#------------------------------------------------------------------------------ #$Date: 2012-02-25 22:47:32 +0000 (Sat, 25 Feb 2012) $ #$Revision: 34932 $ #$URL: svn://www.crystallography.net/cod/cif/4/00/07/4000753.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_4000753 loop_ _publ_author_name 'Guiot, V.' 'Janod, E.' 'Corraze, B.' 'Cario, L.' _publ_section_title ; Control of the Electronic Properties and Resistive Switching in the New Series of Mott Insulators GaTa4Se8--yTey(0 ≤y≤ 6.5) ; _journal_issue 10 _journal_name_full 'Chemistry of Materials' _journal_page_first 2611 _journal_volume 23 _journal_year 2011 _chemical_formula_sum 'Ga Se5.24 Ta4 Te2.76' _chemical_formula_weight 1558.5 _chemical_name_systematic ' ?' _space_group_IT_number 216 _symmetry_cell_setting cubic _symmetry_space_group_name_Hall 'F -4 2 3' _symmetry_space_group_name_H-M 'F -4 3 m' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 10.7389(10) _cell_length_b 10.7389(10) _cell_length_c 10.7389(10) _cell_measurement_reflns_used 8695 _cell_measurement_temperature 295 _cell_measurement_theta_max 34.97 _cell_measurement_theta_min 6.58 _cell_volume 1238.5(2) _computing_publication_material 'Jana2006 (Petricek, Dusek & Palatinus, 2006)' _computing_structure_refinement 'Jana2006 (Petricek, Dusek & Palatinus, 2006)' _diffrn_ambient_temperature 295 _diffrn_measured_fraction_theta_full 0.98 _diffrn_measurement_device 'four-cycle diffractometer' _diffrn_measurement_device_type 'Nonius CCD' _diffrn_measurement_method ;'302 images collected with a CCD camera' 'and 2° rotation and 40s exposure per frame' ; _diffrn_radiation_monochromator graphite _diffrn_radiation_source 'X-ray tube' _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.71069 _diffrn_reflns_av_R_equivalents 0.0985 _diffrn_reflns_av_sigmaI/netI 0.0103 _diffrn_reflns_limit_h_max 15 _diffrn_reflns_limit_h_min -17 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_k_min -17 _diffrn_reflns_limit_l_max 17 _diffrn_reflns_limit_l_min -17 _diffrn_reflns_number 8695 _diffrn_reflns_theta_full 34.97 _diffrn_reflns_theta_max 34.97 _diffrn_reflns_theta_min 6.58 _exptl_absorpt_coefficient_mu 59.086 _exptl_absorpt_correction_T_max 0.2383 _exptl_absorpt_correction_T_min 0.0832 _exptl_absorpt_correction_type gaussian _exptl_absorpt_process_details 'Jana2006 (Petricek, Dusek & Palatinus, 2000)' _exptl_crystal_colour 'metallic grey' _exptl_crystal_density_diffrn 8.3558(13) _exptl_crystal_description 'small slab from bigger single crystal' _exptl_crystal_F_000 2578 _exptl_crystal_size_max 