Crystallography Open Database

Information card for entry 4060275

Preview

Coordinates	4060275.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C79 H130 N12 Na4 P6 Sn2
Calculated formula	C79 H130 N12 Na4 P6 Sn2
SMILES	[Sn]12P(c3ccccc3)[P]([Na]34([N](C)(C)CC[N]3(C)CC[N]4(C)C)[P]2([Sn]2[P]1(c1ccccc1)[Na]13([N](C)(C)CC[N]1(C)CC[N]3(C)C)[P](P2c1ccccc1)(c1ccccc1)[Na]12[N](C)(C)CC[N]1(C)CC[N]2(C)C)c1ccccc1)(c1ccccc1)[Na]12[N](C)(C)CC[N]1(C)CC[N]2(C)C.c1(ccccc1)C
Title of publication	Reactions of Sn(NMe~2~)~2~ with Primary Aryl Phosphides, ArPH-: Synthesis and Structures of the Heteroleptic Cages [{(PhP‒PPh)Sn(μ-PPh)}~2~(Na·PMDETA)~4~ and [{Sn(μ~3~-Ppy)}~3~{Sn(μ~3~,μ~1~-pyP‒Ppy)}~3~]
Authors of publication	García, Felipe; Hopkins, Alexander D.; Kowenicki, Richard A.; McPartlin, Mary; Pask, Christopher M.; Stead, Matthew L.; Woods, Anthony D.; Wright, Dominic S.
Journal of publication	Organometallics
Year of publication	2005
Journal volume	24
Journal issue	8
Pages of publication	1813 - 1818
a	22.058 ± 0.004 Å
b	18.543 ± 0.004 Å
c	25.931 ± 0.005 Å
α	90°
β	109.2 ± 0.03°
γ	90°
Cell volume	10017 ± 3 Å³
Cell temperature	180 ± 2 K
Ambient diffraction temperature	180 ± 2 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Version history is temporarily not available due to server issues.