#------------------------------------------------------------------------------
#$Date: 2012-01-26 18:12:37 +0000 (Thu, 26 Jan 2012) $
#$Revision: 32063 $
#$URL: svn://www.crystallography.net/cod/cif/4/4308374.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308374
loop_
_publ_author_name
'Takashi Komuro'
'Tsukasa Matsuo'
'Hiroyuki Kawaguchi'
'Kazuyuki Tatsumi'
_publ_contact_author_email       hkawa@ims.ac.jp
_publ_contact_author_fax         +81-564-55-5245
_publ_contact_author_name        'Hiroyuki KAWAGUCHI'
_publ_contact_author_phone       +81-564-55-7290
_publ_section_title
;
Synthesis of a Vanadium(III) Tris(arylthiolato) Complex and Its Reactions
with Azide and Azo Compounds: Formation of a Sulfenamide Complex via
Cleavage of an Azo NN Bond
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              175
_journal_page_last               177
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C30 H57 N2 S2 Si4 V '
_chemical_formula_sum            'C30 H57 N2 S2 Si4 V'
_chemical_formula_weight         673.20
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             2004-06-19
_audit_creation_method           'by CrystalStructure v3.5.1'
_cell_angle_alpha                90
_cell_angle_beta                 106.141(6)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.338(4)
_cell_length_b                   19.654(7)
_cell_length_c                   21.400(9)
_cell_measurement_reflns_used    12092
_cell_measurement_temperature    173.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     3773(3)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.5.1'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.9919
_diffrn_measured_fraction_theta_max 0.9934
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.060
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            60464
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.522
_exptl_absorpt_correction_T_max  0.984
_exptl_absorpt_correction_T_min  0.863
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            reddish-brown
_exptl_crystal_density_diffrn    1.185
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1448.00
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.31
_refine_diff_density_min         -1.08
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.001
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     392
_refine_ls_number_reflns         8602
_refine_ls_R_factor_gt           0.0820
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0071Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2450
_reflns_number_gt                6399
_reflns_number_total             8863
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_[local]_cod_data_source_file    ic048721csi20041021_032116_2.cif
_[local]_cod_data_source_block
'_V{SC6H3(CH2SiMe2)(SiMe3)}{SC6H3(SiMe3)2}(tmeda)'
_[local]_cod_chemical_formula_sum_orig 'C30 H57 N2 S2 Si4 V '
_cod_original_cell_volume        3772.7(26)
_cod_database_code               4308374
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
-x,y+1/2,-z+1/2
x,-y+1/2,z+1/2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
V(1) V 0.96701(8) 0.20716(3) -0.02057(3) 0.0224(2) Uani 1.00 1 d . . .
S(1) S 0.73620(11) 0.25845(5) -0.02535(5) 0.0257(3) Uani 1.00 1 d . . .
S(2) S 1.03775(12) 0.21328(5) 0.09507(5) 0.0255(3) Uani 1.00 1 d . . .
Si(1) Si 0.6839(1) 0.11184(6) -0.10925(6) 0.0293(3) Uani 1.00 1 d . . .
Si(2) Si 0.5520(2) 0.40154(7) -0.08730(7) 0.0333(4) Uani 1.00 1 d . . .
Si(3) Si 0.8573(2) 0.10940(7) 0.17164(7) 0.0363(4) Uani 1.00 1 d . . .
Si(4) Si 1.0344(3) 0.3851(1) 0.1461(2) 0.0308(6) Uiso 0.50 1 d P . .
Si(5) Si 1.0081(3) 0.38474(13) 0.1187(2) 0.0289(6) Uiso 0.50 1 d P . .
N(1) N 1.2107(4) 0.1760(2) -0.0053(2) 0.0285(10) Uani 1.00 1 d . . .
N(2) N 1.0114(5) 0.2532(2) -0.1096(2) 0.0408(12) Uani 1.00 1 d . . .
C(1) C 0.6161(5) 0.2571(2) -0.1064(2) 0.0258(11) Uani 1.00 1 d . . .
C(2) C 0.5934(5) 0.1951(2) -0.1418(2) 0.0255(10) Uani 1.00 1 d . . .
C(3) C 0.4927(5) 0.1966(3) -0.2041(2) 0.0344(13) Uani 1.00 1 d . . .
C(4) C 0.4193(6) 0.2552(3) -0.2309(2) 0.040(1) Uani 1.00 1 d . . .
C(5) C 0.4435(5) 0.3153(3) -0.1950(2) 0.0375(13) Uani 1.00 1 d . . .
C(6) C 0.5408(5) 0.3177(2) -0.1325(2) 0.0297(11) Uani 1.00 1 d . . .
C(7) C 0.8842(5) 0.1149(2) -0.0613(2) 0.0287(11) Uani 1.00 1 d . . .
C(8) C 0.6673(7) 0.0535(4) -0.1809(3) 0.063(2) Uani 1.00 1 d . . .
C(9) C 0.5694(6) 0.0743(3) -0.0580(4) 0.055(2) Uani 1.00 1 d . . .
C(10) C 0.4709(8) 0.3930(3) -0.0176(3) 0.055(2) Uani 1.00 1 d . . .
C(11) C 0.4444(10) 0.4661(3) -0.1451(3) 0.076(2) Uani 1.00 1 d . . .
C(12) C 0.7419(7) 0.4374(3) -0.0577(5) 0.083(3) Uani 1.00 1 d . . .
C(13) C 0.8946(5) 0.2471(2) 0.1270(2) 0.0240(10) Uani 1.00 1 d . . .
C(14) C 0.8050(5) 0.2009(2) 0.1498(2) 0.0289(11) Uani 1.00 1 d . . .
C(15) C 0.6785(6) 0.2283(3) 0.1648(2) 0.038(1) Uani 1.00 1 d . . .
C(16) C 0.6482(6) 0.2968(3) 0.1606(3) 0.041(1) Uani 1.00 1 d . . .
C(17) C 0.7479(6) 0.3409(3) 0.1467(2) 0.040(1) Uani 1.00 1 d . . .
C(18) C 0.8758(5) 0.3177(2) 0.1307(2) 0.0315(12) Uani 1.00 1 d . . .
C(19) C 1.0550(7) 0.1047(3) 0.2231(3) 0.048(2) Uani 1.00 1 d . . .
C(20) C 0.8379(9) 0.0481(3) 0.1034(3) 0.066(2) Uani 1.00 1 d . . .
C(21) C 0.7323(8) 0.0784(3) 0.2208(3) 0.062(2) Uani 1.00 1 d . . .
C(22) C 0.9357(8) 0.4725(4) 0.1230(3) 0.066(2) Uiso 1.00 1 d . . .
C(23) C 1.181(2) 0.3745(8) 0.1007(7) 0.070(4) Uiso 0.50 1 d P . .
C(24) C 1.094(1) 0.3801(6) 0.0510(6) 0.053(3) Uiso 0.50 1 d P . .
C(25) C 1.130(1) 0.3852(6) 0.2344(6) 0.050(3) Uiso 0.50 1 d P . .
C(26) C 1.167(2) 0.3786(7) 0.1968(7) 0.062(3) Uiso 0.50 1 d P . .
C(27) C 1.2393(6) 0.1059(3) 0.0184(3) 0.041(1) Uani 1.00 1 d . . .
