#------------------------------------------------------------------------------ #$Date: 2023-11-01 19:18:41 +0000 (Wed, 01 Nov 2023) $ #$Revision: 287220 $ #$URL: svn://www.crystallography.net/cod/hkl/4/51/94/4519471.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_4519471 _cell_angle_alpha 90.000 _cell_angle_beta 96.133 _cell_angle_gamma 90.000 _cell_length_a 5.8291 _cell_length_b 8.1043 _cell_length_c 13.1926 _exptl_crystal_F_000 303.82 _reflns_d_resolution_high 0.8198 _cod_data_source_file S28_Pq-Br_1_00_Cl_1_00_P21_c.fcf _cod_data_source_block jw25612 _shelx_title ' jw25612_a.res in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 112.63 _shelx_f_squared_multiplier 1.000 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 2.37 13.30 1.44 o 2 0 0 2779.66 2982.88 63.63 o 3 0 0 5089.76 5139.92 94.13 o 4 0 0 183.62 190.97 5.74 o 5 0 0 469.09 495.04 13.50 o 6 0 0 526.21 526.39 23.35 o 1 1 0 39.86 64.22 1.26 o 2 1 0 1388.51 1369.29 18.24 o 3 1 0 540.27 565.98 9.02 o 4 1 0 33.01 29.86 2.42 o 5 1 0 193.40 194.57 5.63 o 6 1 0 6.30 5.74 2.22 o 7 1 0 82.68 93.79 6.85 o 0 2 0 80.84 108.55 3.12 o 1 2 0 5995.89 6045.50 109.45 o 2 2 0 1690.71 1710.48 22.59 o 3 2 0 613.25 587.09 9.30 o 4 2 0 122.35 125.80 4.27 o 5 2 0 119.22 115.05 10.11 o 6 2 0 41.58 46.42 4.45 o 1 3 0 2254.42 2256.32 31.73 o 2 3 0 93.80 70.79 3.11 o 3 3 0 0.20 2.42 0.97 o 4 3 0 1195.49 1171.25 21.32 o 5 3 0 216.20 221.09 7.87 o 6 3 0 33.23 31.83 3.03 o 0 4 0 1010.23 1020.68 20.94 o 1 4 0 958.17 993.84 16.26 o 2 4 0 2139.60 2137.39 30.58 o 3 4 0 176.60 173.64 3.77 o 4 4 0 30.97 33.87 2.88 o 5 4 0 166.90 163.12 8.85 o 6 4 0 94.14 89.67 4.84 o 1 5 0 77.65 76.73 2.51 o 2 5 0 136.00 139.79 4.40 o 3 5 0 160.52 156.43 4.70 o 4 5 0 190.41 189.25 5.62 o 5 5 0 28.84 30.17 4.20 o 6 5 0 84.38 91.90 5.62 o 0 6 0 2357.01 2314.98 51.34 o 1 6 0 224.30 223.69 5.36 o 2 6 0 198.92 192.69 4.35 o 3 6 0 1774.69 1712.63 25.68 o 4 6 0 1.89 3.45 2.05 o 5 6 0 156.92 169.96 9.76 o 1 7 0 143.99 127.72 4.25 o 2 7 0 102.39 108.12 3.91 o 3 7 0 20.17 13.02 2.33 o 4 7 0 12.52 16.22 2.73 o 0 8 0 66.07 56.22 5.89 o 1 8 0 80.65 75.45 5.51 o 2 8 0 29.58 26.39 2.91 o 3 8 0 22.41 13.71 3.44 o 4 8 0 80.79 79.16 10.68 o 1 9 0 101.13 124.84 14.22 o 2 9 0 213.13 225.33 10.17 o -7 1 1 128.01 133.85 