Efficient Two-step Synthesis of 3-Halo-3-enals or 2-Halo-2-alkenyl Ketones from Propargylic Bromides via a unique cationc 1,2-Aryl or Proton Shift in Electrophilic Addition Reaction of 2,3-Allenols with X+
Authors of publication
Chunling Fu.; Shengming Ma.; Jing Li.
Journal of publication
Chemical Communications
Year of publication
2005
a
9.8575 ± 0.0003 Å
b
10.7013 ± 0.0004 Å
c
14.9705 ± 0.0006 Å
α
80.852 ± 0.0008°
β
75.931 ± 0.003°
γ
89.953 ± 0.0006°
Cell volume
1511.17 ± 0.09 Å3
Cell temperature
253 ± 1 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Has coordinates
Yes
Has disorder
No
Has Fobs
No
Version history
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