C(28) C 1.3248(5) 0.2198(3) 0.0395(3) 0.041(1) Uani 1.00 1 d . . .
C(29) C 1.2320(5) 0.1799(3) -0.0716(3) 0.0375(13) Uani 1.00 1 d . . .
C(30) C 1.1729(6) 0.2472(3) -0.1027(3) 0.040(1) Uani 1.00 1 d . . .
C(31) C 0.9698(9) 0.3259(4) -0.1151(4) 0.079(3) Uani 1.00 1 d . . .
C(32) C 0.9306(7) 0.2192(4) -0.1709(3) 0.063(2) Uani 1.00 1 d . . .
H(1) H 0.4736 0.1549 -0.2293 0.041 Uiso 1.00 1 c . . .
H(2) H 0.3516 0.2548 -0.2745 0.046 Uiso 1.00 1 c . . .
H(3) H 0.3915 0.3565 -0.2137 0.045 Uiso 1.00 1 c . . .
H(4) H 0.9434 0.1009 -0.0898 0.036 Uiso 1.00 1 c . . .
H(5) H 0.8973 0.0825 -0.0260 0.036 Uiso 1.00 1 c . . .
H(6) H 0.7279 0.0713 -0.2073 0.071 Uiso 1.00 1 c . . .
H(7) H 0.7020 0.0084 -0.1655 0.071 Uiso 1.00 1 c . . .
H(8) H 0.5641 0.0511 -0.2067 0.071 Uiso 1.00 1 c . . .
H(9) H 0.6121 0.0311 -0.0401 0.068 Uiso 1.00 1 c . . .
H(10) H 0.5689 0.1053 -0.0227 0.068 Uiso 1.00 1 c . . .
H(11) H 0.4681 0.0672 -0.0847 0.068 Uiso 1.00 1 c . . .
H(12) H 0.3710 0.3744 -0.0325 0.072 Uiso 1.00 1 c . . .
H(13) H 0.5330 0.3629 0.0146 0.072 Uiso 1.00 1 c . . .
H(14) H 0.4670 0.4375 0.0016 0.072 Uiso 1.00 1 c . . .
H(15) H 0.3424 0.4504 -0.1619 0.091 Uiso 1.00 1 c . . .
H(16) H 0.4453 0.5090 -0.1226 0.091 Uiso 1.00 1 c . . .
H(17) H 0.4884 0.4723 -0.1807 0.091 Uiso 1.00 1 c . . .
H(18) H 0.7380 0.4806 -0.0365 0.103 Uiso 1.00 1 c . . .
H(19) H 0.8050 0.4061 -0.0271 0.102 Uiso 1.00 1 c . . .
H(20) H 0.7824 0.4441 -0.0944 0.103 Uiso 1.00 1 c . . .
H(21) H 0.6122 0.1976 0.1790 0.046 Uiso 1.00 1 c . . .
H(22) H 0.5570 0.3140 0.1681 0.050 Uiso 1.00 1 c . . .
H(23) H 0.7298 0.3895 0.1475 0.049 Uiso 1.00 1 c . . .
H(24) H 1.1215 0.1165 0.1971 0.057 Uiso 1.00 1 c . . .
H(25) H 1.0699 0.1361 0.2594 0.057 Uiso 1.00 1 c . . .
H(26) H 1.0760 0.0587 0.2396 0.057 Uiso 1.00 1 c . . .
H(27) H 0.9063 0.0605 0.0785 0.080 Uiso 1.00 1 c . . .
H(28) H 0.8615 0.0027 0.1211 0.080 Uiso 1.00 1 c . . .
H(29) H 0.7366 0.0489 0.0753 0.080 Uiso 1.00 1 c . . .
H(30) H 0.7639 0.0334 0.2377 0.077 Uiso 1.00 1 c . . .
H(31) H 0.7382 0.1095 0.2566 0.077 Uiso 1.00 1 c . . .
H(32) H 0.6304 0.0764 0.1934 0.077 Uiso 1.00 1 c . . .
H(33) H 1.3392 0.0922 0.0185 0.049 Uiso 1.00 1 c . . .
H(34) H 1.2295 0.1033 0.0623 0.049 Uiso 1.00 1 c . . .
H(35) H 1.1672 0.0758 -0.0097 0.049 Uiso 1.00 1 c . . .
H(36) H 1.3105 0.2667 0.0249 0.049 Uiso 1.00 1 c . . .
H(37) H 1.3134 0.2165 0.0831 0.049 Uiso 1.00 1 c . . .
H(38) H 1.4240 0.2049 0.0398 0.049 Uiso 1.00 1 c . . .
H(39) H 1.3373 0.1761 -0.0687 0.047 Uiso 1.00 1 c . . .
H(40) H 1.1779 0.1433 -0.0984 0.047 Uiso 1.00 1 c . . .
H(41) H 1.1905 0.2508 -0.1451 0.049 Uiso 1.00 1 c . . .
H(42) H 1.2246 0.2837 -0.0750 0.049 Uiso 1.00 1 c . . .
H(43) H 0.8641 0.3308 -0.1195 0.103 Uiso 1.00 1 c . . .
H(44) H 1.0264 0.3486 -0.0757 0.104 Uiso 1.00 1 c . . .
H(45) H 0.9931 0.3460 -0.1524 0.103 Uiso 1.00 1 c . . .
H(46) H 0.9599 0.1717 -0.1693 0.076 Uiso 1.00 1 c . . .
H(47) H 0.8241 0.2222 -0.1764 0.076 Uiso 1.00 1 c . . .
