 0.00013 0.00137 0.00147 0.00138 0.00116 0.00112 0.00111 C31 1 -0.065914 -0.030381 0.286693 11.00000 0.04179 0.04560 = 0.04618 0.01664 0.00756 0.00196 0.00035 0.00017 0.00013 0.00144 0.00153 0.00146 0.00123 0.00118 0.00116 AFIX 43 H31 2 -0.133617 -0.031190 0.325250 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C32 1 -0.029276 -0.111581 0.241733 11.00000 0.03872 0.04161 = 0.04670 0.01722 0.00515 0.00057 0.00034 0.00017 0.00013 0.00138 0.00145 0.00145 0.00119 0.00114 0.00111 C33 1 0.069407 -0.110003 0.184112 11.00000 0.03900 0.03738 = 0.04193 0.00966 0.00423 0.00119 0.00034 0.00016 0.00013 0.00135 0.00138 0.00136 0.00111 0.00110 0.00107 C34 1 0.134587 -0.028280 0.174704 11.00000 0.03731 0.04233 = 0.04104 0.01189 0.00210 0.00087 0.00034 0.00017 0.00013 0.00135 0.00146 0.00136 0.00115 0.00109 0.00110 C35 1 0.095495 0.051264 0.221426 11.00000 0.04047 0.04165 = 0.04680 0.01623 0.00315 -0.00147 0.00035 0.00017 0.00013 0.00139 0.00146 0.00146 0.00119 0.00116 0.00112 AFIX 43 H35 2 0.139965 0.106562 0.215018 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C36 1 -0.057521 0.133481 0.326843 11.00000 0.04150 0.04636 = 0.04278 0.01171 0.00477 0.00236 0.00035 0.00018 0.00013 0.00143 0.00156 0.00141 0.00119 0.00115 0.00116 AFIX 43 H36 2 -0.117175 0.126068 0.365610 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C37 1 -0.028026 0.217466 0.323169 11.00000 0.03940 0.04770 = 0.04215 0.01133 0.00266 0.00382 0.00035 0.00018 0.00013 0.00143 0.00158 0.00139 0.00117 0.00114 0.00116 AFIX 43 H37 2 0.036719 0.224936 0.285501 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C38 1 -0.084360 0.299591 0.370775 11.00000 0.03533 0.04694 = 0.04268 0.01045 -0.00066 0.00050 0.00034 0.00018 0.00013 0.00133 0.00151 0.00139 0.00117 0.00110 0.00112 C39 1 -0.060591 0.381219 0.354841 11.00000 0.04832 0.04090 = 0.04843 0.00788 0.00571 0.00303 0.00038 0.00017 0.00014 0.00157 0.00151 0.00152 0.00125 0.00125 0.00121 AFIX 43 H39 2 -0.002568 0.382576 0.314304 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C40 1 -0.118502 0.460491 0.395969 11.00000 0.05073 0.04497 = 0.05425 0.00739 0.00405 0.00049 0.00038 0.00019 0.00014 0.00168 0.00160 0.00170 0.00132 0.00137 0.00129 AFIX 43 H40 2 -0.100820 0.515827 0.384329 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C41 1 -0.203111 0.456999 0.454682 11.00000 0.04433 0.04658 = 0.04385 -0.00230 0.00159 0.00548 0.00037 0.00018 0.00014 0.00152 0.00161 0.00149 0.00124 0.00121 0.00123 C42 1 -0.228163 0.377869 0.472869 11.00000 0.05976 0.06050 = 0.04410 0.00362 0.01048 0.00284 0.00042 0.00021 0.00015 0.00188 0.00194 0.00155 0.00141 0.00138 0.00149 AFIX 43 H42 2 -0.285623 0.377432 0.513693 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C43 1 -0.169185 0.298905 0.431356 11.00000 0.05875 0.04921 = 0.04611 0.01194 0.00755 -0.00321 0.00040 0.00019 0.00014 0.00178 0.00167 0.00155 0.00132 0.00135 0.00135 AFIX 43 H43 2 -0.185911 0.243995 0.443721 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C44 1 -0.098103 -0.197925 0.256701 11.00000 0.04961 0.04401 = 0.05799 0.01821 0.00951 -0.00037 0.00038 0.00018 0.00015 0.00161 0.00156 0.00168 0.00131 0.00134 0.00123 AFIX 13 H44 2 -0.061380 -0.249112 0.219100 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C45 1 -0.305038 -0.200775 0.257782 11.00000 0.05552 0.06280 = 0.11087 0.03392 0.01987 -0.00696 0.00044 0.00023 0.00021 0.00194 0.00210 0.00288 0.00201 0.00192 