8.27 o -6 1 1 351.89 348.96 9.20 o -5 1 1 9.99 11.00 1.87 o -4 1 1 1092.58 1068.42 16.40 o -3 1 1 413.17 398.32 7.29 o -2 1 1 995.02 996.23 17.03 o -1 1 1 1361.27 1468.96 24.21 o 0 1 1 91.43 79.85 2.20 o 1 1 1 2323.27 2530.49 32.58 o 2 1 1 3375.37 3347.52 50.07 o 3 1 1 35.68 56.40 2.46 o 4 1 1 1055.44 1085.02 17.90 o 5 1 1 310.04 320.01 8.42 o 6 1 1 17.16 16.43 2.60 o -6 2 1 197.16 195.86 20.26 o -5 2 1 890.10 898.61 17.25 o -4 2 1 11.18 10.50 1.53 o -3 2 1 1598.71 1559.39 24.30 o -2 2 1 2216.18 2151.31 28.26 o -1 2 1 2913.92 2889.22 43.25 o 0 2 1 4487.43 4779.02 86.36 o 1 2 1 12684.43 12864.63 188.77 o 2 2 1 21.73 21.56 1.22 o 3 2 1 2267.29 2251.99 31.96 o 4 2 1 906.80 899.91 16.60 o 5 2 1 130.57 136.65 6.97 o 6 2 1 387.19 389.05 9.66 o -6 3 1 1.80 1.78 2.26 o -5 3 1 26.17 25.97 2.79 o -4 3 1 34.25 28.83 2.72 o -3 3 1 0.57 2.12 1.05 o -2 3 1 113.54 111.40 2.76 o -1 3 1 36.60 38.25 1.90 o 0 3 1 29.16 31.84 1.37 o 1 3 1 547.72 550.28 13.15 o 2 3 1 170.82 181.63 3.93 o 3 3 1 2.51 3.72 0.84 o 4 3 1 8.73 12.02 1.73 o 5 3 1 126.52 115.02 4.83 o 6 3 1 10.10 4.59 4.17 o -6 4 1 116.24 114.96 5.45 o -5 4 1 432.47 439.16 11.02 o -4 4 1 56.57 59.59 4.06 o -3 4 1 965.18 966.14 14.78 o -2 4 1 4000.84 3909.45 54.60 o -1 4 1 24.74 27.95 1.50 o 0 4 1 2059.47 2086.24 29.42 o 1 4 1 2102.37 2170.16 36.33 o 2 4 1 156.08 165.46 3.88 o 3 4 1 1560.67 1533.34 22.63 o 4 4 1 210.08 218.09 10.03 o 5 4 1 38.63 41.33 4.39 o 6 4 1 178.47 177.10 6.47 o -6 5 1 104.11 108.63 13.35 o -5 5 1 20.55 23.03 3.94 o -4 5 1 707.40 728.03 14.57 o -3 5 1 123.98 130.49 3.91 o -2 5 1 415.81 410.03 7.40 o -1 5 1 934.68 894.28 16.55 o 0 5 1 385.60 374.91 6.65 o 1 5 1 1451.90 1431.91 22.91 o 2 5 1 406.15 392.40 6.70 o 3 5 1 1.03 2.67 1.20 o 4 5 1 117.78 121.47 7.99 o 5 5 1 249.48 259.58 8.76 o 6 5 1 2.83 2.22 4.82 o -5 6 1 2.26 3.83 3.28 o -4 6 1 2.49 2.04 1.67 o -3 6 1 74.83 76.53 3.25 o -2 6 1 0.47 0.89 1.23 o -1 6 1 1.18 1.68 1.12 o 0 6 1 24.02 20.45 1.95 o 1 6 1 18.36 17.55 1.84 o 2 6 1 15.94 16.15 1.62 o 3 6 1 302.62 300.69 9.15 o 4 6 1 0.32 -0.46 2.03 o 5 6 1 0.03 -2.70 3.33 o -5 7 1 0.83 5.05 5.71 o -4 7 1 54.70 64.51 5.09 o -3 7 1 149.25 155.64 5.03 o -2 7 1 23.42 29.64 2.31 o -1 7 1 656.28 632.36 12.32 o 0 7 1 3.20 6.47 1.78 o 1 7 1 110.16 117.17 4.60 o 2 7 1 371.22 