H(48) H 0.9547 0.2413 -0.2072 0.076 Uiso 1.00 1 c . . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
V(1) 0.0209(4) 0.0198(4) 0.0276(4) 0.0015(3) 0.0087(3) 0.0012(3)
S(1) 0.0224(5) 0.0244(5) 0.0295(6) 0.0049(4) 0.0058(4) -0.0015(4)
S(2) 0.0241(5) 0.0238(5) 0.0285(6) 0.0036(4) 0.0070(4) -0.0003(4)
Si(1) 0.0273(6) 0.0237(6) 0.0377(7) 0.0008(5) 0.0103(5) -0.0050(5)
Si(2) 0.0316(7) 0.0245(6) 0.0474(8) 0.0083(5) 0.0172(6) 0.0072(5)
Si(3) 0.0477(8) 0.0296(7) 0.0323(7) -0.0095(6) 0.0122(6) -0.0009(5)
N(1) 0.023(2) 0.027(2) 0.037(2) 0.005(2) 0.010(2) -0.001(2)
N(2) 0.032(2) 0.048(3) 0.049(3) 0.011(2) 0.024(2) 0.022(2)
C(1) 0.021(2) 0.031(2) 0.027(2) 0.003(2) 0.010(2) 0.007(2)
C(2) 0.018(2) 0.030(2) 0.029(2) 0.001(2) 0.007(2) -0.001(2)
C(3) 0.031(2) 0.040(3) 0.033(3) -0.003(2) 0.010(2) -0.004(2)
C(4) 0.031(3) 0.054(3) 0.030(3) 0.009(2) 0.001(2) 0.007(2)
C(5) 0.030(2) 0.053(3) 0.030(3) 0.012(2) 0.009(2) 0.014(2)
C(6) 0.029(2) 0.030(2) 0.033(2) 0.007(2) 0.013(2) 0.007(2)
C(7) 0.030(2) 0.024(2) 0.035(2) 0.002(2) 0.014(2) 0.001(2)
C(8) 0.052(4) 0.060(4) 0.065(4) 0.015(3) -0.002(3) -0.030(3)
C(9) 0.036(3) 0.037(3) 0.098(5) 0.007(2) 0.030(3) 0.018(3)
C(10) 0.087(5) 0.034(3) 0.058(4) -0.001(3) 0.046(4) -0.008(3)
C(11) 0.123(7) 0.047(4) 0.059(4) 0.043(4) 0.025(4) 0.016(3)
C(12) 0.045(4) 0.028(3) 0.183(9) -0.004(3) 0.042(5) -0.021(4)
C(13) 0.022(2) 0.025(2) 0.025(2) -0.002(2) 0.006(2) -0.002(2)
C(14) 0.028(2) 0.034(2) 0.024(2) -0.006(2) 0.006(2) -0.002(2)
C(15) 0.029(2) 0.055(3) 0.032(3) -0.003(2) 0.011(2) 0.004(2)
C(16) 0.027(2) 0.062(4) 0.036(3) 0.008(2) 0.014(2) -0.003(2)
C(17) 0.041(3) 0.038(3) 0.042(3) 0.014(2) 0.014(2) -0.001(2)
C(18) 0.034(2) 0.030(2) 0.031(2) 0.003(2) 0.010(2) 0.003(2)
C(19) 0.055(4) 0.049(3) 0.038(3) 0.014(3) 0.010(3) 0.007(2)
C(20) 0.107(6) 0.038(3) 0.054(4) -0.021(4) 0.026(4) -0.011(3)
C(21) 0.075(5) 0.058(4) 0.060(4) -0.015(3) 0.031(3) 0.017(3)
C(27) 0.036(3) 0.035(3) 0.052(3) 0.018(2) 0.015(2) 0.005(2)
C(28) 0.022(2) 0.053(3) 0.048(3) -0.005(2) 0.007(2) -0.010(2)
C(29) 0.026(2) 0.046(3) 0.044(3) 0.007(2) 0.016(2) 0.000(2)
C(30) 0.031(3) 0.044(3) 0.048(3) 0.004(2) 0.018(2) 0.012(2)
C(31) 0.079(5) 0.058(4) 0.122(7) 0.031(4) 0.065(5) 0.056(4)
C(32) 0.036(3) 0.117(6) 0.038(3) -0.009(3) 0.014(2) 0.024(3)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.000 0.000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
N N 0.006 0.003
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Si Si 0.082 0.070
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
S S 0.125 0.123
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
V V 0.300 0.529
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
S(1) V(1) S(2) 90.55(4) yes . . .
S(1) V(1) N(1) 168.9(1) yes . . .
S(1) V(1) N(2) 100.0(1) yes . . .
S(1) V(1) C(7) 97.3(1) yes . . .
S(2) V(1) N(1) 83.5(1) yes . . .
S(2) V(1) N(2) 142.9(1) yes . . .
S(2) V(1) C(7) 116.5(1) yes . . .
N(1) V(1) N(2) 79.6(1) yes . . .
N(1) V(1) C(7) 93.8(2) yes . . .
N(2) V(1) C(7) 97.5(2) yes . . .
C(1) S(1) V(1) 110.9(2) yes . . .
C(13) S(2) V(1) 113.3(1) yes . . .
C(2) Si(1) C(7) 116.9(2) yes . . .
C(2) Si(1) C(8) 107.5(2) yes . . .
C(2) Si(1) C(9) 106.7(2) yes . . .
C(7) Si(1) C(8) 108.1(3) yes . . .
C(7) Si(1) C(9) 109.7(2) yes . . .
C(8) Si(1) C(9) 107.7(3) yes . . .
C(6) Si(2) C(10) 110.7(2) yes . . .
C(6) Si(2) C(11) 108.1(2) yes . . .
C(6) Si(2) C(12) 114.6(3) yes . . .
C(10) Si(2) C(11) 109.3(3) yes . . .
C(10) Si(2) C(12) 109.0(4) yes . . .
C(11) Si(2) C(12) 104.9(3) yes . . .
C(14) Si(3) C(19) 109.8(2) yes . . .
C(14) Si(3) C(20) 117.4(2) yes . . .
C(14) Si(3) C(21) 106.8(3) yes . . .
C(19) Si(3) C(20) 107.1(3) yes . . .
C(19) Si(3) C(21) 108.6(3) yes . . .
C(20) Si(3) C(21) 106.8(3) yes . . .
Si(5) Si(4) C(18) 74.2(4) yes . . .
Si(5) Si(4) C(22) 73.1(4) yes . . .
Si(5) Si(4) C(23) 68.9(6) yes . . .
Si(5) Si(4) C(24) 38.2(5) yes . . .
Si(5) Si(4) C(25) 177.1(7) yes . . .
Si(5) Si(4) C(26) 146.0(9) yes . . .
C(18) Si(4) C(22) 105.9(3) yes . . .
C(18) Si(4) C(23) 117.6(5) yes . . .
C(18) Si(4) C(24) 100.6(4) yes . . .
C(18) Si(4) C(25) 107.4(5) yes . . .
C(18) Si(4) C(26) 122.3(6) yes . . .
C(22) Si(4) C(23) 109.0(6) yes . . .
C(22) Si(4) C(24) 91.5(4) yes . . .
C(22) Si(4) C(25) 108.5(5) yes . . .
C(22) Si(4) C(26) 121.9(6) yes . . .
C(23) Si(4) C(24) 30.8(5) yes . . .
C(23) Si(4) C(25) 108.2(6) yes . . .
C(23) Si(4) C(26) 77.2(8) yes . . .
C(24) Si(4) C(25) 138.9(5) yes . . .
C(24) Si(4) C(26) 107.9(8) yes . . .
C(25) Si(4) C(26) 31.1(8) yes . . .
C(18) Si(5) C(22) 112.5(3) yes . . .
C(18) Si(5) C(23) 128.7(6) yes . . .
C(18) Si(5) C(24) 121.3(4) yes . . .
C(18) Si(5) C(26) 102.6(5) yes . . .
C(18) Si(5) Si(4) 88.8(5) yes . . .
C(22) Si(5) C(23) 118.7(6) yes . . .
C(22) Si(5) C(24) 109.1(5) yes . . .
C(22) Si(5) C(26) 102.7(5) yes . . .
C(22) Si(5) Si(4) 89.9(5) yes . . .
C(23) Si(5) C(24) 37.1(6) yes . . .
C(23) Si(5) C(26) 69.4(7) yes . . .
C(23) Si(5) Si(4) 93.7(6) yes . . .
C(24) Si(5) C(26) 106.5(6) yes . . .
C(24) Si(5) Si(4) 130.8(6) yes . . .
C(26) Si(5) Si(4) 24.4(6) yes . . .
C(27) N(1) C(28) 106.9(3) yes . . .
C(27) N(1) C(29) 108.6(4) yes . . .
C(27) N(1) V(1) 112.3(3) yes . . .
C(28) N(1) C(29) 108.7(4) yes . . .
C(28) N(1) V(1) 116.1(3) yes . . .
C(29) N(1) V(1) 103.9(2) yes . . .
C(30) N(2) C(31) 108.9(5) yes . . .
