#------------------------------------------------------------------------------ #$Date: 2009-11-16 01:43:51 +0000 (Mon, 16 Nov 2009) $ #$Revision: 853 $ #$URL: svn://www.crystallography.net/cod/cif/4/4300911.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_4300911 _journal_name_full 'Inorganic Chemistry' _journal_year 2005 _chemical_formula_sum 'C22 H56 Ga N2 P2 Si4' _chemical_formula_weight 592.71 _symmetry_cell_setting monoclinic _space_group_IT_number 13 _symmetry_space_group_name_Hall '-P 2yc' _symmetry_space_group_name_H-M 'P 1 2/c 1' _[local]_cod_cif_authors_sg_H-M 'P 2/c' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' _cell_length_a 31.505(6) _cell_length_b 9.822(2) _cell_length_c 16.731(3) _cell_angle_alpha 90.00 _cell_angle_beta 90.69(3) _cell_angle_gamma 90.00 _cell_volume 5176.9(18) _cell_formula_units_Z 6 _cell_measurement_temperature 150(2) _exptl_crystal_density_diffrn 1.141 _diffrn_ambient_temperature 150(2) loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ga1 Ga 0.829565(13) 0.37794(5) 0.55048(3) 0.03261(15) Uani 1 1 d . . . Ga2 Ga 0.5000 0.11520(6) 0.2500 0.02964(18) Uani 1 2 d S . . P1 P 0.78202(3) 0.39406(12) 0.44193(6) 0.0344(3) Uani 1 1 d . . . P2 P 0.88439(3) 0.21971(13) 0.53537(6) 0.0381(3) Uani 1 1 d . . . P3 P 0.55295(3) -0.01216(12) 0.18769(7) 0.0345(3) Uani 1 1 d . A . Si1 Si 0.72467(4) 0.51093(14) 0.48149(8) 0.0405(3) Uani 1 1 d . . . Si2 Si 0.75581(4) 0.19099(15) 0.40234(8) 0.0446(4) Uani 1 1 d . . . Si3 Si 0.91834(4) 0.23191(18) 0.41885(8) 0.0570(5) Uani 1 1 d . . . Si4 Si 0.93468(4) 0.23171(16) 0.63245(8) 0.0473(4) Uani 1 1 d . . . Si5 Si 0.60604(4) 0.12334(14) 0.14741(8) 0.0415(3) Uani 1 1 d . . . Si6 Si 0.58295(4) -0.16910(13) 0.26807(8) 0.0402(3) Uani 1 1 d . . . N1 N 0.80534(10) 0.3559(4) 0.65896(19) 0.0359(9) Uani 1 1 d . . . N2 N 0.84383(10) 0.5649(4) 0.5869(2) 0.0405(9) Uani 1 1 d . . . N3 N 0.48229(10) 0.2643(4) 0.1769(2) 0.0401(9) Uani 1 1 d . . . C1 C 0.81113(14) 0.4713(5) 0.6998(3) 0.0469(12) Uani 1 1 d . . . H1 H 0.8019 0.4795 0.7534 0.056 Uiso 1 1 calc R . . C2 C 0.83110(14) 0.5795(5) 0.6617(3) 0.0486(13) Uani 1 1 d . . . H2 H 0.8356 0.6632 0.6890 0.058 Uiso 1 1 calc R . . C3 C 0.78847(13) 0.2318(5) 0.6988(3) 0.0410(11) Uani 1 1 d . . . C4 C 0.77010(16) 0.1407(5) 0.6336(3) 0.0561(14) Uani 