#------------------------------------------------------------------------------ #$Date: 2016-02-16 20:30:59 +0000 (Tue, 16 Feb 2016) $ #$Revision: 176467 $ #$URL: svn://www.crystallography.net/cod/cif/4/30/10/4301022.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_4301022 loop_ _publ_author_name 'Scott Brownridge' 'T. Stanley Cameron' 'Hongbin Du' 'Carsten Knapp' 'Ralf K\"oppe' 'Jack Passmore' 'J. Mikko Rautiainen' 'Hansgeorg Schn\"ockel' _publ_section_title ; The Highest Bond Order Between Heavier Main-Group Elements in an Isolated Compound? Energetics and Vibrational Spectroscopy of S2I4(MF6)2 (M = As, Sb) ; _journal_name_full 'Inorganic Chemistry' _journal_page_first 1660 _journal_page_last 1671 _journal_paper_doi 10.1021/ic049035g _journal_volume 44 _journal_year 2005 _chemical_formula_sum 'As2 F12 I4 S2' _chemical_formula_weight 949.56 _space_group_IT_number 15 _symmetry_cell_setting monoclinic _symmetry_Int_Tables_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _audit_creation_date 2001-05-16 _audit_creation_method 'by teXsan for Windows v1.06' _cell_angle_alpha 90 _cell_angle_beta 94.644(12) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 9.605(2) _cell_length_b 12.734(2) _cell_length_c 13.504(2) _cell_measurement_reflns_used 0 _cell_measurement_temperature 193.2 _cell_measurement_theta_max 0.0 _cell_measurement_theta_min 0.0 _cell_volume 1646.3(5) _computing_cell_refinement 'CrystalClear (Rigaku Corporation, 1999)' _computing_data_collection 'CrystalClear (Rigaku Corporation, 1999)' _computing_data_reduction 'CrystalClear (Rigaku Corporation, 1999)' _computing_publication_material 'teXsan for Windows version 1.06' _computing_structure_refinement 'teXsan for Windows version 1.06' _computing_structure_solution ; SHELX97 (Sheldrick, 1997) ; _diffrn_ambient_temperature 193.2 _diffrn_measurement_device 'Mercury CCD' _diffrn_measurement_method \w _diffrn_orient_matrix_UB_11 0.00000 _diffrn_orient_matrix_UB_12 0.00000 _diffrn_orient_matrix_UB_13 0.00000 _diffrn_orient_matrix_UB_21 0.00000 _diffrn_orient_matrix_UB_22 0.00000 _diffrn_orient_matrix_UB_23 0.00000 _diffrn_orient_matrix_UB_31 0.00000 _diffrn_orient_matrix_UB_32 0.00000 _diffrn_orient_matrix_UB_33 0.00000 _diffrn_radiation_detector CCD _diffrn_radiation_monochromator graphite _diffrn_radiation_source 'X-ray tube' _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.7107 _diffrn_reflns_av_R_equivalents 0.06030 _diffrn_reflns_av_sigmaI/netI 0.086 _diffrn_reflns_limit_h_max 16 _diffrn_reflns_limit_h_min 0 _diffrn_reflns_limit_k_max 21 _diffrn_reflns_limit_k_min -21 _diffrn_reflns_limit_l_max 18 _diffrn_reflns_limit_l_min -20 _diffrn_reflns_number 10848 _diffrn_reflns_reduction_process 'Lp corrections applied' _diffrn_reflns_theta_max 37.98 _diffrn_reflns_theta_min 3.14 _diffrn_standards_decay_% 0.00 _diffrn_standards_interval_count 0 _diffrn_standards_number 0 _exptl_absorpt_coefficient_mu 11.920 _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_correction_T_min 1.000 _exptl_absorpt_correction_type multi-scan _exptl_crystal_colour Deeppurple _exptl_crystal_density_diffrn 3.831 _exptl_crystal_density_meas ? _exptl_crystal_description Squarebasepyramid _exptl_crystal_F_000 1672.00 _exptl_crystal_size_max 0.18 _exptl_crystal_size_mid 0.18 _exptl_crystal_size_min 0.14 _refine_diff_density_max 1.81 _refine_diff_density_min -1.70 _refine_ls_extinction_coef 0.000000048(6) _refine_ls_extinction_expression 'equ(3) Acta Cryst.(1968) A24, p213.' _refine_ls_extinction_method 'Zachariasen (1967)' _refine_ls_goodness_of_fit_all 1.691 _refine_ls_goodness_of_fit_ref 1.690 _refine_ls_matrix_type full _refine_ls_number_constraints 0 _refine_ls_number_parameters 121 _refine_ls_number_reflns 1966 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0355 _refine_ls_R_factor_gt 0.0350 _refine_ls_shift/su_max 0.0000 _refine_ls_shift/su_mean 0.0000 _refine_ls_structure_factor_coef F _refine_ls_weighting_details 'w = 1/[\s^2^(Fo)]' _refine_ls_weighting_scheme sigma _refine_ls_wR_factor_all 0.0410 _refine_ls_wR_factor_ref 0.0410 _reflns_number_gt 1966 _reflns_number_total 3922 _reflns_threshold_expression I>3.00\s(I) _cod_data_source_file ic049035gsi20040720_090839.cif _cod_data_source_block '_Template_texray.inf' _cod_original_cell_volume 1646.2(5) _cod_original_sg_symbol_H-M 'C 2/c ' _cod_original_formula_sum 'As2 F12 I4 S2 ' _cod_database_code 4301022 loop_ _symmetry_equiv_pos_as_xyz ' +x, +y, +z' ' -x, +y,1/2-z' ' -x, -y, -z' ' +x, -y,1/2+z' '1/2+x,1/2+y, +z' 1/2-x,1/2+y,1/2-z '1/2-x,1/2-y, -z' 1/2+x,1/2-y,1/2+z loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_occupancy _atom_site_refinement_flags _atom_site_adp_type _atom_site_calc_flag _atom_site_calc_attached_atom I(1) 0.65314(4) 0.16026(4) 0.61132(3) 0.03516(11) 1.000 . Uani d ? I(2) 0.38488(5) 