C(30) N(2) C(32) 107.9(5) yes . . .
C(30) N(2) V(1) 107.8(3) yes . . .
C(31) N(2) C(32) 108.0(5) yes . . .
C(31) N(2) V(1) 110.5(5) yes . . .
C(32) N(2) V(1) 113.6(4) yes . . .
C(2) C(1) C(6) 121.8(4) yes . . .
C(2) C(1) S(1) 119.5(3) yes . . .
C(6) C(1) S(1) 118.7(3) yes . . .
C(3) C(2) Si(1) 118.9(3) yes . . .
C(3) C(2) C(1) 116.8(4) yes . . .
Si(1) C(2) C(1) 124.3(3) yes . . .
C(4) C(3) C(2) 122.5(4) yes . . .
C(5) C(4) C(3) 119.5(4) yes . . .
C(6) C(5) C(4) 121.3(5) yes . . .
Si(2) C(6) C(1) 125.3(3) yes . . .
Si(2) C(6) C(5) 116.5(4) yes . . .
C(1) C(6) C(5) 118.1(4) yes . . .
V(1) C(7) Si(1) 117.4(2) yes . . .
C(14) C(13) C(18) 121.5(4) yes . . .
C(14) C(13) S(2) 118.0(3) yes . . .
C(18) C(13) S(2) 120.4(4) yes . . .
C(15) C(14) Si(3) 118.8(4) yes . . .
C(15) C(14) C(13) 116.5(4) yes . . .
Si(3) C(14) C(13) 124.2(4) yes . . .
C(16) C(15) C(14) 121.9(5) yes . . .
C(17) C(16) C(15) 119.8(5) yes . . .
C(18) C(17) C(16) 121.6(5) yes . . .
Si(4) C(18) C(13) 125.6(4) yes . . .
Si(4) C(18) C(17) 113.3(4) yes . . .
Si(5) C(18) Si(4) 17.0(2) yes . . .
Si(5) C(18) C(13) 126.2(4) yes . . .
Si(5) C(18) C(17) 116.2(4) yes . . .
C(13) C(18) C(17) 117.5(5) yes . . .
Si(5) C(22) Si(4) 17.0(2) yes . . .
C(24) C(23) Si(4) 91(1) yes . . .
Si(5) C(23) C(24) 74(1) yes . . .
Si(5) C(23) Si(4) 17.4(2) yes . . .
Si(5) C(24) Si(4) 11.0(1) yes . . .
Si(5) C(24) C(23) 68(1) yes . . .
C(23) C(24) Si(4) 57(1) yes . . .
C(26) C(25) Si(4) 48.4(9) yes . . .
Si(5) C(26) Si(4) 9.6(3) yes . . .
Si(5) C(26) C(25) 110(1) yes . . .
C(25) C(26) Si(4) 100(1) yes . . .
C(30) C(29) N(1) 109.6(4) yes . . .
N(2) C(30) C(29) 110.5(4) yes . . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
V(1) S(1) 2.356(1) yes . .
V(1) S(2) 2.380(1) yes . .
V(1) N(1) 2.291(4) yes . .
V(1) N(2) 2.249(5) yes . .
V(1) C(7) 2.066(4) yes . .
S(1) C(1) 1.784(4) yes . .
S(2) C(13) 1.791(5) yes . .
Si(1) C(2) 1.885(4) yes . .
Si(1) C(7) 1.868(4) yes . .
Si(1) C(8) 1.886(7) yes . .
Si(1) C(9) 1.883(8) yes . .
Si(2) C(6) 1.899(5) yes . .
Si(2) C(10) 1.858(8) yes . .
Si(2) C(11) 1.859(7) yes . .
Si(2) C(12) 1.849(6) yes . .
Si(3) C(14) 1.887(5) yes . .
Si(3) C(19) 1.871(5) yes . .
Si(3) C(20) 1.864(7) yes . .
Si(3) C(21) 1.876(8) yes . .
Si(4) Si(5) 0.569(5) yes . .
Si(4) C(18) 1.945(6) yes . .
Si(4) C(22) 1.948(8) yes . .
Si(4) C(23) 1.90(2) yes . .
Si(4) C(24) 2.25(1) yes . .
Si(4) C(25) 1.85(1) yes . .
Si(4) C(26) 1.41(1) yes . .
Si(5) C(18) 1.872(6) yes . .
Si(5) C(22) 1.864(8) yes . .
Si(5) C(23) 1.78(2) yes . .
Si(5) C(24) 1.84(2) yes . .
Si(5) C(26) 1.91(1) yes . .
N(1) C(27) 1.467(6) yes . .
N(1) C(28) 1.493(6) yes . .
N(1) C(29) 1.490(7) yes . .
N(2) C(30) 1.479(7) yes . .
N(2) C(31) 1.477(8) yes . .
N(2) C(32) 1.479(7) yes . .
C(1) C(2) 1.419(6) yes . .
C(1) C(6) 1.416(6) yes . .
C(2) C(3) 1.403(6) yes . .
C(3) C(4) 1.379(7) yes . .
C(4) C(5) 1.394(8) yes . .
C(5) C(6) 1.394(6) yes . .
C(13) C(14) 1.411(7) yes . .
C(13) C(18) 1.402(6) yes . .
C(14) C(15) 1.414(8) yes . .
C(15) C(16) 1.375(8) yes . .
C(16) C(17) 1.363(8) yes . .
C(17) C(18) 1.408(8) yes . .
C(23) C(24) 1.15(2) yes . .
C(25) C(26) 0.97(2) yes . .
C(29) C(30) 1.513(7) yes . .
