Crystallography Open Database

Information card for entry 4308705

Preview

Coordinates	4308705.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C98 H110 Ag2 F12 O24 P8 Pt2 S4
Calculated formula	C98 H110 Ag2 F12 O24 P8 Pt2 S4
SMILES	[Ag]12([O]=P(OCC)(OCC)[C@H]([P]([Pt]31([O]=P([C@@H](c1ccccc1)[P]3(c1ccccc1)c1ccccc1)(OCC)OCC)C)(c1ccccc1)c1ccccc1)c1ccccc1)[O]=S(=O)(O[Ag]1([O]=P(OCC)(OCC)[C@@H]([P]([Pt]31([O]=P([C@H](c1ccccc1)[P]3(c1ccccc1)c1ccccc1)(OCC)OCC)C)(c1ccccc1)c1ccccc1)c1ccccc1)[O]=S(O2)(=O)C(F)(F)F)C(F)(F)F.FC(S(=O)(=O)[O-])(F)F.FC(F)(F)S(=O)(=O)[O-]
Title of publication	Synthesis and Structure of Pt(II) Phosphonato-Phosphine Complexes and of a P,O-Stabilized Metal-Metal-Bonded Pt2Ag2 Complex
Authors of publication	Nicola Oberbeckmann-Winter; Xavier Morise; Pierre Braunstein; Richard Welter
Journal of publication	Inorganic Chemistry
Year of publication	2005
Journal volume	44
Pages of publication	1391 - 1403
a	13.55 ± 0.005 Å
b	14.827 ± 0.005 Å
c	15.009 ± 0.005 Å
α	90.958 ± 0.005°
β	109.643 ± 0.005°
γ	94.52 ± 0.005°
Cell volume	2828.1 ± 1.7 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	8
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0711
Residual factor for significantly intense reflections	0.0499
Weighted residual factors for significantly intense reflections	0.1175
Weighted residual factors for all reflections included in the refinement	0.1381
Goodness-of-fit parameter for all reflections included in the refinement	1.124
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Version history is temporarily not available due to server issues.