0.00157 AFIX 137 H45A 2 -0.346410 -0.259600 0.262329 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H45B 2 -0.357433 -0.190627 0.215397 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H45C 2 -0.344536 -0.153932 0.296317 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C46 1 -0.011740 -0.210519 0.322642 11.00000 0.10103 0.05865 = 0.06687 0.02892 0.00074 0.00397 0.00055 0.00023 0.00017 0.00283 0.00201 0.00210 0.00169 0.00195 0.00189 AFIX 137 H46A 2 -0.039886 -0.159431 0.360145 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H46B 2 0.120644 -0.214317 0.319040 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H46C 2 -0.060277 -0.265932 0.331268 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 N47 3 0.106149 -0.190364 0.132957 11.00000 0.04404 0.03697 = 0.04494 0.00756 -0.00090 0.00118 0.00029 0.00014 0.00011 0.00124 0.00116 0.00118 0.00095 0.00098 0.00094 C48 1 0.239374 -0.250166 0.150941 11.00000 0.04716 0.04622 = 0.05688 0.01656 0.00364 0.00524 0.00038 0.00019 0.00015 0.00157 0.00155 0.00165 0.00130 0.00131 0.00125 AFIX 23 H48A 2 0.175071 -0.300697 0.162651 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 H48B 2 0.313400 -0.217318 0.191573 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C49 1 0.363884 -0.286763 0.093835 11.00000 0.06727 0.06098 = 0.07881 0.01893 0.01829 0.01914 0.00047 0.00022 0.00018 0.00212 0.00202 0.00222 0.00171 0.00177 0.00165 AFIX 137 H49A 2 0.293701 -0.326602 0.055807 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H49B 2 0.460895 -0.320434 0.109862 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H49C 2 0.417848 -0.237001 0.078783 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C50 1 -0.048690 -0.233748 0.089141 11.00000 0.05361 0.04869 = 0.05350 0.00602 -0.00258 -0.00613 0.00041 0.00019 0.00015 0.00171 0.00164 0.00162 0.00132 0.00135 0.00133 AFIX 23 H50A 2 -0.134125 -0.258568 0.116438 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 H50B 2 -0.004816 -0.284358 0.053501 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C51 1 -0.148751 -0.170437 0.055930 11.00000 0.05248 0.06374 = 0.06142 0.01325 -0.00794 0.00124 0.00042 0.00021 0.00016 0.00179 0.00196 0.00184 0.00154 0.00147 0.00148 AFIX 137 H51A 2 -0.194690 -0.120797 0.090971 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H51B 2 -0.251196 -0.202564 0.027206 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H51C 2 -0.065560 -0.146701 0.027976 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C52 1 0.252334 -0.025848 0.115951 11.00000 0.05133 0.04139 = 0.04489 0.01224 0.01197 0.00124 0.00037 0.00018 0.00013 0.00160 0.00146 0.00143 0.00117 0.00123 0.00120 AFIX 13 H52 2 0.233703 -0.084770 0.081633 11.00000 -1.20000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C53 1 0.452029 -0.017357 0.138217 11.00000 0.05182 0.07783 = 0.06981 0.02812 0.01841 0.00600 0.00042 0.00023 0.00017 0.00180 0.00224 0.00203 0.00173 0.00156 0.00159 AFIX 137 H53A 2 0.475829 0.040128 0.171657 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H53B 2 0.525616 -0.020161 0.098754 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H53C 2 0.484121 -0.066533 0.158678 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 C54 1 0.202100 0.046958 0.080462 11.00000 0.07436 0.07894 = 0.06077 0.03641 0.01690 0.01231 0.00049 0.00023 0.00017 0.00223 0.00227 0.00189 0.00173 0.00168 0.00181 AFIX 137 H54A 2 0.072450 0.040702 