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_publ_flag
_geom_contact_site_symmetry_1
_geom_contact_site_symmetry_2
V(1) S(1) 2.356(1) yes . 55501
V(1) S(2) 2.380(1) yes . 55501
V(1) Si(1) 3.363(1) yes . 55501
V(1) N(1) 2.291(4) yes . 55501
V(1) N(2) 2.249(5) yes . 55501
V(1) C(1) 3.425(4) yes . 55501
V(1) C(7) 2.066(4) yes . 55501
V(1) C(13) 3.499(5) yes . 55501
V(1) C(27) 3.153(5) yes . 55501
V(1) C(28) 3.238(5) yes . 55501
V(1) C(29) 3.018(6) yes . 55501
V(1) C(30) 3.047(6) yes . 55501
V(1) C(31) 3.092(8) yes . 55501
V(1) C(32) 3.148(6) yes . 55501
S(1) V(1) 2.356(1) yes . 55501
S(1) S(2) 3.365(1) yes . 55501
S(1) Si(1) 3.358(2) yes . 55501
S(1) Si(2) 3.370(2) yes . 55501
S(1) N(2) 3.527(5) yes . 55501
S(1) C(2) 2.773(4) yes . 55501
S(1) C(6) 2.759(4) yes . 55501
S(1) C(7) 3.324(5) yes . 55501
S(1) C(12) 3.587(6) yes . 55501
S(1) C(13) 3.192(4) yes . 55501
S(1) C(18) 3.433(5) yes . 55501
S(1) C(31) 3.540(9) yes . 55501
S(2) V(1) 2.380(1) yes . 55501
S(2) S(1) 3.365(1) yes . 55501
S(2) Si(3) 3.351(2) yes . 55501
S(2) Si(4) 3.551(3) yes . 55501
S(2) Si(5) 3.430(3) yes . 55501
S(2) N(1) 3.112(4) yes . 55501
S(2) C(13) 1.791(5) yes . 55501
S(2) C(14) 2.752(5) yes . 55501
S(2) C(18) 2.778(5) yes . 55501
S(2) C(19) 3.442(6) yes . 55501
S(2) C(23) 3.43(2) yes . 55501
S(2) C(24) 3.49(1) yes . 55501
S(2) C(27) 3.522(6) yes . 55501
S(2) C(28) 3.223(6) yes . 55501
Si(1) V(1) 3.363(1) yes . 55501
Si(1) S(1) 3.358(2) yes . 55501
Si(1) C(1) 2.929(4) yes . 55501
Si(1) C(2) 1.885(4) yes . 55501
Si(1) C(3) 2.841(5) yes . 55501
Si(1) C(8) 1.886(7) yes . 55501
Si(1) C(9) 1.883(8) yes . 55501
Si(2) S(1) 3.370(2) yes . 55501
Si(2) C(1) 2.953(5) yes . 55501
Si(2) C(5) 2.813(5) yes . 55501
Si(2) C(6) 1.899(5) yes . 55501
Si(3) S(2) 3.351(2) yes . 55501
Si(3) C(13) 2.923(4) yes . 55501
Si(3) C(14) 1.887(5) yes . 55501
Si(3) C(15) 2.851(6) yes . 55501
Si(4) S(2) 3.551(3) yes . 55501
Si(4) C(13) 2.987(5) yes . 55501
Si(4) C(17) 2.817(6) yes . 55501
Si(4) C(18) 1.945(6) yes . 55501
Si(4) C(22) 1.948(8) yes . 55501
Si(4) C(23) 1.90(2) yes . 55501
Si(4) C(24) 2.25(1) yes . 55501
Si(5) S(2) 3.430(3) yes . 55501
Si(5) C(13) 2.928(5) yes . 55501
Si(5) C(17) 2.796(7) yes . 55501
Si(5) C(25) 2.42(1) yes . 55501
Si(5) C(26) 1.91(1) yes . 55501
N(1) V(1) 2.291(4) yes . 55501
N(1) S(2) 3.112(4) yes . 55501
N(1) N(2) 2.905(5) yes . 55501
N(1) C(7) 3.184(6) yes . 55501
N(1) C(30) 2.453(7) yes . 55501
N(2) V(1) 2.249(5) yes . 55501
N(2) S(1) 3.527(5) yes . 55501
N(2) N(1) 2.905(5) yes . 55501
N(2) C(7) 3.247(7) yes . 55501
N(2) C(29) 2.459(6) yes . 55501
C(1) V(1) 3.425(4) yes . 55501
C(1) Si(1) 2.929(4) yes . 55501
C(1) Si(2) 2.953(5) yes . 55501
C(1) C(3) 2.403(6) yes . 55501
C(1) C(4) 2.785(6) yes . 55501
C(1) C(5) 2.410(6) yes . 55501
C(2) S(1) 2.773(4) yes . 55501
C(2) Si(1) 1.885(4) yes . 55501
C(2) C(4) 2.439(6) yes . 55501
C(2) C(5) 2.820(7) yes . 55501
C(2) C(6) 2.477(6) yes . 55501
C(2) C(7) 3.198(6) yes . 55501
C(2) C(8) 3.040(8) yes . 55501
C(2) C(9) 3.022(8) yes . 55501
C(2) C(32) 3.408(8) yes . 55501
C(3) Si(1) 2.841(5) yes . 55501
C(3) C(1) 2.403(6) yes . 55501
C(3) C(5) 2.396(7) yes . 55501
C(3) C(6) 2.798(7) yes . 55501
C(3) C(8) 3.220(8) yes . 55501
C(4) C(1) 2.785(6) yes . 55501
C(4) C(2) 2.439(6) yes . 55501
C(4) C(6) 2.430(6) yes . 55501
C(5) Si(2) 2.813(5) yes . 55501
C(5) C(1) 2.410(6) yes . 55501
C(5) C(2) 2.820(7) yes . 55501
C(5) C(3) 2.396(7) yes . 55501
C(5) C(11) 3.149(9) yes . 55501
C(6) S(1) 2.759(4) yes . 55501
C(6) Si(2) 1.899(5) yes . 55501
C(6) C(2) 2.477(6) yes . 55501
C(6) C(3) 2.798(7) yes . 55501
C(6) C(4) 2.430(6) yes . 55501
C(6) C(10) 3.090(9) yes . 55501
C(6) C(11) 3.043(8) yes . 55501
C(6) C(12) 3.154(8) yes . 55501
C(7) V(1) 2.066(4) yes . 55501
C(7) V(1) 2.684(4) yes . 65505
C(7) S(1) 3.324(5) yes . 55501
C(7) N(1) 3.184(6) yes . 55501
C(7) N(2) 3.247(7) yes . 55501
C(7) C(2) 3.198(6) yes . 55501
C(7) C(8) 3.038(7) yes . 55501
C(7) C(9) 3.066(8) yes . 55501
C(7) C(27) 3.285(7) yes . 55501
C(7) C(29) 3.554(7) yes . 55501
C(7) C(32) 3.232(9) yes . 55501
C(8) Si(1) 1.886(7) yes . 55501
C(8) C(2) 3.040(8) yes . 55501
C(8) C(3) 3.220(8) yes . 55501
C(8) C(7) 3.038(7) yes . 55501
C(8) C(9) 3.04(1) yes . 55501
C(9) Si(1) 1.883(8) yes . 55501
C(9) C(2) 3.022(8) yes . 55501
C(9) C(7) 3.066(8) yes . 55501
C(9) C(8) 3.04(1) yes . 55501
C(10) C(6) 3.090(9) yes . 55501
C(10) C(11) 3.031(9) yes . 55501
C(10) C(12) 3.02(1) yes . 55501
C(11) C(5) 3.149(9) yes . 55501
C(11) C(6) 3.043(8) yes . 55501
C(11) C(10) 3.031(9) yes . 55501
C(11) C(12) 2.94(1) yes . 55501
C(12) S(1) 3.587(6) yes . 55501
C(12) C(6) 3.154(8) yes . 55501
C(12) C(10) 3.02(1) yes . 55501
C(12) C(11) 2.94(1) yes . 55501
C(12) C(31) 3.51(1) yes . 55501
C(13) V(1) 3.499(5) yes . 55501
C(13) S(1) 3.192(4) yes . 55501