0.049 _exptl_crystal_size_mid 0.048 _exptl_crystal_size_min 0.032 _refine_diff_density_max 1.82 _refine_diff_density_min -2.41 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_gt 1.13 _refine_ls_goodness_of_fit_ref 1.13 _refine_ls_number_constraints 3 _refine_ls_number_parameters 12 _refine_ls_number_reflns 319 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0309 _refine_ls_R_factor_gt 0.0280 _refine_ls_shift/su_max 0.0059 _refine_ls_shift/su_mean 0.0019 _refine_ls_structure_factor_coef F _refine_ls_weighting_details w=1/(\s^2^(F)+0.0009F^2^) _refine_ls_weighting_scheme sigma _refine_ls_wR_factor_gt 0.0383 _refine_ls_wR_factor_ref 0.0391 _reflns_number_gt 307 _reflns_number_total 319 _reflns_threshold_expression I>3\s(I) _[local]_cod_data_source_file cm200266n_si_004.cif _[local]_cod_data_source_block (I) _[local]_cod_chemical_formula_sum_orig 'Ga1 Se5.24 Ta4 Te2.76' _cod_database_code 4000753 loop_ _symmetry_equiv_pos_site_id _symmetry_equiv_pos_as_xyz 1 x,y,z 2 -x,-y,z 3 -x,y,-z 4 x,-y,-z 5 z,x,y 6 z,-x,-y 7 -z,-x,y 8 -z,x,-y 9 y,z,x 10 -y,z,-x 11 y,-z,-x 12 -y,-z,x 13 y,x,z 14 -y,-x,z 15 y,-x,-z 16 -y,x,-z 17 x,z,y 18 -x,z,-y 19 -x,-z,y 20 x,-z,-y 21 z,y,x 22 z,-y,-x 23 -z,y,-x 24 -z,-y,x 25 x,y+1/2,z+1/2 26 -x,-y+1/2,z+1/2 27 -x,y+1/2,-z+1/2 28 x,-y+1/2,-z+1/2 29 z,x+1/2,y+1/2 30 z,-x+1/2,-y+1/2 31 -z,-x+1/2,y+1/2 32 -z,x+1/2,-y+1/2 33 y,z+1/2,x+1/2 34 -y,z+1/2,-x+1/2 35 y,-z+1/2,-x+1/2 36 -y,-z+1/2,x+1/2 37 y,x+1/2,z+1/2 38 -y,-x+1/2,z+1/2 39 y,-x+1/2,-z+1/2 40 -y,x+1/2,-z+1/2 41 x,z+1/2,y+1/2 42 -x,z+1/2,-y+1/2 43 -x,-z+1/2,y+1/2 44 x,-z+1/2,-y+1/2 45 z,y+1/2,x+1/2 46 z,-y+1/2,-x+1/2 47 -z,y+1/2,-x+1/2 48 -z,-y+1/2,x+1/2 49 x+1/2,y,z+1/2 50 -x+1/2,-y,z+1/2 51 -x+1/2,y,-z+1/2 52 x+1/2,-y,-z+1/2 53 z+1/2,x,y+1/2 54 z+1/2,-x,-y+1/2 55 -z+1/2,-x,y+1/2 56 -z+1/2,x,-y+1/2 57 y+1/2,z,x+1/2 58 -y+1/2,z,-x+1/2 59 y+1/2,-z,-x+1/2 60 -y+1/2,-z,x+1/2 61 y+1/2,x,z+1/2 62 -y+1/2,-x,z+1/2 63 y+1/2,-x,-z+1/2 64 -y+1/2,x,-z+1/2 65 x+1/2,z,y+1/2 66 -x+1/2,z,-y+1/2 67 -x+1/2,-z,y+1/2 68 x+1/2,-z,-y+1/2 69 z+1/2,y,x+1/2 70 z+1/2,-y,-x+1/2 71 -z+1/2,y,-x+1/2 72 -z+1/2,-y,x+1/2 73 x+1/2,y+1/2,z 74 -x+1/2,-y+1/2,z 75 -x+1/2,y+1/2,-z 76 x+1/2,-y+1/2,-z 77 z+1/2,x+1/2,y 78 z+1/2,-x+1/2,-y 79 -z+1/2,-x+1/2,y 80 -z+1/2,x+1/2,-y 81 y+1/2,z+1/2,x 82 -y+1/2,z+1/2,-x 83 y+1/2,-z+1/2,-x 84 -y+1/2,-z+1/2,x 85 y+1/2,x+1/2,z 86 -y+1/2,-x+1/2,z 87 y+1/2,-x+1/2,-z 88 -y+1/2,x+1/2,-z 89 x+1/2,z+1/2,y 90 -x+1/2,z+1/2,-y 91 -x+1/2,-z+1/2,y 92 x+1/2,-z+1/2,-y 93 z+1/2,y+1/2,x 94 z+1/2,-y+1/2,-x 95 -z+1/2,y+1/2,-x 96 -z+1/2,-y+1/2,x loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_adp_type _atom_site_U_iso_or_equiv _atom_site_symmetry_multiplicity _atom_site_occupancy _atom_site_calc_flag Ta1 Ta 0.59937(4) 0.59937(4) 0.59937(4) Uani 0.01450(11) 16 1 d Te1 Te 0.86427(10) 0.86427(10) 0.86427(10) Uani 0.0130(2) 16 0.69(2) d Se1 Se 0.36636(14) 0.36636(14) 0.36636(14) Uani 0.01587(19) 16 1 d Se2 Se 0.86427(10) 0.86427(10) 0.86427(10) Uani 0.0130(2) 16 0.31(2) d Ga1 Ga 0 0 0 Uani 0.0266(5) 4 1 d loop_ _atom_site_aniso_label _atom_site_aniso_type_symbol _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Ta1 Ta 0.01450(19) 0.01450(19) 0.01450(19) 0.00021(13) 0.00021(13) 0.00021(13) Te1 Te 0.0130(3) 0.0130(3) 0.0130(3) 0.0007(3) 0.0007(3) 0.0007(3) Se1 Se 0.0159(3) 0.0159(3) 0.0159(3) -0.0003(4) -0.0003(4) -0.0003(4) Se2 Se 0.0130(3) 0.0130(3) 0.0130(3) 0.0007(3) 0.0007(3) 0.0007(3) Ga1 Ga 0.0266(9) 0.0266(9) 0.0266(9) 0 0 0 loop_ _atom_type_symbol _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source Ga 0.231 1.608 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' Ta -0.705 6.523 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' Se -0.093 2.226 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' Te -0.531 1.675 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle Ta1 Te1 Se1 89.269(28) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Ta1 Te1 74_665 2.8977(12) yes Ta1 Te1 51_656 2.8977(12) yes Ta1 Te1 28_566 2.8977(12) yes Ta1 Se1 2_665 2.5558(17) yes Ta1 Se1 3_656 2.5558(17) yes Ta1 Se1 4_566 2.5558(17) yes Ta1 Se2 74_665 2.8977(12) yes Ta1 Se2 51_656 2.8977(12) yes Ta1 Se2 28_566 2.8977(12) yes Te1 Se2 . 0 yes Te1 Ga1 1_666 2.5247(11) yes Se2 Ga1 1_666 2.5247(11) yes loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_meas _refln_F_calc _refln_F_sigma _refln_observed_status -2 2 2 45.52 43.88 1.39 o 2 2 2 53.53 53.49 1.62 o -3 3 3 162.11 168.08 4.87 o -1 3 3 114.15 119.64 3.43 o 1 3 3 108.24 113.96 3.25 o 3 3 3 160.46 172.10 4.82 o 0 0 4 357.19 360.19 10.72 o -2 2 4 151.39 154.22 4.54 o 0 2 4 7.48 6.60 0.41 o 2 2 4 150.32 155.59 4.51 o -4 4 4 224.18 226.10 6.73 o -2 4 4 58.03 59.53 1.75 o 0 4 4 299.94 312.76 9.00 o 2 4 4 56.77 59.74 1.71 o 4 4 4 211.69 224.19 6.36 o -1 1 5 146.74 144.92 4.41 o 1 1 5 144.00 140.06 4.32 o -3 3 5 26.97 25.75 0.84 o -1 3 5 22.16 21.45 0.69 o 1 3 5 26.57 25.90 0.81 o 3 3 5 22.75 23.27 0.73 o -5 5 5 156.96 155.90 4.72 o -3 5 5 57.80 56.92 1.75 o -1 5 5 117.16 120.64 3.52 o 1 5 5 113.73 114.79 3.42 o 3 5 5 58.96 60.65 1.78 o 5 5 5 144.39 149.77 4.35 o 0 0 6 64.35 65.05 1.94 o -2 