0.13147(4) 0.57961(3) 0.03876(11) 1.000 . Uani d ? As(1) 1.0000 0.0000 0.5000 0.0275(2) 0.500 S Uani d ? As(2) 1.0000 0.31915(7) 0.7500 0.0295(2) 1.000 S Uani d ? S(5) 0.5962(2) 0.31306(12) 0.75431(11) 0.0303(4) 1.000 . Uani d ? F(1) 1.1098(5) 0.2245(4) 0.7114(5) 0.081(2) 1.000 . Uani d ? F(2) 1.1097(5) 0.4130(4) 0.7113(4) 0.074(2) 1.000 . Uani d ? F(3) 1.0944(6) 0.3178(6) 0.8623(3) 0.085(2) 1.000 . Uani d ? F(4) 1.0905(7) 0.1175(4) 0.5012(5) 0.056(2) 0.740 S Uani d ? F(5) 0.8564(6) 0.0604(5) 0.4430(5) 0.050(2) 0.740 S Uani d ? F(6) 1.0586(7) -0.0281(5) 0.3876(4) 0.052(2) 0.740 S Uani d ? F(7) 1.114(2) 0.016(2) 0.6036(12) 0.063(6) 0.260 S Uani d ? F(8) 1.124(2) 0.045(2) 0.430(2) 0.069(7) 0.260 S Uani d ? F(9) 0.942(2) 0.1224(12) 0.516(2) 0.062(6) 0.260 S Uani d ? loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 I(1) 0.0253(2) 0.0430(2) 0.0382(2) -0.0004(2) 0.0089(2) -0.0053(2) I(2) 0.0288(2) 0.0445(3) 0.0425(2) -0.0075(2) -0.0007(2) -0.0046(2) As(1) 0.0213(4) 0.0249(4) 0.0366(4) 0.0008(3) 0.0045(3) 0.0039(3) As(2) 0.0209(4) 0.0364(5) 0.0307(4) 0.0000 -0.0015(3) 0.0000 S(5) 0.0276(7) 0.0302(8) 0.0335(7) -0.0054(6) 0.0049(6) -0.0015(6) F(1) 0.043(3) 0.061(3) 0.140(5) 0.011(3) 0.008(3) -0.037(3) F(2) 0.030(3) 0.066(3) 0.126(4) -0.012(2) 0.001(3) 0.040(3) F(3) 0.056(3) 0.167(6) 0.030(2) -0.009(4) -0.012(2) -0.002(3) F(4) 0.061(4) 0.037(3) 0.072(4) -0.021(3) 0.007(3) 0.011(3) F(5) 0.033(3) 0.059(4) 0.058(4) 0.016(3) -0.001(3) 0.018(3) F(6) 0.048(4) 0.065(4) 0.044(3) 0.004(3) 0.010(3) -0.001(3) F(7) 0.048(11) 0.10(2) 0.040(9) -0.005(11) -0.025(8) 0.013(9) F(8) 0.048(11) 0.09(2) 0.072(12) 0.020(11) 0.031(10) 0.046(12) F(9) 0.057(12) 0.021(8) 0.11(2) 0.013(8) 0.013(11) 0.007(9) loop_ _atom_type_symbol _atom_type_oxidation_number _atom_type_number_in_cell _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source I 0 16 -0.726 1.812 ;International Tables for Crystallography (1992, Vol. C, Table 6.1.1.2) ; As 0 8 -0.030 2.007 ;International Tables for Crystallography (1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1) ; S 0 8 0.110 0.124 ;International Tables for Crystallography (1992, Vol. C, Table 6.1.1.2) ; F 0 48 0.014 0.010 ;International Tables for Crystallography (1992, Vol. C, Table 6.1.1.2) ; loop_ _diffrn_standard_refln_index_h ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_2 _geom_angle_site_symmetry_3 _geom_angle_publ_flag I2 I1 S5 