C(13) S(2) 1.791(5) yes . 55501
C(13) Si(3) 2.923(4) yes . 55501
C(13) Si(4) 2.987(5) yes . 55501
C(13) Si(5) 2.928(5) yes . 55501
C(13) C(15) 2.402(7) yes . 55501
C(13) C(16) 2.771(7) yes . 55501
C(13) C(17) 2.403(7) yes . 55501
C(13) C(19) 3.550(7) yes . 55501
C(14) S(2) 2.752(5) yes . 55501
C(14) Si(3) 1.887(5) yes . 55501
C(14) C(16) 2.437(7) yes . 55501
C(14) C(17) 2.801(7) yes . 55501
C(14) C(18) 2.455(7) yes . 55501
C(14) C(19) 3.074(7) yes . 55501
C(14) C(20) 3.205(8) yes . 55501
C(14) C(21) 3.022(9) yes . 55501
C(15) Si(3) 2.851(6) yes . 55501
C(15) C(13) 2.402(7) yes . 55501
C(15) C(17) 2.369(8) yes . 55501
C(15) C(18) 2.787(8) yes . 55501
C(15) C(21) 3.166(9) yes . 55501
C(16) C(3) 3.584(8) yes . 55504
C(16) C(13) 2.771(7) yes . 55501
C(16) C(14) 2.437(7) yes . 55501
C(16) C(18) 2.419(8) yes . 55501
C(17) Si(4) 2.817(6) yes . 55501
C(17) Si(5) 2.796(7) yes . 55501
C(17) C(13) 2.403(7) yes . 55501
C(17) C(14) 2.801(7) yes . 55501
C(17) C(15) 2.369(8) yes . 55501
C(17) C(22) 3.24(1) yes . 55501
C(18) S(1) 3.433(5) yes . 55501
C(18) S(2) 2.778(5) yes . 55501
C(18) Si(4) 1.945(6) yes . 55501
C(18) C(14) 2.455(7) yes . 55501
C(18) C(15) 2.787(8) yes . 55501
C(18) C(16) 2.419(8) yes . 55501
C(18) C(22) 3.106(9) yes . 55501
C(18) C(23) 3.29(2) yes . 55501
C(18) C(24) 3.24(2) yes . 55501
C(18) C(25) 3.06(1) yes . 55501
C(18) C(26) 2.95(1) yes . 55501
C(19) S(2) 3.442(6) yes . 55501
C(19) C(13) 3.550(7) yes . 55501
C(19) C(14) 3.074(7) yes . 55501
C(19) C(20) 3.004(8) yes . 55501
C(19) C(21) 3.04(1) yes . 55501
C(20) V(1) 3.153(8) yes . 65505
C(20) C(14) 3.205(8) yes . 55501
C(20) C(19) 3.004(8) yes . 55501
C(20) C(21) 3.00(1) yes . 55501
C(21) C(14) 3.022(9) yes . 55501
C(21) C(15) 3.166(9) yes . 55501
C(21) C(19) 3.04(1) yes . 55501
C(21) C(20) 3.00(1) yes . 55501
C(22) Si(4) 1.948(8) yes . 55501
C(22) C(17) 3.24(1) yes . 55501
C(22) C(18) 3.106(9) yes . 55501
C(22) C(23) 3.13(2) yes . 55501
C(22) C(24) 3.02(2) yes . 55501
C(22) C(25) 3.08(1) yes . 55501
C(22) C(26) 2.95(2) yes . 55501
C(23) S(2) 3.43(2) yes . 55501
C(23) Si(4) 1.90(2) yes . 55501
C(23) C(18) 3.29(2) yes . 55501
C(23) C(22) 3.13(2) yes . 55501
C(23) C(25) 3.04(2) yes . 55501
C(23) C(26) 2.10(2) yes . 55501
C(24) S(2) 3.49(1) yes . 55501
C(24) Si(4) 2.25(1) yes . 55501
C(24) C(18) 3.24(2) yes . 55501
C(24) C(22) 3.02(2) yes . 55501
C(24) C(26) 3.00(2) yes . 55501
C(24) C(31) 3.58(1) yes . 55501
C(25) Si(5) 2.42(1) yes . 55501
C(25) C(18) 3.06(1) yes . 55501
C(25) C(22) 3.08(1) yes . 55501
C(25) C(23) 3.04(2) yes . 55501
C(26) Si(5) 1.91(1) yes . 55501
C(26) C(3) 3.51(1) yes . 65504
C(26) C(4) 3.58(1) yes . 65504
C(26) C(18) 2.95(1) yes . 55501
C(26) C(22) 2.95(2) yes . 55501
C(26) C(23) 2.10(2) yes . 55501
C(26) C(24) 3.00(2) yes . 55501
C(27) V(1) 3.153(5) yes . 55501
C(27) V(1) 2.998(5) yes . 65505
C(27) S(2) 3.522(6) yes . 55501
C(27) C(7) 3.285(7) yes . 55501
C(27) C(28) 2.378(8) yes . 55501
C(27) C(29) 2.401(8) yes . 55501
C(28) V(1) 3.238(5) yes . 55501
C(28) S(2) 3.223(6) yes . 55501
C(28) C(27) 2.378(8) yes . 55501
C(28) C(29) 2.424(7) yes . 55501
C(28) C(30) 3.026(7) yes . 55501
C(29) V(1) 3.018(6) yes . 55501
C(29) N(2) 2.459(6) yes . 55501
C(29) C(7) 3.554(7) yes . 55501
C(29) C(27) 2.401(8) yes . 55501
C(29) C(28) 2.424(7) yes . 55501
C(29) C(32) 3.115(7) yes . 55501
C(30) V(1) 3.047(6) yes . 55501
C(30) N(1) 2.453(7) yes . 55501
C(30) C(28) 3.026(7) yes . 55501
C(30) C(31) 2.404(9) yes . 55501
C(30) C(32) 2.391(7) yes . 55501
C(31) V(1) 3.092(8) yes . 55501
C(31) S(1) 3.540(9) yes . 55501
C(31) C(12) 3.51(1) yes . 55501
C(31) C(24) 3.58(1) yes . 55501
C(31) C(30) 2.404(9) yes . 55501
C(31) C(32) 2.39(1) yes . 55501
C(32) V(1) 3.148(6) yes . 55501
C(32) C(2) 3.408(8) yes . 55501
C(32) C(7) 3.232(9) yes . 55501
C(32) C(29) 3.115(7) yes . 55501
C(32) C(30) 2.391(7) yes . 55501
C(32) C(31) 2.39(1) yes . 55501
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
S(2) V(1) S(1) C(1) -172.0(2) yes . . . .
N(1) V(1) S(1) C(1) 130.3(3) yes . . . .
N(2) V(1) S(1) C(1) 43.8(2) yes . . . .
C(7) V(1) S(1) C(1) -55.2(2) yes . . . .
S(1) V(1) S(2) C(13) 2.9(2) yes . . . .
N(1) V(1) S(2) C(13) 173.4(2) yes . . . .
N(2) V(1) S(2) C(13) 110.3(2) yes . . . .
C(7) V(1) S(2) C(13) -95.5(2) yes . . . .
S(1) V(1) N(1) C(27) 133.0(5) yes . . . .
S(1) V(1) N(1) C(28) 9.6(8) yes . . . .
S(1) V(1) N(1) C(29) -109.8(5) yes . . . .
S(2) V(1) N(1) C(27) 74.8(3) yes . . . .
S(2) V(1) N(1) C(28) -48.6(3) yes . . . .
S(2) V(1) N(1) C(29) -168.0(3) yes . . . .
N(2) V(1) N(1) C(27) -138.4(3) yes . . . .
N(2) V(1) N(1) C(28) 98.1(3) yes . . . .
N(2) V(1) N(1) C(29) -21.2(3) yes . . . .
C(7) V(1) N(1) C(27) -41.4(3) yes . . . .
C(7) V(1) N(1) C(28) -164.9(3) yes . . . .
C(7) V(1) N(1) C(29) 75.7(3) yes . . . .
S(1) V(1) N(2) C(30) 160.0(3) yes . . . .
