#------------------------------------------------------------------------------ #$Date: 2026-06-26 00:52:31 +0100 (Fri, 26 Jun 2026) $ #$Revision: 306652 $ #$URL: svn://www.crystallography.net/cod/cif/7/72/11/7721163.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_7721163 loop_ _publ_author_name 'Xie, Pengzhi' 'Ren, Qixian' 'Feng, Junwei' 'Du, Hong' 'Mi, Shuyi' _publ_section_title ; [Rb4Cl][Cd11In9Se26]: a salt inclusion chalcogenide with a diamond-like framework for infrared nonlinear optics. ; _journal_name_full 'Dalton transactions (Cambridge, England : 2003)' _journal_paper_doi 10.1039/d6dt00409a _journal_year 2026 _chemical_formula_moiety 'Cd11 Cl In9 Rb4 Se26' _chemical_formula_sum 'Cd11 Cl In9 Rb4 Se26' _chemical_formula_weight 4700.07 _space_group_crystal_system orthorhombic _space_group_IT_number 36 _space_group_name_Hall 'C 2c -2' _space_group_name_H-M_alt 'C m c 21' _atom_sites_solution_primary dual _audit_block_doi 10.25505/fiz.icsd.cc2qxsq5 _audit_creation_date 2026-01-07 _audit_creation_method ; Olex2 1.5 (compiled 2025.07.13 svn.rb7424aed for OlexSys, GUI svn.r7314) ; _audit_update_record ; 2026-02-10 deposited with the CCDC. 2026-05-13 downloaded from the CCDC. ; _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 20.7867(13) _cell_length_b 21.5042(11) _cell_length_c 13.5456(8) _cell_measurement_reflns_used 9799 _cell_measurement_temperature 293.00 _cell_measurement_theta_max 27.503 _cell_measurement_theta_min 2.418 _cell_volume 6054.9(6) _computing_cell_refinement 'SAINT V8.40B (?, 2016)' _computing_data_reduction 'SAINT V8.40B (?, 2016)' _computing_molecular_graphics 'Olex2 1.5 (Dolomanov et al., 2009)' _computing_publication_material 'Olex2 1.5 (Dolomanov et al., 2009)' _computing_structure_refinement 'SHELXL 2018/3 (Sheldrick, 2015)' _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' _diffrn_ambient_temperature 293.00 _diffrn_measured_fraction_theta_full 0.996 _diffrn_measured_fraction_theta_max 0.996 _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_radiation_monochromator graphite _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0813 _diffrn_reflns_av_unetI/netI 0.0414 _diffrn_reflns_Laue_measured_fraction_full 0.996 _diffrn_reflns_Laue_measured_fraction_max 0.996 _diffrn_reflns_limit_h_max 25 _diffrn_reflns_limit_h_min -25 _diffrn_reflns_limit_k_max 26 _diffrn_reflns_limit_k_min -26 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_number 64995 _diffrn_reflns_point_group_measured_fraction_full 0.995 _diffrn_reflns_point_group_measured_fraction_max 0.995 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 25.500 _diffrn_reflns_theta_min 2.029 _diffrn_source_current 1.4 _diffrn_source_power 0.07 _diffrn_source_voltage 50.0 _diffrn_standards_number 0 _exptl_absorpt_coefficient_mu 26.001 _exptl_absorpt_correction_T_max 0.7456 _exptl_absorpt_correction_T_min 0.4999 _exptl_absorpt_correction_type none _exptl_absorpt_process_details ; SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1207 before and 0.0828 after correction. The Ratio of minimum to maximum transmission is 0.6705. The \l/2 correction factor is Not present. ; _exptl_crystal_colour 'clear reddish red' _exptl_crystal_colour_lustre clear _exptl_crystal_colour_modifier reddish _exptl_crystal_colour_primary red _exptl_crystal_density_diffrn 5.156 _exptl_crystal_description block _exptl_crystal_F_000 8072 _exptl_crystal_size_max 0.004 _exptl_crystal_size_mid 0.003 _exptl_crystal_size_min 0.002 _refine_diff_density_max 0.948 _refine_diff_density_min -0.901 _refine_diff_density_rms 0.211 _refine_ls_abs_structure_details ; Refined as an inversion twin. ; _refine_ls_abs_structure_Flack 0.038(7) _refine_ls_extinction_coef 0.000045(5) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_extinction_method 'SHELXL-2018/3 (Sheldrick 2018)' _refine_ls_goodness_of_fit_ref 1.095 _refine_ls_hydrogen_treatment undef _refine_ls_matrix_type full _refine_ls_number_parameters 246 _refine_ls_number_reflns 5772 _refine_ls_number_restraints 1 _refine_ls_restrained_S_all 1.095 _refine_ls_R_factor_all 0.0229 _refine_ls_R_factor_gt 0.0216 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+7.0482P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0440 _refine_ls_wR_factor_ref 0.0443 _reflns_Friedel_coverage 0.909 _reflns_Friedel_fraction_full 0.994 _reflns_Friedel_fraction_max 0.994 _reflns_number_gt 5585 _reflns_number_total 5772 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file d6dt00409a2.cif _cod_data_source_block 19-10-long _cod_database_code 7721163 _shelx_shelxl_version_number 2018/3 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _diffrn_oxdiff_ac3_digest_hkl 41f80dc5b8c5d4a63edc57d58255c87b0d2d8d _olex2_refinement_description ; 1. Twinned data refinement Scales: 0.962(7) 0.038(7) ; _shelx_res_file ; TITL a in Cmc2(1) 19-10-long.res created by SHELXL-2018/3 at 12:44:04 on 07-Jan-2026 CELL 0.71073 20.7867 21.5042 13.5456 90 90 90 ZERR 4 0.0013 0.0011 0.0008 0 0 0 LATT -7 SYMM -X,-Y,0.5+Z SYMM +X,-Y,0.5+Z SYMM -X,+Y,+Z SFAC Cd Cl In Rb Se UNIT 44 4 36 16 104 L.S. 20 PLAN 5 CONF MORE -1 fmap 2 acta TWIN -1 0 0 0 -1 0 0 0 -1 2 OMIT -3 51 OMIT 0 2 0 OMIT 2 0 0 REM REM REM WGHT 0.000000 7.048200 EXTI 0.000045 BASF 0.03789 FVAR 0.02990 RB1 4 0.500000 0.857611 0.727485 10.50000 0.06917 0.02534 = 0.04826 0.01047 0.00000 0.00000 RB2 4 0.877004 0.843419 0.230744 11.00000 0.03836 0.05402 = 0.05467 0.00643 -0.01031 0.01682 RB3 4 0.500000 0.723869 0.022945 10.50000 0.06602 0.05699 = 0.02097 0.00111 0.00000 0.00000 CD1 1 0.797014 0.666489 0.429085 11.00000 0.01588 0.01286 = 0.01563 -0.00126 -0.00186 0.00180 CD2 1 0.500000 0.502985 0.430232 10.50000 0.01353 0.01477 = 0.01709 