372.11 7.51 o 3 7 1 13.98 10.67 2.16 o 4 7 1 191.77 190.94 8.28 o -4 8 1 70.53 64.61 6.95 o -3 8 1 176.71 178.89 6.98 o -2 8 1 271.44 278.10 7.40 o -1 8 1 2.67 2.39 2.73 o 0 8 1 405.31 413.02 9.93 o 1 8 1 293.34 299.58 10.32 o 2 8 1 34.07 32.25 5.01 o 3 8 1 188.29 184.85 9.19 o -2 9 1 3.49 2.80 3.36 o -1 9 1 51.48 53.16 4.41 o 0 9 1 3.42 2.76 2.56 o 1 9 1 3.41 1.75 2.96 o 2 9 1 1.30 -2.18 3.58 o -7 0 2 200.40 183.37 13.12 o -6 0 2 48.57 42.88 4.44 o -5 0 2 1850.87 1871.43 36.50 o -4 0 2 995.53 1006.96 20.73 o -3 0 2 645.97 670.21 15.71 o -2 0 2 8514.34 8585.01 179.30 o -1 0 2 537.95 631.84 14.19 o 0 0 2 393.54 317.20 7.27 o 1 0 2 8873.10 9366.21 150.51 o 2 0 2 407.56 428.72 10.54 o 3 0 2 137.22 120.09 4.57 o 4 0 2 2216.60 2205.07 48.48 o 5 0 2 12.15 13.74 3.95 o -7 1 2 47.37 49.09 4.80 o -6 1 2 0.95 2.82 2.44 o -5 1 2 235.78 237.83 5.86 o -4 1 2 516.12 503.70 8.96 o -3 1 2 434.01 425.65 7.23 o -2 1 2 2.27 8.05 0.83 o -1 1 2 5385.84 5485.27 74.89 o 0 1 2 144.18 123.85 2.15 o 1 1 2 0.26 6.34 1.03 o 2 1 2 1190.29 1230.96 16.60 o 3 1 2 727.77 717.76 12.01 o 4 1 2 367.28 370.19 7.93 o 5 1 2 183.59 188.47 5.24 o 6 1 2 1.03 -0.27 2.61 o -6 2 2 19.84 21.76 4.83 o -5 2 2 262.98 270.14 7.82 o -4 2 2 454.43 430.37 8.33 o -3 2 2 160.14 151.62 3.55 o -2 2 2 1035.56 1025.21 14.06 o -1 2 2 2621.74 2686.63 40.30 o 0 2 2 1184.07 1223.70 16.59 o 1 2 2 53.68 57.05 1.22 o 2 2 2 1187.66 1272.41 19.34 o 3 2 2 692.82 706.12 11.86 o 4 2 2 102.39 98.60 3.73 o 5 2 2 1.05 3.01 1.81 o 6 2 2 80.10 75.77 4.11 o -6 3 2 384.26 413.70 10.55 o -5 3 2 3.35 4.11 2.56 o -4 3 2 237.55 230.90 5.86 o -3 3 2 2323.44 2228.19 37.68 o -2 3 2 466.22 522.18 12.89 o -1 3 2 2643.02 2688.34 37.69 o 0 3 2 3041.82 3053.14 39.55 o 1 3 2 1044.37 1090.20 15.83 o 2 3 2 3599.69 3593.54 39.69 o 3 3 2 723.61 711.71 10.81 o 5 3 2 618.80 642.69 14.31 o 6 3 2 42.40 42.89 3.31 o -6 4 2 1.64 -0.16 2.80 o -5 4 2 179.26 188.59 6.43 o -4 4 2 177.99 177.24 5.09 o -3 4 2 360.82 355.33 6.55 o -2 4 2 212.62 202.63 4.59 o -1 4 2 196.76 200.93 4.86 o 0 4 2 505.89 510.84 8.26 o 1 4 2 67.90 58.90 2.20 o 2 4 2 889.53 908.47 15.24 o 3 4 2 264.18 249.32 5.58 o 4 4 2 379.89 367.32 9.34 o 5 4 2 48.03 51.70 6.89 o 6 4 2 81.65 62.52 4.18 o -6 5 2 15.28 7.46 3.25 o -5 5 2 9.13 8.69 2.13 o -4 5 2 158.77 