0.066287 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H54B 2 0.275113 0.041004 0.040474 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 H54C 2 0.226399 0.106034 0.111779 11.00000 -1.50000 0.00000 0.00000 0.00000 0.00000 AFIX 0 N55 3 -0.266688 0.540272 0.498260 11.00000 0.05096 0.06006 = 0.05584 -0.00257 -0.00564 0.00556 0.00035 0.00019 0.00014 0.00152 0.00177 0.00157 0.00133 0.00124 0.00128 O56 4 -0.340250 0.536225 0.551034 11.00000 0.07496 0.08486 = 0.05444 -0.01050 0.01460 0.00906 0.00033 0.00016 0.00012 0.00159 0.00170 0.00133 0.00118 0.00121 0.00129 O57 4 -0.247693 0.609864 0.481125 11.00000 0.09205 0.05229 = 0.08346 -0.00135 0.01129 0.01456 0.00036 0.00016 0.00013 0.00184 0.00142 0.00170 0.00126 0.00141 0.00129 HKLF 4 ; _cod_data_source_file bt6943.cif _cod_data_source_block I _cod_database_code 2238838 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_refinement_flags _atom_site_occupancy _atom_site_symmetry_multiplicity C C1 0.4949(3) 0.30348(17) 0.27877(12) 0.0396(6) Uani d . 1 1 C C2 0.5948(4) 0.26657(17) 0.22148(13) 0.0422(6) Uani d . 1 1 H H2 0.6339 0.2065 0.2140 0.051 Uiso calc R 1 1 C C3 0.6378(3) 0.31579(17) 0.17551(13) 0.0410(6) Uani d . 1 1 C C4 0.5801(3) 0.40409(17) 0.18589(12) 0.0394(6) Uani d . 1 1 C C5 0.4832(3) 0.44422(17) 0.24438(13) 0.0412(6) Uani d . 1 1 C C6 0.4431(4) 0.39198(17) 0.28856(13) 0.0422(6) Uani d . 1 1 H H6 0.3768 0.4181 0.3274 0.051 Uiso calc R 1 1 C C7 0.4422(4) 0.25363(18) 0.32733(13) 0.0429(6) Uani d . 1 1 H H7 0.3810 0.2859 0.3658 0.051 Uiso calc R 1 1 C C8 0.4714(3) 0.16727(18) 0.32324(13) 0.0428(6) Uani d . 1 1 H H8 0.5366 0.1356 0.2857 0.051 Uiso calc R 1 1 C C9 0.4133(3) 0.11634(17) 0.37066(13) 0.0403(6) Uani d . 1 1 C C10 0.3318(4) 0.15621(19) 0.43165(14) 0.0499(7) Uani d . 1 1 H H10 0.3172 0.2193 0.4443 0.060 Uiso calc R 1 1 C C11 0.2725(4) 0.1049(2) 0.47359(15) 0.0554(7) Uani d . 1 1 H H11 0.2174 0.1322 0.5148 0.067 Uiso calc R 1 1 C C12 0.2945(4) 0.0136(2) 0.45466(14) 0.0475(7) Uani d . 1 1 C C13 0.3759(4) -0.0285(2) 0.39530(15) 0.0512(7) Uani d . 1 1 H H13 0.3913 -0.0915 0.3832 0.061 Uiso calc R 1 1 C C14 0.4338(4) 0.02433(18) 0.35431(14) 0.0470(7) Uani d . 1 1 H H14 0.4899 -0.0035 0.3134 0.056 Uiso calc R 1 1 C C15 0.7519(4) 0.27354(18) 0.11555(13) 0.0469(6) Uani d . 1 1 H H15 0.7405 0.3114 0.0824 0.056 Uiso calc R 1 1 C C16 0.9520(4) 0.2754(2) 0.13855(17) 0.0641(8) Uani d . 1 1 H H16A 0.9907 0.3371 0.1617 0.096 Uiso calc R 1 1 H H16B 1.0255 0.2536 0.0989 0.096 Uiso calc R 1 1 H H16C 0.9687 0.2369 0.1698 0.096 Uiso calc R 1 1 C C17 0.6881(5) 0.1789(2) 0.07859(17) 0.0735(10) Uani d . 1 1 H H17A 0.7058 0.1391 0.1088 0.110 Uiso calc R 1 1 H H17B 0.7587 0.1577 0.0381 0.110 Uiso calc R 1 1 H H17C 0.5586 0.1790 0.0650 0.110 Uiso calc R 1 1 N N18 0.6186(3) 0.45126(14) 0.13554(11) 0.0433(5) Uani d . 1 1 C C19 0.4644(4) 0.4686(2) 0.09364(15) 0.0543(7) Uani d . 1 1 H H19A 0.5098 0.4964 0.0585 0.065 Uiso calc R 1 1 H H19B 0.3838 0.5117 0.1224 0.065 Uiso calc R 1 1 C C20 0.3550(4) 0.3842(2) 0.05932(16) 0.0628(8) Uani d . 1 1 H H20A 0.4335 0.3415 0.0301 0.094 Uiso calc R 1 1 H H20B 0.2536 0.3992 0.0317 0.094 Uiso calc R 1 1 H H20C 0.3069 0.3571 0.0939 0.094 Uiso calc R 1 1 C C21 0.7607(4) 0.5215(2) 0.15235(15) 0.0531(7) Uani d . 1 1 H H21A 0.8299 0.5176 0.1942 0.064 Uiso calc R 1 1 H H21B 0.7035 0.5809 0.1614 0.064 Uiso calc R 1 1 C C22 0.8914(5) 0.5135(2) 0.09515(18) 0.0709(9) Uani d . 