1 1 d . . . H4A H 0.7470 0.1887 0.6057 0.084 Uiso 1 1 calc R . . H4B H 0.7591 0.0571 0.6576 0.084 Uiso 1 1 calc R . . H4C H 0.7924 0.1177 0.5955 0.084 Uiso 1 1 calc R . . C5 C 0.75368(15) 0.2672(6) 0.7590(3) 0.0583(14) Uani 1 1 d . . . H5A H 0.7660 0.3216 0.8026 0.087 Uiso 1 1 calc R . . H5B H 0.7417 0.1831 0.7808 0.087 Uiso 1 1 calc R . . H5C H 0.7312 0.3195 0.7321 0.087 Uiso 1 1 calc R . . C6 C 0.82492(15) 0.1573(5) 0.7406(3) 0.0580(14) Uani 1 1 d . . . H6A H 0.8466 0.1334 0.7015 0.087 Uiso 1 1 calc R . . H6B H 0.8141 0.0742 0.7657 0.087 Uiso 1 1 calc R . . H6C H 0.8375 0.2165 0.7817 0.087 Uiso 1 1 calc R . . C7 C 0.86953(14) 0.6724(6) 0.5481(3) 0.0529(14) Uani 1 1 d . . . C8 C 0.86433(16) 0.6567(6) 0.4579(3) 0.0673(17) Uani 1 1 d . . . H8A H 0.8725 0.5643 0.4423 0.101 Uiso 1 1 calc R . . H8B H 0.8825 0.7228 0.4309 0.101 Uiso 1 1 calc R . . H8C H 0.8346 0.6727 0.4426 0.101 Uiso 1 1 calc R . . C9 C 0.91608(14) 0.6532(6) 0.5718(3) 0.0652(16) Uani 1 1 d . . . H9A H 0.9194 0.6637 0.6298 0.098 Uiso 1 1 calc R . . H9B H 0.9334 0.7216 0.5447 0.098 Uiso 1 1 calc R . . H9C H 0.9254 0.5619 0.5561 0.098 Uiso 1 1 calc R . . C10 C 0.85497(17) 0.8164(5) 0.5730(4) 0.0695(17) Uani 1 1 d . . . H10A H 0.8242 0.8245 0.5649 0.104 Uiso 1 1 calc R . . H10B H 0.8695 0.8846 0.5405 0.104 Uiso 1 1 calc R . . H10C H 0.8620 0.8313 0.6296 0.104 Uiso 1 1 calc R . . C11 C 0.69677(15) 0.4472(6) 0.5718(3) 0.0620(15) Uani 1 1 d . . . H11A H 0.7167 0.4440 0.6171 0.093 Uiso 1 1 calc R . . H11B H 0.6857 0.3557 0.5613 0.093 Uiso 1 1 calc R . . H11C H 0.6732 0.5086 0.5844 0.093 Uiso 1 1 calc R . . C12 C 0.68586(13) 0.5166(5) 0.3950(3) 0.0561(14) Uani 1 1 d . . . H12A H 0.6775 0.4237 0.3804 0.084 Uiso 1 1 calc R . . H12B H 0.6992 0.5607 0.3492 0.084 Uiso 1 1 calc R . . H12C H 0.6607 0.5684 0.4105 0.084 Uiso 1 1 calc R . . C13 C 0.74092(16) 0.6900(5) 0.5049(3) 0.0624(15) Uani 1 1 d . . . H13A H 0.7156 0.7453 0.5144 0.094 Uiso 1 1 calc R . . H13B H 0.7565 0.7279 0.4597 0.094 Uiso 1 1 calc R . . H13C H 0.7591 0.6907 0.5528 0.094 Uiso 1 1 calc R . . C14 C 0.70182(15) 0.1455(5) 0.4393(3) 0.0639(16) Uani 1 1 d . . . H14A H 0.6929 0.0584 0.4160 0.096 Uiso 1 1 calc R . . H14B H 0.6815 0.2166 0.4235 0.096 Uiso 1 1 calc R . . H14C H 0.7027 0.1379 0.4977 0.096 Uiso 1 1 calc R . . C15 