88.03(5) . . . ? F4 AS1 F4 180.00 . . . ? F4 AS1 F5 89.3(4) . . . ? F4 AS1 F5 90.7(4) . . . ? F4 AS1 F6 89.3(4) . . . ? F4 AS1 F6 90.7(4) . . . ? F4 AS1 F7 68.5(9) . . . ? F4 AS1 F7 111.5(9) . . . ? F4 AS1 F8 48.1(12) . . . ? F4 AS1 F8 131.9(12) . . . ? F4 AS1 F9 50.4(10) . . . ? F4 AS1 F9 129.6(10) . . . ? F4 AS1 F5 90.7(4) 3_756 3_756 3_756 ? F4 AS1 F5 89.3(4) 3_756 3_756 3_756 ? F4 AS1 F6 90.7(4) 3_756 3_756 3_756 ? F4 AS1 F6 89.3(4) 3_756 3_756 3_756 ? F4 AS1 F7 111.5(9) 3_756 3_756 3_756 ? F4 AS1 F7 68.5(9) 3_756 3_756 3_756 ? F4 AS1 F8 131.9(12) 3_756 3_756 3_756 ? F4 AS1 F8 48.1(12) 3_756 3_756 3_756 ? F4 AS1 F9 129.6(10) 3_756 3_756 3_756 ? F4 AS1 F9 50.4(10) 3_756 3_756 3_756 ? F5 AS1 F5 180.00 . . . ? F5 AS1 F6 90.2(4) . . . ? F5 AS1 F6 89.8(4) . . . ? F5 AS1 F7 139.8(11) . . . ? F5 AS1 F7 40.2(11) . . . ? F5 AS1 F8 98.2(9) . . . ? F5 AS1 F8 81.8(9) . . . ? F5 AS1 F9 50.6(11) . . . ? F5 AS1 F9 129.4(11) . . . ? F5 AS1 F6 89.8(4) 3_756 3_756 3_756 ? F5 AS1 F6 90.2(4) 3_756 3_756 3_756 ? F5 AS1 F7 40.2(11) 3_756 3_756 3_756 ? F5 AS1 F7 139.8(11) 3_756 3_756 3_756 ? F5 AS1 F8 81.8(9) 3_756 3_756 3_756 ? F5 AS1 F8 98.2(9) 3_756 3_756 3_756 ? F5 AS1 F9 129.4(11) 3_756 3_756 3_756 ? F5 AS1 F9 50.6(11) 3_756 3_756 3_756 ? F6 AS1 F6 180.00 . . . ? F6 AS1 F7 121.2(11) . . . ? F6 AS1 F7 58.8(11) . . . ? F6 AS1 F8 42.5(11) . . . ? F6 AS1 F8 137.5(11) . . . ? F6 AS1 F9 116.2(9) . . . ? F6 AS1 F9 63.8(9) . . . ? F6 AS1 F7 58.8(11) 3_756 3_756 3_756 ? F6 AS1 F7 121.2(11) 3_756 3_756 3_756 ? F6 AS1 F8 137.5(11) 3_756 3_756 3_756 ? F6 AS1 F8 42.5(11) 3_756 3_756 3_756 ? F6 AS1 F9 63.8(9) 3_756 3_756 3_756 ? F6 AS1 F9 116.2(9) 3_756 3_756 3_756 ? F7 AS1 F7 180.00 . . . ? F7 AS1 F8 91.2(13) . . . ? F7 AS1 F8 88.8(13) . . . ? F7 AS1 F9 90.7(16) . . . ? F7 AS1 F9 89.3(16) . . . ? F7 AS1 F8 88.8(13) 3_756 3_756 3_756 ? F7 AS1 F8 91.2(13) 3_756 3_756 3_756 ? F7 AS1 F9 89.3(16) 3_756 3_756 3_756 ? F7 AS1 F9 90.7(16) 3_756 3_756 3_756 ? F8 AS1 F8 180.00 . . . ? F8 AS1 F9 89.7(14) . . . ? F8 AS1 F9 90.3(14) . . . ? F8 AS1 F9 90.3(14) 3_756 3_756 3_756 ? F8 AS1 F9 89.7(14) 3_756 3_756 3_756 ? F9 AS1 F9 180.00 . . . ? F1 AS2 F1 90.6(5) . . . ? F1 AS2 F2 89.1(4) . . . ? F1 AS2 F2 179.7(3) . . . ? F1 AS2 F3 87.9(4) . . . ? F1 AS2 F3 90.6(4) . . . ? F1 AS2 F2 179.7(3) 2_756 2_756 2_756 ? F1 AS2 F2 89.1(4) 2_756 2_756 2_756 ? F1 AS2 F3 90.6(4) 2_756 2_756 2_756 ? F1 AS2 F3 87.9(4) 