1 1 H H22A 0.9481 0.4548 0.0860 0.106 Uiso calc R 1 1 H H22B 0.9860 0.5609 0.1085 0.106 Uiso calc R 1 1 H H22C 0.8240 0.5197 0.0541 0.106 Uiso calc R 1 1 C C23 0.4226(4) 0.54056(18) 0.26072(14) 0.0485(7) Uani d . 1 1 H H23 0.4635 0.5677 0.2240 0.058 Uiso calc R 1 1 C C24 0.2156(5) 0.5448(2) 0.2612(2) 0.0734(10) Uani d . 1 1 H H24A 0.1723 0.5217 0.2985 0.110 Uiso calc R 1 1 H H24B 0.1624 0.5084 0.2179 0.110 Uiso calc R 1 1 H H24C 0.1790 0.6072 0.2675 0.110 Uiso calc R 1 1 C C25 0.5106(5) 0.5954(2) 0.32779(16) 0.0707(9) Uani d . 1 1 H H25A 0.4773 0.5685 0.3645 0.106 Uiso calc R 1 1 H H25B 0.4678 0.6570 0.3371 0.106 Uiso calc R 1 1 H H25C 0.6434 0.5958 0.3248 0.106 Uiso calc R 1 1 N N26 0.2300(3) -0.0413(2) 0.49818(15) 0.0605(7) Uani d . 1 1 O O27 0.2465(4) -0.12263(18) 0.48017(13) 0.0808(7) Uani d . 1 1 O O28 0.1604(3) -0.00304(18) 0.55168(12) 0.0764(7) Uani d . 1 1 C C30 -0.0084(3) 0.05172(17) 0.27794(13) 0.0409(6) Uani d . 1 1 C C31 -0.0659(4) -0.03038(17) 0.28669(13) 0.0435(6) Uani d . 1 1 H H31 -0.1336 -0.0312 0.3253 0.052 Uiso calc R 1 1 C C32 -0.0293(3) -0.11158(17) 0.24173(13) 0.0412(6) Uani d . 1 1 C C33 0.0694(3) -0.11000(16) 0.18411(13) 0.0394(6) Uani d . 1 1 C C34 0.1346(3) -0.02828(17) 0.17470(13) 0.0400(6) Uani d . 1 1 C C35 0.0955(3) 0.05126(17) 0.22143(13) 0.0421(6) Uani d . 1 1 H H35 0.1400 0.1066 0.2150 0.050 Uiso calc R 1 1 C C36 -0.0575(4) 0.13348(18) 0.32684(13) 0.0434(6) Uani d . 1 1 H H36 -0.1172 0.1261 0.3656 0.052 Uiso calc R 1 1 C C37 -0.0280(3) 0.21747(18) 0.32317(13) 0.0430(6) Uani d . 1 1 H H37 0.0367 0.2249 0.2855 0.052 Uiso calc R 1 1 C C38 -0.0844(3) 0.29959(18) 0.37077(13) 0.0419(6) Uani d . 1 1 C C39 -0.0606(4) 0.38122(17) 0.35484(14) 0.0464(6) Uani d . 1 1 H H39 -0.0026 0.3826 0.3143 0.056 Uiso calc R 1 1 C C40 -0.1185(4) 0.46049(19) 0.39597(14) 0.0509(7) Uani d . 1 1 H H40 -0.1008 0.5158 0.3843 0.061 Uiso calc R 1 1 C C41 -0.2031(4) 0.45700(18) 0.45468(14) 0.0474(7) Uani d . 1 1 C C42 -0.2282(4) 0.3779(2) 0.47287(15) 0.0563(8) Uani d . 1 1 H H42 -0.2856 0.3774 0.5137 0.068 Uiso calc R 1 1 C C43 -0.1692(4) 0.29890(19) 0.43136(14) 0.0513(7) Uani d . 1 1 H H43 -0.1859 0.2440 0.4437 0.062 Uiso calc R 1 1 C C44 -0.0981(4) -0.19792(18) 0.25670(15) 0.0494(7) Uani d . 1 1 H H44 -0.0614 -0.2491 0.2191 0.059 Uiso calc R 1 1 C C45 -0.3050(4) -0.2008(2) 0.2578(2) 0.0739(10) Uani d . 1 1 H H45A -0.3464 -0.2596 0.2623 0.111 Uiso calc R 1 1 H H45B -0.3574 -0.1906 0.2154 0.111 Uiso calc R 1 1 H H45C -0.3445 -0.1539 0.2963 0.111 Uiso calc R 1 1 C C46 -0.0117(5) -0.2105(2) 0.32264(17) 0.0732(10) Uani d . 1 1 H H46A -0.0399 -0.1594 0.3601 0.110 Uiso calc R 1 1 H H46B 0.1206 -0.2143 0.3190 0.110 Uiso calc R 1 1 H H46C -0.0603 -0.2659 0.3313 0.110 Uiso calc R 1 1 N N47 0.1061(3) -0.19036(14) 0.13296(11) 0.0426(5) Uani d . 1 1 C C48 0.2394(4) -0.25017(19) 0.15094(15) 0.0494(7) Uani d . 1 1 H H48A 0.1751 -0.3007 0.1627 0.059 Uiso calc R 1 1 H H48B 0.3134 -0.2173 0.1916 0.059 Uiso calc R 1 1 C C49 0.3639(5) -0.2868(2) 0.09384(18) 0.0682(9) Uani d . 1 1 H H49A 0.2937 -0.3266 0.0558 0.102 Uiso calc R 1 1 H H49B 0.4609 -0.3204 0.1099 0.102 Uiso calc R 1 1 H H49C 0.4178 -0.2370 0.0788 0.102 Uiso calc R 1 1 C C50 -0.0487(4) -0.23375(19) 0.08914(15) 0.0534(7) Uani d . 1 1 H H50A -0.1341 -0.2586 0.1164 0.064 Uiso calc R 1 1 H H50B -0.0048 -0.2844 0.0535 0.064 Uiso calc R 1 1 C C51 -0.1488(4) -0.1704(2) 0.05593(16) 0.0600(8) Uani d . 