0.00319 0.00000 0.00000 CD3 1 0.597414 0.668757 0.418814 11.00000 0.01917 0.01693 = 0.01992 -0.00083 0.00070 -0.00066 CD4 1 0.696917 0.828143 0.426076 11.00000 0.01972 0.01835 = 0.02191 -0.00109 -0.00215 0.00085 CD5 1 0.693632 0.503944 0.424698 11.00000 0.01866 0.02002 = 0.02101 0.00214 0.00044 -0.00031 CD6 1 0.797415 0.554227 0.185558 11.00000 0.01884 0.02170 = 0.01815 -0.00049 0.00016 0.00293 IN1 3 0.500000 0.833414 0.419575 10.50000 0.01699 0.01604 = 0.01778 0.00110 0.00000 0.00000 IN2 3 0.599749 0.556301 0.175511 11.00000 0.01811 0.02226 = 0.01697 -0.00088 -0.00060 -0.00023 IN3 3 0.901739 0.500557 0.425819 11.00000 0.02037 0.01875 = 0.02173 -0.00049 0.00035 0.00282 IN4 3 0.699547 0.721548 0.175868 11.00000 0.02422 0.01786 = 0.01690 0.00064 -0.00046 0.00139 IN5 3 0.601394 0.890661 0.175977 11.00000 0.02249 0.01783 = 0.01739 -0.00003 0.00106 0.00010 SE1 5 0.590554 0.671857 0.228762 11.00000 0.01947 0.01748 = 0.01614 -0.00043 0.00021 -0.00031 SE2 5 0.706878 0.836800 0.234572 11.00000 0.01912 0.01542 = 0.01694 -0.00076 -0.00151 0.00143 SE3 5 0.500000 0.825737 0.230363 10.50000 0.01768 0.01541 = 0.01443 0.00100 0.00000 0.00000 SE4 5 0.903831 0.722067 0.006454 11.00000 0.01738 0.01445 = 0.01830 0.00030 0.00243 0.00076 SE5 5 0.808618 0.782073 0.481902 11.00000 0.01917 0.01381 = 0.01489 -0.00109 -0.00057 0.00098 SE6 5 0.596589 0.565846 -0.017744 11.00000 0.01513 0.01710 = 0.01542 -0.00170 0.00009 -0.00162 SE7 5 0.906531 0.617875 0.482076 11.00000 0.01737 0.01609 = 0.01503 -0.00048 -0.00157 0.00276 SE8 5 0.500000 0.612344 0.506329 10.50000 0.01783 0.01521 = 0.01722 0.00163 0.00000 0.00000 SE9 5 0.500000 0.942351 0.502279 10.50000 0.01599 0.01242 = 0.01613 0.00146 0.00000 0.00000 SE10 5 0.807327 0.671669 0.237619 11.00000 0.02216 0.01725 = 0.01390 -0.00039 -0.00134 0.00349 SE11 5 0.803469 0.990639 0.233673 11.00000 0.01728 0.02033 = 0.01745 0.00136 0.00075 -0.00096 SE12 5 0.907236 0.505083 0.234094 11.00000 0.01724 0.01418 = 0.01697 -0.00084 -0.00132 0.00132 SE13 5 0.702563 0.944880 0.489662 11.00000 0.01481 0.01349 = 0.01341 -0.00069 0.00054 -0.00136 SE14 5 0.500000 0.508561 0.737707 10.50000 0.01547 0.02001 = 0.01337 -0.00282 0.00000 0.00000 SE15 5 0.696629 0.614316 0.502467 11.00000 0.01711 0.01718 = 0.01798 -0.00020 0.00081 0.00112 CL1 2 0.500000 0.722157 -0.202087 10.50000 0.03052 0.03030 = 0.03163 0.00241 0.00000 0.00000 HKLF 4 REM a in Cmc2(1) REM wR2 = 0.0443, GooF = S = 1.095, Restrained GooF = 1.095 for all data REM R1 = 0.0216 for 5585 Fo > 4sig(Fo) and 0.0229 for all 5772 data REM 246 parameters refined using 1 restraints END WGHT 0.0000 7.0578 REM Highest difference peak 0.948, deepest hole -0.901, 1-sigma level 0.211 Q1 1 0.5000 0.7207 -0.0514 10.50000 0.05 0.95 Q2 1 0.5000 0.6757 -0.1736 10.50000 0.05 0.83 Q3 1 0.8002 0.6873 0.3947 11.00000 0.05 0.82 Q4 1 0.5000 0.5091 0.6826 10.50000 