2_756 2_756 2_756 ? F2 AS2 F2 91.2(5) . . . ? F2 AS2 F3 89.4(4) . . . ? F2 AS2 F3 92.2(4) . . . ? F2 AS2 F3 92.2(4) 2_756 2_756 2_756 ? F2 AS2 F3 89.4(4) 2_756 2_756 2_756 ? F3 AS2 F3 177.8(6) . . . ? I1 S5 S5 101.85(11) . . . ? AS1 F4 F8 63.4(10) . . . ? AS1 F4 F9 63.7(9) . . . ? F8 F4 F9 113.0(17) . . . ? AS1 F5 F7 69.4(12) . . . ? AS1 F5 F9 64.0(9) . . . ? F7 F5 F9 129.9(16) 3_756 3_756 3_756 ? AS1 F6 F7 60.6(8) . . . ? AS1 F6 F8 66.9(11) . . . ? F7 F6 F8 107.9(17) 3_756 3_756 3_756 ? AS1 F7 F5 70.3(12) . . . ? AS1 F7 F6 60.6(9) . . . ? F5 F7 F6 115.2(18) 3_756 3_756 3_756 ? AS1 F8 F4 68.5(10) . . . ? AS1 F8 F6 70.7(12) . . . ? F4 F8 F6 135.8(20) . . . ? AS1 F9 F4 66.0(10) . . . ? AS1 F9 F5 65.4(9) . . . ? F4 F9 F5 112.2(16) . . . ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_1 _geom_bond_site_symmetry_2 _geom_bond_publ_flag I1 I2 2.6026(9) . . ? I1 S5 2.827(2) . . ? AS1 F4 1.721(7) . . ? AS1 F4 1.721(7) . . ? AS1 F5 1.708(7) . . ? AS1 F5 1.708(7) . . ? AS1 F6 1.698(7) . . ? AS1 F6 1.698(7) . . ? AS1 F7 1.70(2) . . ? AS1 F7 1.70(2) . . ? AS1 F8 1.65(2) . . ? AS1 F8 1.65(2) . . ? AS1 F9 1.69(2) . . ? AS1 F9 1.69(2) . . ? AS2 F1 1.706(6) . . ? AS2 F1 1.706(6) . . ? AS2 F2 1.703(6) . . ? AS2 F2 1.703(6) . . ? AS2 F3 1.702(6) . . ? AS2 F3 1.702(6) . . ? S5 S5 1.842(4) . . ? F4 F8 1.38(3) . . ? F4 F9 1.45(3) . . ? F5 F7 1.17(3) . . ? F5 F9 1.45(3) . . ? F6 F7 1.67(3) . . ? F6 F8 1.21(3) . . ? loop_ _geom_contact_atom_site_label_1 _geom_contact_atom_site_label_2 _geom_contact_distance _geom_contact_site_symmetry_1 _geom_contact_site_symmetry_2 _geom_contact_publ_flag I1 F3 3.137(8) . 2_756 no I1 F9 3.18(3) . . no I1 F6 3.246(8) . 3_756 no I1 F1 3.275(8) . 2_756 no I1 F9 3.33(2) . 7_656 no I1 F5 3.361(8) . . no I1 F3 3.378(6) . 8_454 no I1 F2 3.466(6) . 5_445 no I1 F8 3.50(3) . 3_756 no I2 F4 2.964(9) . 1_455 no I2 F7 3.06(2) . 1_455 no I2 F8 3.32(3) . 1_455 no I2 F5 3.371(9) . 3_656 no I2 F4 3.392(7) . 7_656 no I2 F1 3.512(6) . 1_455 no S5 F8 2.95(2) . 8_455 no S5 F1 3.041(7) . 2_756 no S5 F2 3.094(7) . 2_756 no S5 F5 3.174(8) . 7_656 no S5 F7 3.27(2) . 5_455 no S5 F6 3.306(9) . 8_455 no S5 F4 3.449(8) . 8_455 no S5 F3 3.476(7) . 2_756 no S5 F8 3.57(3) . 7_656 no S5 F6 3.586(8) . 7_656 no F1 F7 3.08(3) . . no F1 F4 3.147(12) . . no F1 F6 3.217(12) . 3_756 no F1 F9 3.26(3) . . no F1 F6 3.524(12) . 4 no F2 F8 3.39(2) . 7_756 no F3 F9 3.00(2) . 2_756 no F3 F5 3.088(10) . 