C 0.79046(16) 0.0436(5) 0.4288(3) 0.0560(14) Uani 1 1 d . . . H15A H 0.7816 0.0053 0.4800 0.084 Uiso 1 1 calc R . . H15B H 0.8200 0.0742 0.4332 0.084 Uiso 1 1 calc R . . H15C H 0.7880 -0.0261 0.3871 0.084 Uiso 1 1 calc R . . C16 C 0.75196(18) 0.2029(6) 0.2904(3) 0.0669(16) Uani 1 1 d . . . H16A H 0.7804 0.2144 0.2684 0.100 Uiso 1 1 calc R . . H16B H 0.7343 0.2812 0.2755 0.100 Uiso 1 1 calc R . . H16C H 0.7392 0.1194 0.2690 0.100 Uiso 1 1 calc R . . C17 C 0.94929(17) 0.0691(7) 0.4111(3) 0.084(2) Uani 1 1 d . . . H17A H 0.9296 -0.0081 0.4086 0.126 Uiso 1 1 calc R . . H17B H 0.9679 0.0595 0.4581 0.126 Uiso 1 1 calc R . . H17C H 0.9665 0.0710 0.3627 0.126 Uiso 1 1 calc R . . C18 C 0.87890(15) 0.2357(7) 0.3343(3) 0.077(2) Uani 1 1 d . . . H18A H 0.8939 0.2434 0.2835 0.116 Uiso 1 1 calc R . . H18B H 0.8600 0.3140 0.3406 0.116 Uiso 1 1 calc R . . H18C H 0.8622 0.1515 0.3344 0.116 Uiso 1 1 calc R . . C19 C 0.95496(16) 0.3791(7) 0.4019(4) 0.088(2) Uani 1 1 d . . . H19A H 0.9759 0.3837 0.4455 0.132 Uiso 1 1 calc R . . H19B H 0.9385 0.4638 0.4002 0.132 Uiso 1 1 calc R . . H19C H 0.9696 0.3669 0.3510 0.132 Uiso 1 1 calc R . . C20 C 0.93965(14) 0.0567(5) 0.6753(3) 0.0572(14) Uani 1 1 d . . . H20A H 0.9627 0.0551 0.7151 0.086 Uiso 1 1 calc R . . H20B H 0.9459 -0.0081 0.6325 0.086 Uiso 1 1 calc R . . H20C H 0.9130 0.0313 0.7008 0.086 Uiso 1 1 calc R . . C21 C 0.98900(14) 0.2762(7) 0.5953(3) 0.0761(19) Uani 1 1 d . . . H21A H 1.0101 0.2587 0.6375 0.114 Uiso 1 1 calc R . . H21B H 0.9898 0.3727 0.5805 0.114 Uiso 1 1 calc R . . H21C H 0.9955 0.2204 0.5484 0.114 Uiso 1 1 calc R . . C22 C 0.92192(16) 0.3537(6) 0.7146(3) 0.0627(16) Uani 1 1 d . . . H22A H 0.8913 0.3518 0.7246 0.094 Uiso 1 1 calc R . . H22B H 0.9303 0.4459 0.6988 0.094 Uiso 1 1 calc R . . H22C H 0.9374 0.3275 0.7633 0.094 Uiso 1 1 calc R . . C23 C 0.49067(18) 0.3818(5) 0.2123(4) 0.0744(19) Uani 1 1 d . . . H23 H 0.4840 0.4652 0.1864 0.089 Uiso 1 1 calc R . . C24 C 0.46188(15) 0.2603(5) 0.0970(3) 0.0488(13) Uani 1 1 d . . . C25 C 0.4633(2) 0.1205(6) 0.0641(4) 0.096(2) Uani 1 1 d . . . H25A H 0.4452 0.0607 0.0959 0.143 Uiso 1 1 calc R . . H25B H 0.4926 0.0869 0.0661 0.143 Uiso 1 1 calc R . . H25C H 0.4531 0.1213 0.0086 0.143 Uiso 1 1 calc R . . C26 C 0.4829(3) 0.3500(10) 0.0385(6) 0.179(4) Uani 1 1 d