154.05 9.24 o -3 5 2 37.91 39.60 2.16 o -2 5 2 43.74 48.60 3.39 o -1 5 2 527.57 544.19 9.17 o 0 5 2 166.51 155.15 3.89 o 1 5 2 111.03 106.24 4.58 o 2 5 2 603.55 611.00 10.20 o 3 5 2 35.69 28.88 4.23 o 4 5 2 0.15 2.15 1.80 o 5 5 2 79.67 69.84 4.61 o -5 6 2 350.88 360.05 11.16 o -4 6 2 246.04 251.37 6.94 o -3 6 2 33.26 38.71 2.32 o -2 6 2 1608.10 1599.15 23.90 o -1 6 2 286.08 288.73 8.00 o 0 6 2 156.31 148.78 4.41 o 1 6 2 1755.14 1700.55 27.13 o 2 6 2 58.73 63.41 2.87 o 3 6 2 231.25 234.29 6.15 o 4 6 2 496.40 485.39 11.97 o 5 6 2 0.12 -1.69 3.68 o -5 7 2 15.79 17.88 4.32 o -4 7 2 181.63 169.92 6.55 o -3 7 2 72.58 72.68 3.15 o -2 7 2 64.03 58.48 3.12 o -1 7 2 297.44 300.22 7.85 o 0 7 2 187.28 191.06 5.99 o 1 7 2 5.53 5.11 2.03 o 2 7 2 218.68 215.08 9.05 o 3 7 2 1.34 0.14 2.02 o 4 7 2 10.66 10.83 3.51 o -4 8 2 56.19 52.18 6.23 o -3 8 2 2.35 1.30 2.58 o -2 8 2 73.01 72.98 4.09 o -1 8 2 238.96 235.24 6.65 o 0 8 2 65.36 60.21 3.79 o 1 8 2 106.19 96.54 4.79 o 2 8 2 0.26 0.24 2.58 o 3 8 2 59.75 56.43 5.21 o -2 9 2 1.93 0.09 3.54 o -1 9 2 117.11 115.65 5.66 o 0 9 2 198.38 202.23 12.29 o 1 9 2 38.77 29.65 3.43 o 2 9 2 94.55 88.06 7.72 o -7 1 3 35.29 37.84 4.27 o -6 1 3 161.32 162.13 6.58 o -5 1 3 34.79 37.23 2.57 o -4 1 3 156.20 161.22 3.98 o -3 1 3 1784.80 1755.37 25.40 o -2 1 3 574.55 577.01 8.40 o -1 1 3 3427.70 3488.55 38.24 o 0 1 3 6815.20 6885.32 93.83 o 1 1 3 123.55 133.21 2.88 o 2 1 3 1434.37 1409.22 21.76 o 3 1 3 1890.40 1845.74 34.94 o 4 1 3 33.20 40.96 2.62 o 5 1 3 471.89 472.13 9.87 o 6 1 3 116.79 132.47 6.56 o -6 2 3 97.04 98.54 4.39 o -5 2 3 625.21 601.17 16.75 o -4 2 3 1485.81 1430.21 21.35 o -3 2 3 136.62 150.65 3.65 o -2 2 3 2861.96 2731.73 35.75 o -1 2 3 4600.86 4479.20 57.47 o 0 2 3 797.37 812.75 14.05 o 1 2 3 2955.54 3006.49 36.62 o 2 2 3 274.19 259.28 4.97 o 3 2 3 82.79 82.01 2.76 o 4 2 3 542.73 531.30 11.71 o 5 2 3 383.02 375.01 25.19 o 6 2 3 72.54 58.39 5.61 o -6 3 3 2.17 -0.79 1.86 o -5 3 3 12.20 13.36 2.67 o -4 3 3 137.92 134.62 4.79 o -3 3 3 28.02 30.23 2.31 o -2 3 3 78.27 86.75 2.94 o -1 3 3 2.01 0.84 0.81 o 0 3 3 4.65 6.15 0.85 o 1 3 3 40.23 50.17 1.95 o 2 3 3 24.51 26.57 1.53 o 3 3 3 9.41 9.18 0.96 o 4 3 3 0.83 0.91 1.20 o 5 3 3 42.46 43.10 3.04 o 6 3 3 0.31 -2.09 3.39 o -6 4 3 22.06 24.10 3.03 o -5 4 3 161.83 