8 no loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag I1 S5 S5 I1 . . . . 90.51(11) no I2 I1 S5 S5 . . . . -1.62(9) no AS1 F4 F8 F6 . . . . 23.7(23) no AS1 F4 F9 F5 . . . . -47.6(10) no AS1 F4 F8 F6 . . . . -23.7(23) no AS1 F4 F9 F5 . . . . 47.6(10) no AS1 F5 F7 F6 . . . . -41.8(11) no AS1 F5 F9 F4 . . . . 47.9(11) no AS1 F5 F7 F6 . . . . 41.8(11) no AS1 F5 F9 F4 . . . . -47.9(11) no AS1 F6 F7 F5 . . . . 46.1(13) no AS1 F6 F8 F4 . . . . -23.4(23) no AS1 F6 F7 F5 . . . . -46.1(13) no AS1 F6 F8 F4 . . . . 23.4(23) no AS1 F7 F5 F9 . . . . -22.4(20) no AS1 F7 F6 F8 . . . . 49.0(14) no AS1 F7 F5 F9 . . . . 22.4(20) no AS1 F7 F6 F8 . . . . -49.0(14) no AS1 F8 F4 F9 . . . . -41.3(13) no AS1 F8 F6 F7 . . . . 45.7(12) no AS1 F8 F4 F9 . . . . 41.3(13) no AS1 F8 F6 F7 . . . . -45.7(12) no AS1 F9 F4 F8 . . . . 41.2(14) no AS1 F9 F5 F7 . . . . -23.4(21) no AS1 F9 F4 F8 . . . . -41.2(14) no AS1 F9 F5 F7 . . . . 23.4(21) no F4 AS1 F4 F8 . . . . 23.4(21) no F4 AS1 F4 F9 . . . . 23.4(21) no F4 AS1 F5 F7 . . . . 125.6(13) no F4 AS1 F5 F9 . . . . -35.4(12) no F4 AS1 F5 F7 . . . . 54.4(13) no F4 AS1 F5 F9 . . . . -144.6(12) no F4 AS1 F6 F7 . . . . -115.9(12) no F4 AS1 F6 F8 . . . . 12.8(14) no F4 AS1 F6 F7 . . . . -64.1(12) no F4 AS1 F6 F8 . . . . 167.2(14) no F4 AS1 F7 F5 . . . . -119.1(13) no F4 AS1 F7 F6 . . . . 104.7(10) no F4 AS1 F7 F5 . . . . -60.9(13) no F4 AS1 F7 F6 . . . . 75.3(10) no F4 AS1 F8 F6 . . . . -162.7(19) no F4 AS1 F8 F6 . . . . -17.3(19) no F4 AS1 F9 F5 . . . . 131.3(14) no F4 AS1 F9 F5 . . . . 48.7(14) no F4 F8 AS1 F5 . . . . 81.5(10) no F4 F8 AS1 F5 . . . . -98.5(10) no F4 F8 AS1 F6 . . . . 162.7(19) no F4 F8 AS1 F6 . . . . -17.3(19) no F4 F8 AS1 F7 . . . . -59.2(14) no F4 F8 AS1 F7 . . . . 120.8(14) no F4 F8 AS1 F8 . . . . 120.8(14) no F4 F8 AS1 F9 . . . . 31.5(14) no F4 F8 AS1 F9 . . . . -148.5(14) no F4 F8 F6 F7 . . . . 22.3(32) no F4 F9 AS1 F5 . . . . -131.3(14) no F4 F9 AS1 F5 . . . . 48.7(14) no F4 F9 AS1 F6 . . . . -64.8(13) no F4 F9 AS1 F6 . . . . 115.2(13) no F4 F9 AS1 F7 . . . . 60.9(12) no F4 F9 AS1 F7 . . . . -119.1(12) no F4 F9 AS1 F8 . . . . -30.3(14) no F4 F9 AS1 F8 . . . . 149.7(14) no F4 F9 AS1 F9 . . . . 149.7(14) no F4 F9 F5 F7 . . . . 24.5(27) no F5 AS1 F4 F8 . . . . -101.8(13) no F5 AS1 F4 F9 . . . . 35.5(13) no F5 AS1 F4 F8 . . . . -78.2(13) no F5 AS1 F4 F9 . . . . 144.5(13) no F5 AS1 F5 F7 . . . . 