1 1 H H51A -0.1947 -0.1208 0.0910 0.090 Uiso calc R 1 1 H H51B -0.2512 -0.2026 0.0272 0.090 Uiso calc R 1 1 H H51C -0.0656 -0.1467 0.0280 0.090 Uiso calc R 1 1 C C52 0.2523(4) -0.02585(18) 0.11595(13) 0.0454(6) Uani d . 1 1 H H52 0.2337 -0.0848 0.0816 0.054 Uiso calc R 1 1 C C53 0.4520(4) -0.0174(2) 0.13822(17) 0.0643(8) Uani d . 1 1 H H53A 0.4758 0.0401 0.1717 0.096 Uiso calc R 1 1 H H53B 0.5256 -0.0202 0.0988 0.096 Uiso calc R 1 1 H H53C 0.4841 -0.0665 0.1587 0.096 Uiso calc R 1 1 C C54 0.2021(5) 0.0470(2) 0.08046(17) 0.0675(9) Uani d . 1 1 H H54A 0.0725 0.0407 0.0663 0.101 Uiso calc R 1 1 H H54B 0.2751 0.0410 0.0405 0.101 Uiso calc R 1 1 H H54C 0.2264 0.1060 0.1118 0.101 Uiso calc R 1 1 N N55 -0.2667(4) 0.54027(19) 0.49826(14) 0.0589(7) Uani d . 1 1 O O56 -0.3403(3) 0.53623(16) 0.55103(12) 0.0761(7) Uani d . 1 1 O O57 -0.2477(4) 0.60986(16) 0.48113(13) 0.0790(7) Uani d . 1 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 C1 0.0364(13) 0.0449(15) 0.0405(13) -0.0010(11) 0.0036(11) 0.0161(11) C2 0.0424(14) 0.0391(14) 0.0476(15) 0.0048(11) 0.0065(12) 0.0150(12) C3 0.0399(14) 0.0428(15) 0.0423(14) 0.0019(11) 0.0037(11) 0.0140(12) C4 0.0372(13) 0.0448(14) 0.0400(13) -0.0021(11) 0.0037(11) 0.0174(11) C5 0.0395(14) 0.0431(14) 0.0419(14) 0.0014(11) 0.0013(11) 0.0125(11) C6 0.0421(14) 0.0438(15) 0.0423(14) 0.0017(11) 0.0039(11) 0.0135(12) C7 0.0410(14) 0.0481(16) 0.0425(14) 0.0015(11) 0.0051(11) 0.0164(12) C8 0.0386(14) 0.0522(17) 0.0401(13) -0.0007(12) 0.0060(11) 0.0160(12) C9 0.0339(13) 0.0478(15) 0.0428(14) 0.0005(11) 0.0035(11) 0.0179(12) C10 0.0558(17) 0.0504(16) 0.0474(16) 0.0062(13) 0.0077(13) 0.0186(13) C11 0.0573(18) 0.068(2) 0.0470(16) 0.0048(15) 0.0106(14) 0.0234(15) C12 0.0405(15) 0.0644(19) 0.0469(15) -0.0022(13) 0.0023(12) 0.0313(14) C13 0.0504(17) 0.0525(17) 0.0565(17) 0.0022(13) 0.0057(14) 0.0238(14) C14 0.0472(16) 0.0493(16) 0.0504(16) 0.0068(13) 0.0090(13) 0.0222(13) C15 0.0517(16) 0.0474(16) 0.0460(15) 0.0019(13) 0.0136(13) 0.0181(12) C16 0.0511(18) 0.077(2) 0.0655(19) 0.0110(16) 0.0166(15) 0.0184(17) C17 0.088(3) 0.062(2) 0.063(2) -0.0143(18) 0.0276(19) -0.0017(16) N18 0.0454(13) 0.0452(12) 0.0456(12) -0.0052(10) 0.0013(10) 0.0233(10) C19 0.0585(18) 0.0606(18) 0.0492(16) 0.0001(14) -0.0021(14) 0.0251(14) C20 0.0538(18) 0.076(2) 0.0578(18) -0.0047(16) -0.0032(15) 0.0163(16) C21 0.0496(16) 0.0509(17) 0.0635(18) -0.0066(13) 0.0020(14) 0.0237(14) C22 0.067(2) 0.073(2) 0.083(2) -0.0051(17) 0.0207(18) 0.0356(19) C23 0.0504(16) 0.0475(16) 0.0509(16) 0.0029(13) 0.0074(13) 0.0178(13) C24 0.061(2) 0.061(2) 0.106(3) 0.0192(17) 0.0203(19) 0.032(2) C25 0.103(3) 0.0473(18) 0.0601(19) -0.0032(18) 0.0006(19) 0.0115(15) N26 0.0478(15) 0.081(2) 0.0655(17) -0.0073(13) -0.0017(13) 0.0430(16) O27 0.0948(19) 0.0746(17) 0.0894(18) -0.0072(14) 0.0134(15) 0.0504(14) O28 0.0732(16) 0.110(2) 0.0594(14) -0.0038(14) 0.0148(12) 0.0438(14) C30 0.0378(14) 0.0434(15) 0.0426(14) -0.0004(11) 0.0001(11) 0.0133(12) C31 0.0418(14) 0.0456(15) 0.0462(15) 0.0020(12) 0.0076(12) 0.0166(12) C32 0.0387(14) 0.0416(15) 0.0467(14) 0.0006(11) 0.0051(11) 0.0172(12) C33 0.0390(14) 0.0374(14) 0.0419(14) 0.0012(11) 0.0042(11) 0.0097(11) C34 0.0373(14) 0.0423(15) 0.0410(14) 0.0009(11) 0.0021(11) 0.0119(11) C35 0.0405(14) 0.0417(15) 0.0468(15) -0.0015(11) 0.0031(12) 0.0162(12) C36 0.0415(14) 0.0464(16) 0.0428(14) 0.0024(12) 0.0048(11) 