Crystallography Open Database

Information card for entry 4075639

Preview

Coordinates	4075639.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C15 H35 F Ni P2
Calculated formula	C15 H35 F Ni P2
SMILES	[Ni]1([P](CC[P]1(C(C)C)C(C)C)(C(C)C)C(C)C)(F)C
Title of publication	Fluoride Displacement by Lithium Reagents. An Improved Method for the Synthesis of Nickel Hydroxo, Alkoxo, and Amido Complexes
Authors of publication	Cámpora, Juan; Matas, Inmaculada; Palma, Pilar; Graiff, Claudia; Tiripicchio, Antonio
Journal of publication	Organometallics
Year of publication	2005
Journal volume	24
Journal issue	12
Pages of publication	2827
a	7.727 ± 0.003 Å
b	13.228 ± 0.005 Å
c	18.666 ± 0.005 Å
α	90°
β	96.02 ± 0.05°
γ	90°
Cell volume	1897.4 ± 1.2 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.064
Residual factor for significantly intense reflections	0.0581
Weighted residual factors for significantly intense reflections	0.1701
Weighted residual factors for all reflections included in the refinement	0.189
Goodness-of-fit parameter for all reflections included in the refinement	1.078
Diffraction radiation wavelength	1.5418 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178645 (current)	2016-03-21	cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/56.	4075639.cif
120075	2014-07-11	Adding DOIs to range 4/07 structures.	4075639.cif
50597	2012-03-31	../uploads/cif-deposit/cod/cif Adding structures of 4075639, 4075640 via cif-deposit CGI script.	4075639.cif