S(1) V(1) N(2) C(31) 41.1(4) yes . . . .
S(1) V(1) N(2) C(32) -80.5(4) yes . . . .
S(2) V(1) N(2) C(30) 55.6(4) yes . . . .
S(2) V(1) N(2) C(31) -63.3(4) yes . . . .
S(2) V(1) N(2) C(32) 175.2(3) yes . . . .
N(1) V(1) N(2) C(30) -8.8(3) yes . . . .
N(1) V(1) N(2) C(31) -127.6(4) yes . . . .
N(1) V(1) N(2) C(32) 110.8(4) yes . . . .
C(7) V(1) N(2) C(30) -101.2(3) yes . . . .
C(7) V(1) N(2) C(31) 139.9(4) yes . . . .
C(7) V(1) N(2) C(32) 18.3(4) yes . . . .
S(1) V(1) C(7) Si(1) 19.0(3) yes . . . .
S(2) V(1) C(7) Si(1) 113.2(2) yes . . . .
N(1) V(1) C(7) Si(1) -162.1(2) yes . . . .
N(2) V(1) C(7) Si(1) -82.1(3) yes . . . .
V(1) S(1) C(1) C(2) 50.2(4) yes . . . .
V(1) S(1) C(1) C(6) -132.5(4) yes . . . .
V(1) S(2) C(13) C(14) 98.6(3) yes . . . .
V(1) S(2) C(13) C(18) -83.1(3) yes . . . .
C(7) Si(1) C(2) C(1) -41.3(5) yes . . . .
C(7) Si(1) C(2) C(3) 141.1(4) yes . . . .
C(8) Si(1) C(2) C(1) -162.9(4) yes . . . .
C(8) Si(1) C(2) C(3) 19.5(4) yes . . . .
C(9) Si(1) C(2) C(1) 81.8(4) yes . . . .
C(9) Si(1) C(2) C(3) -95.8(4) yes . . . .
C(2) Si(1) C(7) V(1) 21.2(3) yes . . . .
C(8) Si(1) C(7) V(1) 142.6(2) yes . . . .
C(9) Si(1) C(7) V(1) -100.3(2) yes . . . .
C(10) Si(2) C(6) C(1) -64.5(5) yes . . . .
C(10) Si(2) C(6) C(5) 111.6(4) yes . . . .
C(11) Si(2) C(6) C(1) 175.8(4) yes . . . .
C(11) Si(2) C(6) C(5) -8.1(5) yes . . . .
C(12) Si(2) C(6) C(1) 59.3(5) yes . . . .
C(12) Si(2) C(6) C(5) -124.6(4) yes . . . .
C(19) Si(3) C(14) C(13) 46.4(4) yes . . . .
C(19) Si(3) C(14) C(15) -124.9(3) yes . . . .
C(20) Si(3) C(14) C(13) -76.2(4) yes . . . .
C(20) Si(3) C(14) C(15) 112.5(3) yes . . . .
C(21) Si(3) C(14) C(13) 164.0(3) yes . . . .
C(21) Si(3) C(14) C(15) -7.3(4) yes . . . .
C(18) Si(4) Si(5) C(22) 112.5(3) yes . . . .
C(18) Si(4) Si(5) C(23) -128.7(5) yes . . . .
C(18) Si(4) Si(5) C(24) -132.0(7) yes . . . .
C(18) Si(4) Si(5) C(26) -124(1) yes . . . .
C(22) Si(4) Si(5) C(18) -112.5(2) yes . . . .
C(22) Si(4) Si(5) C(23) 118.8(5) yes . . . .
C(22) Si(4) Si(5) C(24) 115.5(7) yes . . . .
C(22) Si(4) Si(5) C(26) 122(1) yes . . . .
C(23) Si(4) Si(5) C(18) 128.7(2) yes . . . .
C(23) Si(4) Si(5) C(22) -118.8(3) yes . . . .
C(23) Si(4) Si(5) C(24) -3.3(6) yes . . . .
C(23) Si(4) Si(5) C(26) 3(1) yes . . . .
C(24) Si(4) Si(5) C(18) 132.0(5) yes . . . .
C(24) Si(4) Si(5) C(22) -115.5(5) yes . . . .
C(24) Si(4) Si(5) C(23) 3.3(6) yes . . . .
C(24) Si(4) Si(5) C(26) 7(1) yes . . . .
C(26) Si(4) Si(5) C(18) 125.0(8) yes . . . .
C(26) Si(4) Si(5) C(22) -122.5(8) yes . . . .
C(26) Si(4) Si(5) C(23) -3(1) yes . . . .
C(26) Si(4) Si(5) C(24) -7(1) yes . . . .
Si(5) Si(4) C(18) C(13) 98.4(6) yes . . . .
Si(5) Si(4) C(18) C(17) -103.7(6) yes . . . .
C(22) Si(4) C(18) Si(5) 66.8(4) yes . . . .
C(22) Si(4) C(18) C(13) 165.2(4) yes . . . .
C(22) Si(4) C(18) C(17) -36.9(4) yes . . . .
C(23) Si(4) C(18) Si(5) -55.2(4) yes . . . .
C(23) Si(4) C(18) C(13) 43.2(5) yes . . . .
C(23) Si(4) C(18) C(17) -158.9(3) yes . . . .
C(24) Si(4) C(18) Si(5) -27.9(4) yes . . . .
C(24) Si(4) C(18) C(13) 70.5(4) yes . . . .
C(24) Si(4) C(18) C(17) -131.6(3) yes . . . .
C(25) Si(4) C(18) Si(5) -177.4(5) yes . . . .
C(25) Si(4) C(18) C(13) -79.0(5) yes . . . .
C(25) Si(4) C(18) C(17) 78.9(4) yes . . . .
C(26) Si(4) C(18) Si(5) -147.2(6) yes . . . .
C(26) Si(4) C(18) C(13) -48.7(6) yes . . . .
C(26) Si(4) C(18) C(17) 109.1(4) yes . . . .
C(18) Si(4) C(22) Si(5) -67.5(5) yes . . . .
C(23) Si(4) C(22) Si(5) 59.8(5) yes . . . .
C(24) Si(4) C(22) Si(5) 34.0(4) yes . . . .
C(25) Si(4) C(22) Si(5) 177.4(6) yes . . . .
C(26) Si(4) C(22) Si(5) 146.2(7) yes . . . .
Si(5) Si(4) C(23) C(24) 3(1) yes . . . .
C(18) Si(4) C(23) Si(5) 57.9(5) yes . . . .
C(18) Si(4) C(23) C(24) 61(1) yes . . . .
C(22) Si(4) C(23) Si(5) -62.5(5) yes . . . .
C(22) Si(4) C(23) C(24) -58(1) yes . . . .
C(24) Si(4) C(23) Si(5) -3.9(7) yes . . . .
C(25) Si(4) C(23) Si(5) 179(359) yes . . . .
C(25) Si(4) C(23) C(24) -176.3(9) yes . . . .
C(26) Si(4) C(23) Si(5) 177.8(6) yes . . . .
C(26) Si(4) C(23) C(24) -178(1) yes . . . .
Si(5) Si(4) C(24) C(23) -174(1) yes . . . .
C(18) Si(4) C(24) Si(5) 46.7(7) yes . . . .
C(18) Si(4) C(24) C(23) -127(1) yes . . . .