2 6 72.05 70.13 2.17 o 0 2 6 37.85 37.65 1.14 o 2 2 6 71.18 71.17 2.14 o -4 4 6 28.28 28.58 0.90 o -2 4 6 102.23 101.44 3.07 o 0 4 6 62.18 63.41 1.87 o 2 4 6 101.08 101.56 3.04 o 4 4 6 21.92 23.91 0.73 o -6 6 6 85.62 84.09 2.61 o -4 6 6 93.13 92.35 2.80 o -2 6 6 83.62 83.69 2.52 o 0 6 6 126.22 127.84 3.79 o 2 6 6 86.48 88.44 2.60 o 4 6 6 90.76 94.27 2.73 o 6 6 6 90.18 91.31 2.75 o -1 1 7 81.47 80.51 2.45 o 1 1 7 83.69 82.76 2.52 o -3 3 7 130.88 128.37 3.93 o -1 3 7 85.85 84.51 2.58 o 1 3 7 82.74 81.45 2.49 o 3 3 7 132.02 134.86 3.96 o -5 5 7 53.27 53.16 1.62 o -3 5 7 30.37 29.58 0.94 o -1 5 7 31.55 31.87 0.97 o 1 5 7 29.27 30.35 0.90 o 3 5 7 31.73 30.85 0.97 o 5 5 7 49.88 51.52 1.52 o -7 7 7 84.04 82.93 2.59 o -5 7 7 15.21 14.29 0.79 o -3 7 7 99.34 97.45 2.99 o -1 7 7 67.97 67.56 2.05 o 1 7 7 61.32 62.10 1.86 o 3 7 7 99.13 102.50 2.99 o 5 7 7 13.45 13.96 0.99 o 7 7 7 87.07 89.37 2.67 o 0 0 8 188.58 186.10 5.66 o -2 2 8 198.46 190.95 5.96 o 0 2 8 10.31 9.35 0.53 o 2 2 8 194.05 190.23 5.82 o -4 4 8 147.10 144.05 4.42 o -2 4 8 61.43 60.59 1.85 o 0 4 8 137.36 135.13 4.12 o 2 4 8 57.30 57.67 1.73 o 4 4 8 139.41 140.59 4.19 o -6 6 8 83.95 81.38 2.54 o -4 6 8 27.32 26.71 0.88 o -2 6 8 114.65 113.26 3.44 o 0 6 8 20.57 19.75 0.69 o 2 6 8 112.51 113.83 3.38 o 4 6 8 23.14 23.41 0.78 o 6 6 8 82.67 81.69 2.50 o -8 8 8 106.49 100.47 3.31 o -6 8 8 39.56 38.92 1.27 o -4 8 8 98.64 95.80 2.98 o -2 8 8 69.34 67.83 2.10 o 0 8 8 97.46 96.32 2.94 o 2 8 8 66.17 67.45 2.01 o 4 8 8 89.69 91.52 2.71 o 6 8 8 34.00 34.64 1.15 o 8 8 8 92.70 95.80 2.86 o -1 1 9 62.75 63.38 1.89 o 1 1 9 60.95 59.27 1.84 o -3 3 9 64.48 63.32 1.95 o -1 3 9 50.95 49.18 1.54 o 1 3 9 52.26 51.73 1.58 o 3 3 9 66.05 64.95 2.00 o -5 5 9 82.21 80.54 2.49 o -3 5 9 21.75 20.32 0.75 o -1 5 9 89.20 88.78 2.68 o 1 5 9 83.92 83.76 2.52 o 3 5 9 23.24 24.09 0.76 o 5 5 9 74.73 74.48 2.26 o -7 7 9 46.38 44.86 1.47 o -5 7 9 20.29 19.15 0.78 o -3 7 9 55.01 54.55 1.67 o -1 7 9 45.17 44.97 1.37 o 1 7 9 42.07 42.95 1.28 o 3 7 9 53.15 54.64 1.61 o 5 7 9 19.18 17.41 0.80 o 7 7 9 44.82 46.18 1.42 o -9 9 9 35.37 31.17 2.22 o -7 9 9 36.63 34.55 1.30 o -5 9 9 63.05 59.98 1.94 o -3 9 9 47.01 45.29 1.49 o -1 9 9 54.68 54.79 1.68 o 1 9 9 50.22 50.42 1.56 o 3 9 9 45.50 46.71 1.45 o 5 9 9 53.74 54.38 1.67 o 7 9 9 34.39 34.12 1.22 o 9 9 9 23.44 25.25 2.13 o 0 0 10 61.20 61.52 1.87 o -2 2 10 98.42 97.78 2.96 o 0 2 10 55.83 55.52 1.69 o 2 2 10 98.47 99.03 2.96 o -4 4 10 20.16 18.66 0.90 o -2 4 10 33.02 32.26 1.03 o 0 4 10 21.51 20.26 0.74 o 2 4 10 34.12 34.20 1.06 o 4 4 10 21.56 21.20 0.86 o -6 6 10 84.17 79.63 2.56 o -4 6 10 90.04 88.08 2.71 o -2 6 10 76.42 75.46 2.30 o 0 6 10 99.03 98.49 2.98 o 2 6 10 78.18 78.30 2.36 o 4 6 10 88.38 89.52 2.66 o 6 6 10 84.85 84.81 2.57 o -8 8 10 24.34 23.85 1.54 o -6 8 10 36.86 35.44 1.20 o -4 8 10 28.16 26.81 0.97 o -2 8 10 34.48 33.67 1.10 o 0 8 10 13.48 13.32 0.86 o 2 8 10 35.14 34.75 1.12 o 4 8 10 26.52 27.82 0.92 o 6 8 10 35.95 36.93 1.15 o 8 8 10 24.80 24.58 1.21 o -10 10 10 48.79 48.01 2.95 o -8 10 10 40.36 39.33 1.68 o -6 10 10 55.98 54.51 1.79 o -4 10 10 78.79 76.21 2.41 o -2 10 10 53.35 51.25 1.68 o 0 10 10 107.06 105.86 3.24 o 2 10 10 54.05 54.04 1.69 o 4 10 10 74.76 77.17 2.29 o 6 10 10 56.09 59.29 1.78 o 8 10 10 39.35 40.22 1.44 o 10 10 10 50.04 51.87 2.25 o -1 1 11 60.13 62.20 1.83 o 1 1 11 61.30 62.90 1.87 o -3 3 11 51.04 49.49 1.58 o -1 3 11 50.28 50.83 1.53 o 1 3 11 47.21 47.95 1.44 o 3 3 11 53.52 53.68 1.64 o -5 5 11 70.29 68.76 2.15 o -3 5 11 22.25 22.13 0.82 o -1 5 11 77.12 75.64 2.33 o 1 5 11 76.13 75.54 2.30 o 3 5 11 22.20 22.39 0.83 o 5 5 11 67.27 68.77 2.06 o -7 7 11 39.89 37.02 1.42 o -5 7 11 9.61 12.32 1.41 o -3 7 11 41.19 40.51 1.29 o -1 7 11 31.64 31.18 1.03 o 1 7 11 28.79 27.85 0.96 o 3 7 11 44.38 46.14 1.37 o 5 7 11 11.73 12.50 1.15 o 7 7 11 40.16 41.78 1.37 o -9 9 11 20.51 27.15 2.65 o -7 9 11 24.35 25.86 1.37 o -5 9 11 49.22 48.13 1.54 o -3 9 11 30.97 30.21 1.12 o -1 9 11 39.39 39.62 1.24 o 1 9 11 38.58 39.50 1.23 o 3 9 11 31.16 31.23 1.07 o 5 9 11 46.31 48.05 1.45 o 7 9 11 24.21 26.22 1.13 o 9 9 11 24.92 27.06 1.56 o -7 11 11 33.03 30.90 1.97 o -5 11 11 42.61 38.41 1.81 o -3 11 11 16.40 16.50 1.91 o -1 11 11 28.94 27.51 1.43 o 1 11 11 27.33 25.41 1.32 o 3 11 11 17.45 21.23 2.01 o 5 11 11 40.49 38.24 1.55 o 7 11 11 32.96 33.64 1.72 o 0 0 12 28.78 28.90 1.13 o -2 2 12 143.61 140.90 4.33 o 0 2 12 24.83 25.50 0.85 o 2 2 12 140.60 140.93 4.24 o -4 4 12 48.62 47.60 1.55 o -2 4 12 35.41 34.92 1.14 o 0 4 12 45.34 42.92 1.41 o 2 4 12 33.14 34.05 1.07 o 4 4 12 42.42 43.60 1.39 o -6 6 12 65.88 63.97 2.06 o -4 6 12 45.79 44.46 1.45 o -2 6 12 94.90 90.74 2.86 o 0 6 12 40.77 40.31 1.28 o 2 6 12 91.54 89.89 2.76 o 4 6 12 41.52 42.05 1.32 o 6 6 12 61.32 62.24 1.93 o -8 8 12 68.46 65.12 2.22 o -6 8 12 22.22 22.40 1.29 o -4 8 12 61.53 60.14 1.89 o -2 8 12 44.28 41.80 1.39 o 0 8 12 34.68 34.66 1.14 o 2 8 12 39.96 39.84 1.27 o 4 8 12 55.80 56.66 1.72 o 6 8 12 19.67 19.35 1.20 o 8 8 12 57.26 62.29 1.86 o -6 10 12 25.00 27.03 1.56 o -4 10 12 40.05 37.80 1.37 o -2 10 12 34.31 31.27 1.27 o 0 10 12 51.00 50.62 1.60 o 2 10 12 28.95 30.13 1.13 o 4 10 12 