159.01 5.52 o -4 4 3 1224.17 1256.72 22.70 o -3 4 3 71.92 77.39 2.93 o -2 4 3 1111.26 1088.53 19.71 o -1 4 3 1080.43 1096.47 17.78 o 0 4 3 2.32 6.97 1.02 o 1 4 3 1131.89 1072.24 17.13 o 2 4 3 623.68 614.36 12.04 o 3 4 3 124.03 113.64 3.61 o 4 4 3 892.95 842.50 18.11 o 5 4 3 26.33 31.08 2.88 o 6 4 3 47.83 27.55 7.48 o -6 5 3 159.08 171.11 12.55 o -5 5 3 61.09 63.29 5.11 o -4 5 3 178.87 185.70 6.10 o -3 5 3 412.51 423.48 7.76 o -2 5 3 318.46 325.48 6.33 o -1 5 3 481.90 468.58 8.82 o 0 5 3 1368.53 1320.98 19.47 o 1 5 3 112.49 109.12 3.65 o 2 5 3 784.92 775.36 13.37 o 3 5 3 581.60 557.96 12.37 o 4 5 3 0.10 -0.26 1.84 o 5 5 3 200.06 207.87 10.90 o -5 6 3 3.82 1.78 2.52 o -4 6 3 6.55 7.24 1.94 o -3 6 3 28.06 34.42 2.36 o -2 6 3 127.96 135.62 3.91 o -1 6 3 1.78 1.18 1.13 o 0 6 3 69.17 72.81 3.04 o 1 6 3 15.07 14.83 2.13 o 2 6 3 5.16 4.39 1.41 o 3 6 3 82.80 83.34 3.87 o 4 6 3 0.09 -1.66 2.50 o 5 6 3 4.55 3.55 5.38 o -4 7 3 102.18 98.25 7.26 o -3 7 3 442.36 441.54 8.41 o -2 7 3 0.40 1.94 1.73 o -1 7 3 157.19 160.59 5.35 o 0 7 3 592.11 578.81 12.43 o 1 7 3 28.86 33.70 4.49 o 2 7 3 261.43 251.55 7.11 o 3 7 3 253.86 264.73 7.22 o 4 7 3 0.15 1.81 3.63 o -4 8 3 111.75 120.34 26.56 o -3 8 3 0.07 0.11 2.33 o -2 8 3 337.63 353.38 9.19 o -1 8 3 245.09 248.31 7.27 o 0 8 3 2.98 6.53 2.57 o 1 8 3 282.31 283.70 7.78 o 2 8 3 339.02 311.04 8.52 o 3 8 3 31.74 40.19 5.64 o -2 9 3 0.05 -1.02 3.70 o -1 9 3 45.75 44.39 3.97 o 0 9 3 2.99 2.69 2.81 o 1 9 3 0.05 -2.98 3.03 o 2 9 3 1.22 -0.60 4.14 o -7 0 4 119.27 139.82 11.02 o -6 0 4 930.43 931.19 40.14 o -5 0 4 77.20 64.26 4.41 o -4 0 4 1740.50 1713.04 33.39 o -3 0 4 752.60 756.03 15.94 o -2 0 4 5.61 8.10 1.59 o -1 0 4 8439.21 8437.88 136.05 o 0 0 4 2322.30 2296.86 48.81 o 1 0 4 7767.98 7820.12 188.63 o 2 0 4 3417.15 3240.54 83.74 o 3 0 4 45.74 47.97 3.98 o 4 0 4 827.99 808.38 23.16 o 5 0 4 524.81 539.42 16.68 o 6 0 4 17.24 14.82 6.03 o -6 1 4 414.37 418.30 10.61 o -5 1 4 0.88 0.59 1.51 o -4 1 4 18.22 20.74 1.67 o -3 1 4 1154.63 1203.87 18.02 o -2 1 4 110.86 101.77 2.81 o -1 1 4 0.61 4.81 0.53 o 0 1 4 1294.50 1310.94 20.11 o 1 1 4 442.06 462.91 7.73 o 2 1 4 16.47 18.61 1.29 o 3 1 4 728.57 714.22 11.89 o 4 1 4 8.20 9.67 1.53 o 5 1 4 6.21 4.53 2.73 o 6 1 4 122.49 136.41 11.28 o -6 2 4 30.94 30.59 2.83 o -5 2 