144.5(13) no F5 AS1 F5 F9 . . . . 144.5(13) no F5 AS1 F6 F7 . . . . -26.6(11) no F5 AS1 F6 F8 . . . . 102.1(14) no F5 AS1 F6 F7 . . . . -153.4(11) no F5 AS1 F6 F8 . . . . 77.9(14) no F5 AS1 F7 F6 . . . . 43.9(15) no F5 AS1 F7 F6 . . . . 136.1(15) no F5 AS1 F8 F6 . . . . -81.2(12) no F5 AS1 F8 F6 . . . . -98.8(12) no F5 F7 AS1 F6 . . . . -136.1(15) no F5 F7 AS1 F6 . . . . 43.9(15) no F5 F7 AS1 F7 . . . . 43.9(15) no F5 F7 AS1 F8 . . . . -104.3(15) no F5 F7 AS1 F8 . . . . 75.7(15) no F5 F7 AS1 F9 . . . . -14.6(14) no F5 F7 AS1 F9 . . . . 165.4(14) no F5 F7 F6 F8 . . . . -2.9(22) no F5 F9 AS1 F6 . . . . 66.5(12) no F5 F9 AS1 F6 . . . . -113.5(12) no F5 F9 AS1 F7 . . . . -167.9(12) no F5 F9 AS1 F7 . . . . 12.1(12) no F5 F9 AS1 F8 . . . . 100.9(13) no F5 F9 AS1 F8 . . . . -79.1(13) no F5 F9 AS1 F9 . . . . -79.1(13) no F5 F9 F4 F8 . . . . -6.4(20) no F6 AS1 F4 F8 . . . . -11.6(13) no F6 AS1 F4 F9 . . . . 125.7(13) no F6 AS1 F4 F8 . . . . -168.4(13) no F6 AS1 F4 F9 . . . . 54.3(13) no F6 AS1 F5 F7 . . . . 36.4(14) no F6 AS1 F5 F9 . . . . -124.6(12) no F6 AS1 F5 F7 . . . . 143.6(14) no F6 AS1 F5 F9 . . . . -55.4(12) no F6 AS1 F6 F7 . . . . -55.4(12) no F6 AS1 F6 F8 . . . . -55.4(12) no F6 F7 AS1 F7 . . . . -55.4(12) no F6 F7 AS1 F8 . . . . 31.8(12) no F6 F7 AS1 F8 . . . . -148.2(12) no F6 F7 AS1 F9 . . . . 121.6(11) no F6 F7 AS1 F9 . . . . -58.4(11) no F6 F7 F5 F9 . . . . -19.4(27) no F6 F8 AS1 F7 . . . . 138.1(16) no F6 F8 AS1 F7 . . . . -41.9(16) no F6 F8 AS1 F8 . . . . -41.9(16) no F6 F8 AS1 F9 . . . . -131.2(15) no F6 F8 AS1 F9 . . . . 48.8(15) no F6 F8 F4 F9 . . . . -17.6(33) no F7 AS1 F4 F8 . . . . 112.6(17) no F7 AS1 F4 F9 . . . . -110.1(18) no F7 AS1 F4 F8 . . . . 67.4(17) no F7 AS1 F4 F9 . . . . -69.9(18) no F7 AS1 F5 F9 . . . . 19.0(18) no F7 AS1 F5 F9 . . . . 161.0(18) no F7 AS1 F6 F8 . . . . -51.3(18) no F7 AS1 F6 F8 . . . . -128.7(18) no F7 F5 AS1 F8 . . . . 101.8(17) no F7 F5 AS1 F8 . . . . -78.2(17) no F7 F5 AS1 F9 . . . . 19.0(18) no F7 F5 AS1 F9 . . . . -161.0(18) no F7 F6 AS1 F8 . . . . -51.3(18) no F7 F6 AS1 F8 . . . . 128.7(18) no F7 F6 AS1 F9 . . . . -108.3(17) no F7 F6 AS1 F9 . . . . 71.7(17) no F8 AS1 F4 F9 . . . . 137.3(18) no F8 AS1 F4 F9 . . . . 42.7(18) no F8 AS1 F5 F9 . . . . -82.8(17) no F8 AS1 F5 F9 . . . . -97.2(17) no F8 F4 AS1 F9 . . . . -137.3(18) no F8 F4 AS1 F9 . . . . 42.7(18) no F8 F6 AS1 F9 . . . . 57.0(19) no F8 F6 AS1 F9 . . . . -123.0(19) no