37.74 37.37 1.29 o 6 10 12 22.28 24.79 1.37 o -2 12 12 21.33 20.66 2.80 o 0 12 12 37.03 36.81 1.71 o 2 12 12 16.54 20.72 2.97 < -1 1 13 31.66 31.57 1.16 o 1 1 13 29.39 28.01 1.08 o -3 3 13 69.66 69.16 2.15 o -1 3 13 39.05 39.17 1.24 o 1 3 13 39.15 39.46 1.24 o 3 3 13 67.32 67.69 2.08 o -5 5 13 28.24 28.41 1.35 o -3 5 13 13.03 13.81 1.34 o -1 5 13 21.30 19.97 0.96 o 1 5 13 14.74 16.50 1.05 o 3 5 13 16.26 16.00 1.02 o 5 5 13 22.69 24.17 1.45 o -7 7 13 52.25 50.52 1.82 o -5 7 13 10.77 8.11 2.03 < -3 7 13 59.67 58.18 1.85 o -1 7 13 36.22 35.29 1.20 o 1 7 13 36.03 36.29 1.20 o 3 7 13 57.97 57.87 1.79 o 5 7 13 12.16 6.72 1.66 o 7 7 13 47.64 49.44 1.65 o -7 9 13 32.49 31.15 1.63 o -5 9 13 15.14 16.69 2.05 o -3 9 13 42.54 40.82 1.44 o -1 9 13 38.31 35.77 1.33 o 1 9 13 34.87 34.30 1.22 o 3 9 13 40.53 41.24 1.36 o 5 9 13 17.61 13.29 1.49 o 7 9 13 29.11 30.90 1.48 o -3 11 13 26.35 27.35 1.83 o -1 11 13 18.76 19.82 2.02 o 1 11 13 19.39 19.92 1.84 o 3 11 13 23.33 26.54 1.71 o 0 0 14 6.37 4.03 3.83 < -2 2 14 87.30 87.54 2.67 o 0 2 14 21.86 21.42 0.99 o 2 2 14 87.89 88.15 2.68 o -4 4 14 14.80 21.55 1.80 o -2 4 14 28.78 27.83 1.09 o 0 4 14 12.30 3.72 1.36 o 2 4 14 29.50 29.64 1.09 o 4 4 14 25.09 26.37 1.38 o -6 6 14 46.67 45.70 1.70 o -4 6 14 45.56 44.61 1.49 o -2 6 14 60.54 60.24 1.88 o 0 6 14 63.67 63.90 1.96 o 2 6 14 62.43 61.35 1.92 o 4 6 14 46.06 45.95 1.48 o 6 6 14 45.10 48.65 1.63 o -6 8 14 22.85 22.81 1.77 o -4 8 14 31.03 30.81 1.40 o -2 8 14 19.64 18.07 1.38 o 0 8 14 28.00 27.17 1.21 o 2 8 14 17.59 19.16 1.39 o 4 8 14 35.07 33.94 1.32 o 6 8 14 21.84 25.05 1.61 o -2 10 14 20.44 23.76 1.91 o 0 10 14 61.25 59.94 1.98 o 2 10 14 21.18 25.46 2.05 o -1 1 15 51.08 53.93 1.64 o 1 1 15 52.83 54.54 1.69 o -3 3 15 21.52 20.08 1.50 o -1 3 15 20.64 20.58 1.10 o 1 3 15 22.71 20.72 1.11 o 3 3 15 13.28 19.23 2.30 < -5 5 15 58.19 59.81 1.95 o -3 5 15 25.47 24.86 1.31 o -1 5 15 49.40 49.58 1.58 o 1 5 15 49.05 50.55 1.58 o 3 5 15 21.33 24.43 1.27 o 5 5 15 58.73 60.95 1.91 o -5 7 15 6.47 15.06 5.70 < -3 7 15 0.00 6.00 37.08 < -1 7 15 7.20 4.72 3.39 < 1 7 15 0.00 6.66 35.43 < 3 7 15 0.00 2.93 36.40 < 5 7 15 12.67 15.43 2.42 < 0 0 16 19.00 17.56 2.16 o -2 2 16 70.97 74.12 2.23 o 0 2 16 15.12 16.66 1.41 o 2 2 16 70.88 73.61 2.21 o -4 4 16 16.46 14.73 2.55 o -2 4 16 18.63 19.63 1.53 o 0 4 16 12.13 13.04 1.93 o 2 4 16 17.43 17.77 1.63 o 4 4 16 4.39 11.10 9.77 < -2 6 16 54.46 54.75 1.78 o 0 6 16 47.09 48.03 1.60 o 2 6 16 50.54 53.52 1.70 o -1 1 17 12.66 14.90 3.01 < 1 1 17 17.82 16.71 2.23 o -1 3 17 20.63 21.67 1.67 o 1 3 17 23.90 23.32 1.54 o