U . . H26A H 0.4819 0.3073 -0.0144 0.269 Uiso 1 1 calc R . . H26B H 0.5125 0.3642 0.0548 0.269 Uiso 1 1 calc R . . H26C H 0.4682 0.4378 0.0364 0.269 Uiso 1 1 calc R . . C27 C 0.4178(3) 0.3076(10) 0.1019(5) 0.147(3) Uani 1 1 d U . . H27A H 0.4034 0.2593 0.1451 0.221 Uiso 1 1 calc R . . H27B H 0.4030 0.2896 0.0511 0.221 Uiso 1 1 calc R . . H27C H 0.4175 0.4057 0.1128 0.221 Uiso 1 1 calc R . . C28 C 0.5864(3) 0.2343(10) 0.0638(5) 0.054(3) Uani 0.545(6) 1 d P A 1 H28A H 0.5649 0.2971 0.0840 0.080 Uiso 0.545(6) 1 calc PR A 1 H28B H 0.5739 0.1774 0.0215 0.080 Uiso 0.545(6) 1 calc PR A 1 H28C H 0.6102 0.2865 0.0422 0.080 Uiso 0.545(6) 1 calc PR A 1 C28A C 0.6097(3) 0.1122(13) 0.0382(6) 0.056(3) Uani 0.455(6) 1 d P A 2 H28D H 0.5817 0.1301 0.0141 0.083 Uiso 0.455(6) 1 calc PR A 2 H28E H 0.6191 0.0208 0.0232 0.083 Uiso 0.455(6) 1 calc PR A 2 H28F H 0.6301 0.1797 0.0191 0.083 Uiso 0.455(6) 1 calc PR A 2 C29 C 0.6468(3) 0.0021(10) 0.1032(7) 0.066(3) Uani 0.545(6) 1 d P A 1 H29A H 0.6668 0.0537 0.0707 0.099 Uiso 0.545(6) 1 calc PR A 1 H29B H 0.6322 -0.0657 0.0697 0.099 Uiso 0.545(6) 1 calc PR A 1 H29C H 0.6622 -0.0442 0.1466 0.099 Uiso 0.545(6) 1 calc PR A 1 C29A C 0.6611(3) 0.0829(14) 0.1854(8) 0.071(4) Uani 0.455(6) 1 d PU A 2 H29D H 0.6819 0.1339 0.1544 0.107 Uiso 0.455(6) 1 calc PR A 2 H29E H 0.6664 -0.0149 0.1798 0.107 Uiso 0.455(6) 1 calc PR A 2 H29F H 0.6636 0.1087 0.2419 0.107 Uiso 0.455(6) 1 calc PR A 2 C30 C 0.6297(3) 0.2327(10) 0.2224(6) 0.058(3) Uani 0.545(6) 1 d P A 1 H30A H 0.6532 0.2838 0.1990 0.087 Uiso 0.545(6) 1 calc PR A 1 H30B H 0.6405 0.1772 0.2669 0.087 Uiso 0.545(6) 1 calc PR A 1 H30C H 0.6083 0.2964 0.2421 0.087 Uiso 0.545(6) 1 calc PR A 1 C30A C 0.5982(4) 0.3153(13) 0.1706(8) 0.070(4) Uani 0.455(6) 1 d PU A 2 H30D H 0.5711 0.3284 0.1975 0.105 Uiso 0.455(6) 1 calc PR A 2 H30E H 0.5982 0.3672 0.1205 0.105 Uiso 0.455(6) 1 calc PR A 2 H30F H 0.6214 0.3472 0.2054 0.105 Uiso 0.455(6) 1 calc PR A 2 C31 C 0.54316(15) -0.2442(5) 0.3366(3) 0.0566(14) Uani 1 1 d . A . H31A H 0.5573 -0.3086 0.3729 0.085 Uiso 1 1 calc R . . H31B H 0.5213 -0.2920 0.3052 0.085 Uiso 1 1 calc R . . H31C H 0.5299 -0.1716 0.3677 0.085 Uiso 1 1 calc R . . C32 C 0.6018(2) -0.3086(6) 0.2019(4) 0.094(2) Uani 1 1 d . A . H32A H 0.6234 -0.2732 0.1660 0.142 Uiso 1 1 calc R . . H32B H 0.5778 -0.3440 0.1704 0.142 Uiso 1 1 calc R . . H32C H 0.6139 -0.3819 0.2347 0.142 Uiso 1 1 calc R . . C33 C 0.62821(16) -0.1148(5) 0.3327(4) 0.081(2) Uani 1 1 d . A . H33A H 0.6190 -0.0413 0.3681 0.121 Uiso 1 1 calc R . . H33B H 0.6514 -0.0822 0.2992 0.121 Uiso 1 1 calc R . . H33C H 0.6381 -0.1922 0.3649 0.121 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ga1 0.0256(2) 0.0524(3) 0.0198(2) 0.0034(2) -0.00071(17) -0.0046(2) Ga2 0.0273(3) 0.0225(4) 0.0393(4) 0.000 0.0084(3) 0.000 P1 0.0235(5) 0.0557(8) 0.0240(6) 0.0001(5) -0.0020(4) 0.0029(5) P2 0.0244(5) 0.0674(9) 0.0224(6) 0.0052(6) -0.0014(4) 0.0015(5) P3 0.0292(5) 0.0328(7) 0.0417(7) -0.0024(5) 0.0096(5) 0.0035(5) Si1 0.0286(6) 0.0485(8) 0.0447(8) 0.0020(6) 0.0040(5) 0.0020(6) Si2 0.0431(7) 0.0569(9) 0.0336(7) -0.0111(7) -0.0111(6) 0.0078(7) Si3 0.0296(6) 0.1133(14) 0.0283(7) 0.0146(8) 0.0047(5) 0.0155(7) Si4 0.0302(6) 0.0779(11) 0.0335(7) 0.0139(7) -0.0103(5) -0.0070(6) Si5 0.0302(6) 0.0534(9) 0.0410(8) -0.0014(7) 0.0092(5) -0.0031(6) Si6 0.0365(7) 0.0310(7) 0.0530(8) -0.0041(6) 0.0015(6) 0.0067(6) N1 0.0387(19) 0.048(2) 0.0206(18) -0.0008(17) 0.0014(14) -0.0068(17) N2 0.0354(19) 0.054(2) 0.032(2) 0.0058(19) -0.0058(16) -0.0127(18) N3 0.0340(19) 0.025(2) 0.062(3) 0.0071(19) 0.0051(17) -0.0002(16) C1 0.054(3) 0.062(4) 0.024(2) -0.006(2) 0.003(2) -0.011(3) C2 0.055(3) 0.054(3) 0.037(3) -0.007(2) -0.007(2) -0.014(3) C3 0.043(2) 0.052(3) 0.027(2) 0.005(2) 0.0082(19) -0.007(2) C4 0.070(3) 0.061(4) 0.037(3) 0.005(3) 0.011(2) -0.021(3) C5 0.057(3) 0.078(4) 0.040(3) 0.003(3) 0.019(2) -0.004(3) C6 0.053(3) 0.071(4) 0.050(3) 0.025(3) 0.006(2) 0.000(3) C7 0.044(3) 0.065(4) 0.050(3) 0.019(3) -0.014(2) -0.020(3) C8 0.057(3) 0.094(4) 0.051(3) 0.031(3) -0.006(3) -0.031(3) C9 0.042(3) 0.085(4) 0.068(4) 0.023(3) -0.013(3) -0.023(3) C10 0.068(4) 0.055(4) 0.085(4) 0.023(3) -0.022(3) -0.020(3) C11 0.051(3) 0.071(4) 0.065(4) 0.005(3) 0.025(3) 0.016(3) C12 0.033(2) 0.061(3) 0.075(4) 0.016(3) -0.008(2) -0.002(2) C13 0.056(3) 0.058(4) 0.072(4) -0.005(3) 0.003(3) 0.006(3) C14 0.053(3) 0.063(4) 0.075(4) -0.020(3) -0.012(3) -0.011(3) C15 0.068(3) 0.059(4) 0.041(3) -0.006(3) -0.010(2) 0.013(3) C16 0.082(4) 0.078(4) 0.041(3) -0.014(3) -0.021(3) 0.020(3) C17 0.059(3) 0.142(6) 0.050(4) 0.008(4) 0.012(3) 