0.0117(12) C37 0.0394(14) 0.0477(16) 0.0422(14) 0.0038(12) 0.0027(11) 0.0113(12) C38 0.0353(13) 0.0469(15) 0.0427(14) 0.0005(11) -0.0007(11) 0.0105(12) C39 0.0483(16) 0.0409(15) 0.0484(15) 0.0030(12) 0.0057(13) 0.0079(12) C40 0.0507(17) 0.0450(16) 0.0543(17) 0.0005(13) 0.0041(14) 0.0074(13) C41 0.0443(15) 0.0466(16) 0.0439(15) 0.0055(12) 0.0016(12) -0.0023(12) C42 0.0598(19) 0.0605(19) 0.0441(16) 0.0028(15) 0.0105(14) 0.0036(14) C43 0.0587(18) 0.0492(17) 0.0461(15) -0.0032(14) 0.0076(13) 0.0119(13) C44 0.0496(16) 0.0440(16) 0.0580(17) -0.0004(12) 0.0095(13) 0.0182(13) C45 0.0555(19) 0.063(2) 0.111(3) -0.0070(16) 0.0199(19) 0.034(2) C46 0.101(3) 0.059(2) 0.067(2) 0.0040(19) 0.001(2) 0.0289(17) N47 0.0440(12) 0.0370(12) 0.0449(12) 0.0012(9) -0.0009(10) 0.0076(9) C48 0.0472(16) 0.0462(16) 0.0569(17) 0.0052(13) 0.0036(13) 0.0166(13) C49 0.067(2) 0.061(2) 0.079(2) 0.0191(17) 0.0183(18) 0.0189(17) C50 0.0536(17) 0.0487(16) 0.0535(16) -0.0061(13) -0.0026(13) 0.0060(13) C51 0.0525(18) 0.064(2) 0.0614(18) 0.0012(15) -0.0079(15) 0.0133(15) C52 0.0513(16) 0.0414(15) 0.0449(14) 0.0012(12) 0.0120(12) 0.0122(12) C53 0.0518(18) 0.078(2) 0.070(2) 0.0060(16) 0.0184(16) 0.0281(17) C54 0.074(2) 0.079(2) 0.0608(19) 0.0123(18) 0.0169(17) 0.0364(17) N55 0.0510(15) 0.0601(18) 0.0558(16) 0.0056(13) -0.0056(12) -0.0026(13) O56 0.0750(16) 0.0849(17) 0.0544(13) 0.0091(13) 0.0146(12) -0.0105(12) O57 0.0921(18) 0.0523(14) 0.0835(17) 0.0146(13) 0.0113(14) -0.0014(13) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C6 C1 C2 117.4(2) C6 C1 C7 119.1(2) C2 C1 C7 123.5(2) C3 C2 C1 121.6(2) C3 C2 H2 119.2 C1 C2 H2 119.2 C2 C3 C4 119.7(2) C2 C3 C15 119.4(2) C4 C3 C15 120.9(2) C3 C4 C5 120.1(2) C3 C4 N18 118.1(2) C5 C4 N18 121.8(2) C6 C5 C4 117.9(2) C6 C5 C23 118.8(2) C4 C5 C23 123.3(2) C5 C6 C1 123.3(2) C5 C6 H6 118.4 C1 C6 H6 118.4 C8 C7 C1 126.6(2) C8 C7 H7 116.7 C1 C7 H7 116.7 C7 C8 C9 126.7(2) C7 C8 H8 116.6 C9 C8 H8 116.6 C14 C9 C10 117.9(2) C14 C9 C8 119.2(2) C10 C9 C8 122.9(2) C11 C10 C9 120.8(3) C11 C10 H10 119.6 C9 C10 H10 119.6 C12 C11 C10 119.0(3) C12 C11 H11 120.5 C10 C11 H11 120.5 C11 C12 C13 122.2(2) C11 C12 N26 119.4(3) C13 C12 N26 118.5(3) C14 C13 C12 117.7(3) C14 C13 H13 121.2 C12 C13 H13 121.2 C13 C14 C9 122.4(3) C13 C14 H14 118.8 C9 C14 H14 118.8 C17 C15 C16 110.8(3) C17 C15 C3 113.3(2) C16 C15 C3 110.2(2) C17 C15 H15 107.4 C16 C15 H15 107.4 C3 C15 H15 107.4 C15 C16 H16A 109.5 C15 C16 H16B 109.5 H16A C16 H16B 109.5 C15 C16 H16C 109.5 H16A C16 H16C 109.5 H16B C16 H16C 109.5 C15 C17 H17A 109.5 C15 C17 H17B 109.5 H17A C17 H17B 109.5 C15 C17 H17C 109.5 H17A C17 H17C 109.5 H17B C17 H17C 109.5 C4 N18 C19 116.9(2) C4 N18 C21 117.8(2) C19 N18 C21 115.3(2) N18 C19 C20 112.6(2) N18 C19 H19A 109.1 C20 C19 H19A 109.1 N18 C19 H19B 109.1 C20 C19 H19B 109.1 H19A C19 H19B 107.8 C19 C20 H20A 109.5 C19 C20 H20B 109.5 H20A C20 H20B 109.5 C19 C20 H20C 109.5 H20A C20 H20C 109.5 H20B C20 H20C 109.5 N18 C21 C22 111.7(3) N18 C21 H21A 109.3 C22 C21 H21A 109.3 N18 C21 H21B 109.3 C22 C21 H21B 109.3 H21A C21 H21B 107.9 C21 C22 H22A 109.5 C21 C22 H22B 109.5 H22A C22 H22B 109.5 C21 C22 H22C 109.5 H22A C22 H22C 109.5 H22B C22 H22C 109.5 C5 C23 C24 110.9(2) C5 C23 C25 111.5(2) C24 C23 C25 111.1(3) C5 C23 H23 107.7 C24 C23 H23 107.7 C25 C23 H23 107.7 C23 C24 H24A 109.5 C23 C24 H24B 109.5 H24A C24 H24B 109.5 C23 C24 H24C 109.5 H24A C24 H24C 109.5 H24B C24 H24C 109.5 C23 C25 H25A 