4 18.67 18.33 2.15 o -4 2 4 302.05 304.78 6.74 o -3 2 4 472.97 482.51 9.48 o -2 2 4 411.03 400.93 6.32 o -1 2 4 480.21 449.16 6.48 o 0 2 4 9.86 9.15 0.71 o 1 2 4 405.09 442.15 7.27 o 2 2 4 840.00 818.94 12.17 o 3 2 4 1.52 4.98 1.13 o 4 2 4 305.19 312.21 7.05 o 6 2 4 0.38 0.66 5.12 o -6 3 4 234.17 244.18 7.23 o -5 3 4 821.09 834.16 16.45 o -4 3 4 435.98 416.55 10.82 o -3 3 4 1143.97 1124.03 18.49 o -2 3 4 1970.96 1963.83 30.62 o -1 3 4 308.30 330.54 5.93 o 0 3 4 2907.61 2895.61 47.78 o 1 3 4 1806.05 1807.14 22.56 o 2 3 4 518.47 524.87 7.30 o 3 3 4 823.42 782.65 11.18 o 5 3 4 191.36 181.80 5.92 o 6 3 4 157.31 177.99 13.51 o -6 4 4 30.69 28.45 2.79 o -5 4 4 6.46 18.29 3.60 o -4 4 4 391.36 367.95 8.46 o -3 4 4 203.98 202.64 4.66 o -2 4 4 92.65 88.51 2.93 o -1 4 4 1420.09 1455.82 23.19 o 0 4 4 426.71 462.01 9.04 o 1 4 4 805.56 799.55 12.24 o 2 4 4 558.23 536.35 9.71 o 3 4 4 19.76 20.11 1.88 o 4 4 4 56.95 65.08 4.02 o 5 4 4 37.04 33.31 3.18 o 6 4 4 1.54 -1.18 8.66 o -6 5 4 32.49 29.31 4.50 o -5 5 4 38.67 41.25 3.23 o -4 5 4 33.63 38.88 2.79 o -3 5 4 829.72 841.10 13.59 o -2 5 4 162.89 165.02 4.35 o -1 5 4 0.06 1.28 1.03 o 0 5 4 724.35 722.68 15.30 o 1 5 4 79.55 81.03 4.85 o 2 5 4 1.38 0.71 1.29 o 3 5 4 188.43 184.70 4.98 o 4 5 4 0.73 1.51 2.22 o 5 5 4 13.57 16.68 3.78 o -5 6 4 11.70 13.77 4.17 o -4 6 4 378.94 393.69 8.43 o -3 6 4 500.45 517.05 9.34 o -2 6 4 384.53 402.46 8.38 o -1 6 4 1090.29 1098.34 18.42 o 0 6 4 57.53 57.67 3.14 o 1 6 4 308.30 310.62 8.73 o 2 6 4 791.30 764.60 13.55 o 3 6 4 38.86 36.48 5.87 o 4 6 4 351.22 335.48 12.29 o 5 6 4 171.48 172.35 14.69 o -4 7 4 0.74 2.03 2.21 o -3 7 4 130.54 130.64 4.38 o -2 7 4 5.10 3.72 1.55 o -1 7 4 3.92 4.45 1.92 o 0 7 4 272.42 258.61 7.26 o 1 7 4 3.05 4.02 2.32 o 2 7 4 16.23 17.60 2.73 o 3 7 4 170.36 159.80 7.11 o 4 7 4 15.90 15.31 6.17 o -3 8 4 0.76 0.45 2.53 o -2 8 4 0.32 2.94 2.61 o -1 8 4 16.19 14.84 2.69 o 0 8 4 0.58 2.03 2.18 o 1 8 4 21.76 24.16 2.83 o 2 8 4 31.39 29.90 3.79 o 3 8 4 4.38 7.03 4.44 o -2 9 4 221.61 237.04 9.23 o -1 9 4 130.02 121.97 5.84 o 0 9 4 96.30 102.99 5.12 o 1 9 4 103.88 100.71 5.35 o 2 9 4 58.43 51.17 5.92 o -6 1 5 178.48 180.01 8.50 o -5 1 5 1189.32 1152.14 16.75 o -4 1 5 295.60 295.69 6.73 o -3 1 5 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