Crystallography Open Database

Information card for entry 7100141

Preview

Coordinates	7100141.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C14 H14 Mn2 N O8 P
Calculated formula	C14 H14 Mn2 N O8 P
SMILES	[Mn]1([Mn](P1N(C(C)C)C(C)C)(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O]
Title of publication	Reactivity of Electrophilic m2-Phosphinidene Complexes with Heterocumulenes: Formation of the First s-p-Aminophosphaimine Complexes [Mn2(CO)8{m-h1,h2-P(NiPr2)=NR}] and Diazoalkane Insertions into Metal-Phosphorus Bonds.
Authors of publication	A. Carty; Todd Graham; Konstantin A. Udachin
Journal of publication	Chemical Communications
Year of publication	2005
a	6.6736 ± 0.0007 Å
b	9.5035 ± 0.0009 Å
c	15.4285 ± 0.0015 Å
α	104.344 ± 0.002°
β	96.656 ± 0.002°
γ	97.44 ± 0.002°
Cell volume	928.81 ± 0.16 Å³
Cell temperature	125 ± 2 K
Ambient diffraction temperature	125 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Has coordinates	Yes
Has disorder	No
Has F_obs	No

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