109.5 C23 C25 H25B 109.5 H25A C25 H25B 109.5 C23 C25 H25C 109.5 H25A C25 H25C 109.5 H25B C25 H25C 109.5 O27 N26 O28 123.1(3) O27 N26 C12 118.9(3) O28 N26 C12 118.0(3) C31 C30 C35 117.5(2) C31 C30 C36 119.1(2) C35 C30 C36 123.4(2) C30 C31 C32 123.1(2) C30 C31 H31 118.5 C32 C31 H31 118.5 C31 C32 C33 118.3(2) C31 C32 C44 118.6(2) C33 C32 C44 123.1(2) C34 C33 C32 120.2(2) C34 C33 N47 117.5(2) C32 C33 N47 122.3(2) C35 C34 C33 119.4(2) C35 C34 C52 119.7(2) C33 C34 C52 120.9(2) C34 C35 C30 121.5(2) C34 C35 H35 119.2 C30 C35 H35 119.2 C37 C36 C30 127.1(2) C37 C36 H36 116.4 C30 C36 H36 116.4 C36 C37 C38 127.2(2) C36 C37 H37 116.4 C38 C37 H37 116.4 C39 C38 C43 118.2(2) C39 C38 C37 119.3(2) C43 C38 C37 122.5(2) C40 C39 C38 122.1(3) C40 C39 H39 118.9 C38 C39 H39 118.9 C39 C40 C41 118.0(3) C39 C40 H40 121.0 C41 C40 H40 121.0 C42 C41 C40 121.9(2) C42 C41 N55 119.5(3) C40 C41 N55 118.5(3) C41 C42 C43 119.5(3) C41 C42 H42 120.2 C43 C42 H42 120.2 C42 C43 C38 120.2(3) C42 C43 H43 119.9 C38 C43 H43 119.9 C46 C44 C45 111.0(3) C46 C44 C32 111.4(2) C45 C44 C32 111.2(2) C46 C44 H44 107.7 C45 C44 H44 107.7 C32 C44 H44 107.7 C44 C45 H45A 109.5 C44 C45 H45B 109.5 H45A C45 H45B 109.5 C44 C45 H45C 109.5 H45A C45 H45C 109.5 H45B C45 H45C 109.5 C44 C46 H46A 109.5 C44 C46 H46B 109.5 H46A C46 H46B 109.5 C44 C46 H46C 109.5 H46A C46 H46C 109.5 H46B C46 H46C 109.5 C33 N47 C48 117.2(2) C33 N47 C50 116.5(2) C48 N47 C50 115.8(2) N47 C48 C49 112.1(2) N47 C48 H48A 109.2 C49 C48 H48A 109.2 N47 C48 H48B 109.2 C49 C48 H48B 109.2 H48A C48 H48B 107.9 C48 C49 H49A 109.5 C48 C49 H49B 109.5 H49A C49 H49B 109.5 C48 C49 H49C 109.5 H49A C49 H49C 109.5 H49B C49 H49C 109.5 N47 C50 C51 112.6(2) N47 C50 H50A 109.1 C51 C50 H50A 109.1 N47 C50 H50B 109.1 C51 C50 H50B 109.1 H50A C50 H50B 107.8 C50 C51 H51A 109.5 C50 C51 H51B 109.5 H51A C51 H51B 109.5 C50 C51 H51C 109.5 H51A C51 H51C 109.5 H51B C51 H51C 109.5 C53 C52 C34 111.0(2) C53 C52 C54 110.3(3) C34 C52 C54 113.8(2) C53 C52 H52 107.1 C34 C52 H52 107.1 C54 C52 H52 107.1 C52 C53 H53A 109.5 C52 C53 H53B 109.5 H53A C53 H53B 109.5 C52 C53 H53C 109.5 H53A C53 H53C 109.5 H53B C53 H53C 109.5 C52 C54 H54A 109.5 C52 C54 H54B 109.5 H54A C54 H54B 109.5 C52 C54 H54C 109.5 H54A C54 H54C 109.5 H54B C54 H54C 109.5 O57 N55 O56 123.0(3) O57 N55 C41 119.2(3) O56 N55 C41 117.8(3) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance C1 C6 1.389(4) C1 C2 1.405(3) C1 C7 1.458(3) C2 C3 1.389(4) C2 H2 0.9500 C3 C4 1.398(3) C3 C15 1.523(4) C4 C5 1.421(3) C4 N18 1.434(3) C5 C6 1.388(4) C5 C23 1.515(4) C6 H6 0.9500 C7 C8 1.333(4) C7 H7 0.9500 C8 C9 1.463(3) C8 H8 0.9500 C9 C14 1.384(4) C9 C10 1.402(4) C10 C11 1.382(4) C10 H10 0.9500 C11 C12 1.375(4) C11 H11 0.9500 C12 C13 1.384(4) C12 N26 1.460(4) C13 C14 1.380(4) C13 H13 0.9500 C14 H14 0.9500 C15 C17 1.520(4) C15 C16 1.522(4) C15 H15 1.0000 C16 H16A 0.9800 C16 H16B 0.9800 C16 H16C 0.9800 C17 H17A 0.9800 C17 H17B 0.9800 C17 H17C 0.9800 N18 C19 1.458(3) N18 C21 1.460(3) C19 C20 1.514(4) C19 H19A 0.9900 C19 H19B 0.9900 C20 H20A 0.9800 C20 H20B 0.9800 C20 H20C 0.9800 C21 C22 1.523(4) C21 H21A 0.9900 C21 H21B 0.9900 C22 H22A 0.9800 C22 H22B 0.9800 C22 H22C 0.9800 C23 C24 1.523(4) C23 C25 1.525(4) C23 H23 1.0000 C24 H24A 0.9800 C24 H24B 0.9800 C24 H24C 0.9800 C25 H25A 0.9800 C25 H25B 0.9800 C25 H25C 0.9800 N26 O27 1.223(3) N26 O28 1.236(3) C30 C31 1.385(4) C30 C35 1.406(4) C30 C36 1.456(4) C31 C32 1.389(4) C31 