0.043(4) C18 0.049(3) 0.157(6) 0.025(3) 0.006(3) 0.004(2) 0.030(4) C19 0.045(3) 0.154(7) 0.065(4) 0.048(4) 0.013(3) 0.001(4) C20 0.039(3) 0.088(4) 0.044(3) 0.016(3) -0.011(2) 0.004(3) C21 0.034(3) 0.132(6) 0.062(4) 0.032(4) -0.016(2) -0.015(3) C22 0.064(3) 0.083(4) 0.040(3) 0.005(3) -0.027(3) -0.012(3) C23 0.075(4) 0.030(3) 0.117(6) 0.011(3) -0.033(3) -0.001(3) C24 0.060(3) 0.040(3) 0.047(3) 0.020(2) 0.016(2) 0.018(2) C25 0.147(6) 0.056(4) 0.082(5) 0.009(4) -0.051(4) -0.006(4) C26 0.210(6) 0.169(6) 0.159(6) 0.015(4) 0.025(4) -0.030(4) C27 0.125(5) 0.182(5) 0.134(5) -0.030(4) -0.036(4) 0.057(4) C28 0.049(5) 0.061(7) 0.050(6) 0.017(5) 0.008(4) -0.012(5) C28A 0.046(6) 0.080(9) 0.041(7) 0.012(6) 0.005(5) -0.017(6) C29 0.042(5) 0.070(7) 0.087(8) -0.006(6) 0.035(5) 0.009(5) C29A 0.058(5) 0.084(6) 0.071(6) 0.007(4) 0.001(4) -0.008(4) C30 0.051(6) 0.058(7) 0.064(7) -0.003(5) 0.005(5) -0.029(5) C30A 0.070(5) 0.071(5) 0.070(5) -0.003(4) 0.015(4) -0.016(4) C31 0.053(3) 0.047(3) 0.070(4) 0.020(3) -0.004(3) 0.005(2) C32 0.135(6) 0.072(4) 0.077(5) -0.005(4) 0.011(4) 0.063(4) C33 0.050(3) 0.053(4) 0.138(6) 0.015(4) -0.036(3) 0.001(3) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ga1 N2 1.984(4) . ? Ga1 N1 1.989(3) . ? Ga1 P2 2.3396(13) . ? Ga1 P1 2.3457(13) . ? Ga2 N3 1.984(4) 2_655 ? Ga2 N3 1.984(4) . ? Ga2 P3 2.3402(12) 2_655 ? Ga2 P3 2.3402(12) . ? P1 Si1 2.2468(17) . ? P1 Si2 2.2551(18) . ? P2 Si3 2.2381(18) . ? P2 Si4 2.2585(16) . ? P3 Si6 2.2466(17) . ? P3 Si5 2.2472(17) . ? Si1 C11 1.865(5) . ? Si1 C13 1.872(5) . ? Si1 C12 1.884(5) . ? Si2 C15 1.863(5) . ? Si2 C14 1.871(5) . ? Si2 C16 1.879(5) . ? Si3 C18 1.872(5) . ? Si3 C19 1.874(6) . ? Si3 C17 1.878(6) . ? Si4 C20 1.868(5) . ? Si4 C22 1.870(5) . ? Si4 C21 1.879(5) . ? Si5 C30 1.806(9) . ? Si5 C28A 1.835(10) . ? Si5 C28 1.872(9) . ? Si5 C29A 1.883(11) . ? Si5 C29 1.906(8) . ? Si5 C30A 1.941(12) . ? Si6 C33 1.857(5) . ? Si6 C31 1.861(5) . ? Si6 C32 1.862(6) . ? N1 C1 1.335(5) . ? N1 C3 1.490(5) . ? N2 C2 1.326(6) . ? N2 C7 1.485(6) . ? N3 C23 1.322(6) . ? N3 C24 1.477(6) . ? C1 C2 1.394(6) . ? C3 C4 1.519(6) . ? C3 C6 1.525(6) . ? C3 C5 1.538(6) . ? C7 C8 1.524(7) . ? C7 C9 1.526(6) . ? C7 C10 1.545(7) . ? C23 C23 1.385(11) 2_655 ? C24 C27 1.469(8) . ? C24 C26 1.479(10) . ? C24 C25 1.480(7) . ?