C(22) Si(4) C(24) Si(5) -59.8(7) yes . . . .
C(22) Si(4) C(24) C(23) 126(1) yes . . . .
C(23) Si(4) C(24) Si(5) 174(1) yes . . . .
C(25) Si(4) C(24) Si(5) 179.4(7) yes . . . .
C(25) Si(4) C(24) C(23) 5(1) yes . . . .
C(26) Si(4) C(24) Si(5) 175.9(7) yes . . . .
C(26) Si(4) C(24) C(23) 1(1) yes . . . .
C(18) Si(4) C(25) C(26) 124(1) yes . . . .
C(22) Si(4) C(25) C(26) -121(1) yes . . . .
C(23) Si(4) C(25) C(26) -3(1) yes . . . .
C(24) Si(4) C(25) C(26) -6(1) yes . . . .
Si(5) Si(4) C(26) C(25) -179(719) yes . . . .
C(18) Si(4) C(26) C(25) -68(1) yes . . . .
C(22) Si(4) C(26) C(25) 71(1) yes . . . .
C(23) Si(4) C(26) C(25) 176(1) yes . . . .
C(24) Si(4) C(26) C(25) 175(1) yes . . . .
Si(4) Si(5) C(18) C(13) -94.0(6) yes . . . .
Si(4) Si(5) C(18) C(17) 84.1(5) yes . . . .
C(22) Si(5) C(18) Si(4) -89.4(5) yes . . . .
C(22) Si(5) C(18) C(13) 176.6(4) yes . . . .
C(22) Si(5) C(18) C(17) -5.3(4) yes . . . .
C(23) Si(5) C(18) Si(4) 93.9(5) yes . . . .
C(23) Si(5) C(18) C(13) -0.1(6) yes . . . .
C(23) Si(5) C(18) C(17) 177.9(3) yes . . . .
C(24) Si(5) C(18) Si(4) 138.8(5) yes . . . .
C(24) Si(5) C(18) C(13) 44.8(5) yes . . . .
C(24) Si(5) C(18) C(17) -137.2(3) yes . . . .
C(26) Si(5) C(18) Si(4) 20.3(4) yes . . . .
C(26) Si(5) C(18) C(13) -73.7(4) yes . . . .
C(26) Si(5) C(18) C(17) 104.4(4) yes . . . .
C(18) Si(5) C(22) Si(4) 88.7(5) yes . . . .
C(23) Si(5) C(22) Si(4) -94.2(5) yes . . . .
C(24) Si(5) C(22) Si(4) -133.7(5) yes . . . .
C(26) Si(5) C(22) Si(4) -20.9(4) yes . . . .
Si(4) Si(5) C(23) C(24) -175(1) yes . . . .
C(18) Si(5) C(23) Si(4) -91.5(6) yes . . . .
C(18) Si(5) C(23) C(24) 92(1) yes . . . .
C(22) Si(5) C(23) Si(4) 91.9(5) yes . . . .
C(22) Si(5) C(23) C(24) -83(1) yes . . . .
C(24) Si(5) C(23) Si(4) 175.9(8) yes . . . .
C(26) Si(5) C(23) Si(4) -1.7(4) yes . . . .
C(26) Si(5) C(23) C(24) -177(1) yes . . . .
Si(4) Si(5) C(24) C(23) 5(1) yes . . . .
C(18) Si(5) C(24) Si(4) -119.5(8) yes . . . .
C(18) Si(5) C(24) C(23) -114(1) yes . . . .
C(22) Si(5) C(24) Si(4) 107.2(7) yes . . . .
C(22) Si(5) C(24) C(23) 112(1) yes . . . .
C(23) Si(5) C(24) Si(4) -5(1) yes . . . .
C(26) Si(5) C(24) Si(4) -3.0(5) yes . . . .
C(26) Si(5) C(24) C(23) 2(1) yes . . . .
Si(4) Si(5) C(26) C(25) 0(1) yes . . . .
C(18) Si(5) C(26) C(25) -57(1) yes . . . .
C(22) Si(5) C(26) C(25) 59(1) yes . . . .
C(23) Si(5) C(26) C(25) 176(1) yes . . . .
C(24) Si(5) C(26) C(25) 174(1) yes . . . .
V(1) N(1) C(29) C(30) 48.7(4) yes . . . .
C(27) N(1) C(29) C(30) 168.4(3) yes . . . .
C(28) N(1) C(29) C(30) -75.6(4) yes . . . .
V(1) N(2) C(30) C(29) 38.3(5) yes . . . .
C(31) N(2) C(30) C(29) 158.1(4) yes . . . .
C(32) N(2) C(30) C(29) -84.9(5) yes . . . .
S(1) C(1) C(2) Si(1) -0.4(6) yes . . . .
S(1) C(1) C(2) C(3) 177.2(4) yes . . . .
C(6) C(1) C(2) Si(1) -177.7(4) yes . . . .
C(6) C(1) C(2) C(3) 0.0(7) yes . . . .
S(1) C(1) C(6) Si(2) -1.9(6) yes . . . .
S(1) C(1) C(6) C(5) -177.9(4) yes . . . .
C(2) C(1) C(6) Si(2) 175.4(4) yes . . . .
C(2) C(1) C(6) C(5) -0.7(7) yes . . . .
Si(1) C(2) C(3) C(4) 178.5(5) yes . . . .
C(1) C(2) C(3) C(4) 0.7(8) yes . . . .
C(2) C(3) C(4) C(5) -0.8(9) yes . . . .
C(3) C(4) C(5) C(6) 0.1(9) yes . . . .
C(4) C(5) C(6) Si(2) -175.8(4) yes . . . .
C(4) C(5) C(6) C(1) 0.6(8) yes . . . .
S(2) C(13) C(14) Si(3) 18.4(5) yes . . . .
S(2) C(13) C(14) C(15) -170.1(3) yes . . . .
C(18) C(13) C(14) Si(3) -159.8(3) yes . . . .
C(18) C(13) C(14) C(15) 11.6(6) yes . . . .
S(2) C(13) C(18) Si(4) -32.5(6) yes . . . .
S(2) C(13) C(18) Si(5) -11.5(5) yes . . . .
S(2) C(13) C(18) C(17) 170.4(3) yes . . . .
C(14) C(13) C(18) Si(4) 145.7(4) yes . . . .
C(14) C(13) C(18) Si(5) 166.7(3) yes . . . .
C(14) C(13) C(18) C(17) -11.3(6) yes . . . .
Si(3) C(14) C(15) C(16) 168.8(4) yes . . . .
C(13) C(14) C(15) C(16) -3.1(6) yes . . . .
C(14) C(15) C(16) C(17) -5.4(7) yes . . . .
C(15) C(16) C(17) C(18) 5.8(7) yes . . . .
C(16) C(17) C(18) Si(4) -157.4(4) yes . . . .
C(16) C(17) C(18) Si(5) -175.9(4) yes . . . .
C(16) C(17) C(18) C(13) 2.4(7) yes . . . .
Si(4) C(23) C(24) Si(5) -1.2(6) yes . . . .
Si(5) C(23) C(24) Si(4) 1.2(6) yes . . . .
Si(4) C(25) C(26) Si(5) -0.0(5) yes . . . .
N(1) C(29) C(30) N(2) -61.5(5) yes . . . .