H31 0.9500 C32 C33 1.411(3) C32 C44 1.523(4) C33 C34 1.402(3) C33 N47 1.440(3) C34 C35 1.391(4) C34 C52 1.514(3) C35 H35 0.9500 C36 C37 1.331(4) C36 H36 0.9500 C37 C38 1.464(4) C37 H37 0.9500 C38 C39 1.387(4) C38 C43 1.408(4) C39 C40 1.380(4) C39 H39 0.9500 C40 C41 1.384(4) C40 H40 0.9500 C41 C42 1.374(4) C41 N55 1.459(4) C42 C43 1.382(4) C42 H42 0.9500 C43 H43 0.9500 C44 C46 1.519(4) C44 C45 1.522(4) C44 H44 1.0000 C45 H45A 0.9800 C45 H45B 0.9800 C45 H45C 0.9800 C46 H46A 0.9800 C46 H46B 0.9800 C46 H46C 0.9800 N47 C48 1.452(3) N47 C50 1.459(3) C48 C49 1.510(4) C48 H48A 0.9900 C48 H48B 0.9900 C49 H49A 0.9800 C49 H49B 0.9800 C49 H49C 0.9800 C50 C51 1.504(4) C50 H50A 0.9900 C50 H50B 0.9900 C51 H51A 0.9800 C51 H51B 0.9800 C51 H51C 0.9800 C52 C53 1.511(4) C52 C54 1.522(4) C52 H52 1.0000 C53 H53A 0.9800 C53 H53B 0.9800 C53 H53C 0.9800 C54 H54A 0.9800 C54 H54B 0.9800 C54 H54C 0.9800 N55 O57 1.217(3) N55 O56 1.239(3) loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion C6 C1 C2 C3 -1.1(4) C7 C1 C2 C3 178.2(3) C1 C2 C3 C4 -0.3(4) C1 C2 C3 C15 177.9(2) C2 C3 C4 C5 2.1(4) C15 C3 C4 C5 -176.1(2) C2 C3 C4 N18 -176.8(2) C15 C3 C4 N18 5.0(4) C3 C4 C5 C6 -2.3(4) N18 C4 C5 C6 176.5(2) C3 C4 C5 C23 177.5(2) N18 C4 C5 C23 -3.7(4) C4 C5 C6 C1 0.9(4) C23 C5 C6 C1 -179.0(2) C2 C1 C6 C5 0.8(4) C7 C1 C6 C5 -178.5(3) C6 C1 C7 C8 175.8(3) C2 C1 C7 C8 -3.6(4) C1 C7 C8 C9 -177.8(3) C7 C8 C9 C14 171.6(3) C7 C8 C9 C10 -6.4(4) C14 C9 C10 C11 -0.6(4) C8 C9 C10 C11 177.4(3) C9 C10 C11 C12 0.0(4) C10 C11 C12 C13 0.7(4) C10 C11 C12 N26 -179.2(3) C11 C12 C13 C14 -0.7(4) N26 C12 C13 C14 179.1(3) C12 C13 C14 C9 0.0(4) C10 C9 C14 C13 0.6(4) C8 C9 C14 C13 -177.5(3) C2 C3 C15 C17 46.7(4) C4 C3 C15 C17 -135.1(3) C2 C3 C15 C16 -78.1(3) C4 C3 C15 C16 100.1(3) C3 C4 N18 C19 109.1(3) C5 C4 N18 C19 -69.7(3) C3 C4 N18 C21 -106.9(3) C5 C4 N18 C21 74.3(3) C4 N18 C19 C20 -53.8(3) C21 N18 C19 C20 161.4(2) C4 N18 C21 C22 133.2(3) C19 N18 C21 C22 -82.3(3) C6 C5 C23 C24 -62.7(3) C4 C5 C23 C24 117.5(3) C6 C5 C23 C25 61.6(3) C4 C5 C23 C25 -118.2(3) C11 C12 N26 O27 178.4(3) C13 C12 N26 O27 -1.5(4) C11 C12 N26 O28 -1.4(4) C13 C12 N26 O28 178.8(3) C35 C30 C31 C32 -1.5(4) C36 C30 C31 C32 178.4(3) C30 C31 C32 C33 -0.8(4) C30 C31 C32 C44 179.5(2) C31 C32 C33 C34 2.7(4) C44 C32 C33 C34 -177.6(2) C31 C32 C33 N47 -176.9(2) C44 C32 C33 N47 2.8(4) C32 C33 C34 C35 -2.2(4) N47 C33 C34 C35 177.3(2) C32 C33 C34 C52 175.5(2) N47 C33 C34 C52 -4.9(4) C33 C34 C35 C30 -0.1(4) C52 C34 C35 C30 -177.9(2) C31 C30 C35 C34 2.0(4) C36 C30 C35 C34 -177.9(2) C31 C30 C36 C37 -173.6(3) C35 C30 C36 C37 6.3(4) C30 C36 C37 C38 177.1(3) C36 C37 C38 C39 -172.5(3) C36 C37 C38 C43 4.8(4) C43 C38 C39 C40 -0.5(4) C37 C38 C39 C40 176.9(2) C38 C39 C40 C41 -0.2(4) C39 C40 C41 C42 0.8(4) C39 C40 C41 N55 -179.4(2) C40 C41 C42 C43 -0.6(5) N55 C41 C42 C43 179.5(3) C41 C42 C43 C38 -0.1(4) C39 C38 C43 C42 0.7(4) C37 C38 C43 C42 -176.7(3) C31 C32 C44 C46 -63.0(3) C33 C32 C44 C46 117.4(3) C31 C32 C44 C45 61.4(3) C33 C32 C44 C45 -118.3(3) C34 C33 N47 C48 108.3(3) C32 C33 N47 C48 -72.1(3) C34 C33 N47 C50 -108.3(3) C32 C33 N47 C50 71.3(3) C33 N47 C48 C49 -138.5(3) C50 N47 C48 C49 77.8(3) C33 N47 C50 C51 53.3(3) C48 N47 C50 C51 -162.7(2) C35 C34 C52 C53 80.0(3) C33 C34 C52 C53 -97.7(3) C35 C34 C52 C54 -45.1(4) C33 C34 C52 C54 137.1(3) C42 C41 N55 O57 -178.4(3) C40 C41 N55 O57 1.7(4) C42 C41 N55 O56 0.7(4) C40 C41 N55 O56 -179.2(3)