0.05 0.81 Q5 1 0.5247 0.7390 0.0037 11.00000 0.05 0.79 ; _shelx_res_checksum 59059 _olex2_submission_special_instructions 'No special instructions were received' loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, z+1/2' 'x, -y, z+1/2' '-x, y, z' 'x+1/2, y+1/2, z' '-x+1/2, -y+1/2, z+1/2' 'x+1/2, -y+1/2, z+1/2' '-x+1/2, y+1/2, z' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_refinement_flags_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Rb1 Rb 0.500000 0.85761(6) 0.72749(13) 0.0476(4) Uani 1 2 d S T P . . Rb2 Rb 0.87700(5) 0.84342(5) 0.23074(10) 0.0490(3) Uani 1 1 d . . . . . Rb3 Rb 0.500000 0.72387(8) 0.02295(12) 0.0480(4) Uani 1 2 d S T P . . Cd1 Cd 0.79701(2) 0.66649(3) 0.42908(5) 0.01479(13) Uani 1 1 d . . . . . Cd2 Cd 0.500000 0.50298(4) 0.43023(8) 0.01513(17) Uani 1 2 d S T P . . Cd3 Cd 0.59741(3) 0.66876(3) 0.41881(5) 0.01867(14) Uani 1 1 d . . . . . Cd4 Cd 0.69692(3) 0.82814(3) 0.42608(6) 0.01999(14) Uani 1 1 d . . . . . Cd5 Cd 0.69363(2) 0.50394(3) 0.42470(6) 0.01990(14) Uani 1 1 d . . . . . Cd6 Cd 0.79742(3) 0.55423(3) 0.18556(6) 0.01956(14) Uani 1 1 d . . . . . In1 In 0.500000 0.83341(4) 0.41958(8) 0.01694(18) Uani 1 2 d S T P . . In2 In 0.59975(3) 0.55630(3) 0.17551(5) 0.01911(14) Uani 1 1 d . . . . . In3 In 0.90174(2) 0.50056(3) 0.42582(6) 0.02028(13) Uani 1 1 d . . . . . In4 In 0.69955(3) 0.72155(3) 0.17587(5) 0.01966(14) Uani 1 1 d . . . . . In5 In 0.60139(3) 0.89066(3) 0.17598(6) 0.01924(14) Uani 1 1 d . . . . . Se1 Se 0.59055(4) 0.67186(4) 0.22876(6) 0.01770(18) Uani 1 1 d . . . . . Se2 Se 0.70688(4) 0.83680(4) 0.23457(7) 0.01716(18) Uani 1 1 d . . . . . Se3 Se 0.500000 0.82574(5) 0.23036(10) 0.0158(2) Uani 1 2 d S T P . . Se4 Se 0.90383(4) 0.72207(4) 0.00645(7) 0.01671(18) Uani 1 1 d . . . . . Se5 Se 0.80862(4) 0.78207(4) 0.48190(7) 0.01596(18) Uani 1 1 d . . . . . Se6 Se 0.59659(4) 0.56585(4) -0.01774(7) 0.01588(19) Uani 1 1 d . . . . . Se7 Se 0.90653(4) 0.61788(4) 0.48208(6) 0.01616(18) Uani 1 1 d . . . . . Se8 Se 0.500000 0.61234(5) 0.50633(10) 0.0168(2) Uani 1 2 d S T P . . Se9 Se 0.500000 0.94235(5) 0.50228(9) 0.0148(2) Uani 1 2 d S T P . . Se10 Se 0.80733(4) 0.67167(4) 0.23762(7) 0.01777(18) Uani 1 1 d . . . . . Se11 Se 0.80347(3) 0.99064(4) 0.23367(7) 0.01835(19) Uani 1 1 d . . . . . Se12 Se 0.90724(4) 0.50508(4) 0.23409(6) 0.01613(19) Uani 1 1 d . . . . . Se13 Se 0.70256(4) 0.94488(4) 0.48966(6) 0.01390(19) Uani 1 1 d . . . . . Se14 Se 0.500000 0.50856(5) 0.73771(9) 0.0163(3) Uani 1 2 d S T P . . Se15 Se 0.69663(4) 0.61432(4) 0.50247(7) 0.01742(19) Uani 1 1 d . . . . . Cl1 Cl 0.500000 0.72216(15) -0.2021(3) 0.0308(7) Uani 1 2 d S T P . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rb1 0.0692(10) 0.0253(7) 0.0483(10) 0.0105(7) 0.000 0.000 Rb2 0.0384(6) 0.0540(6) 0.0547(7) 0.0064(6) -0.0103(6) 0.0168(5) Rb3 0.0660(11) 0.0570(10) 0.0210(8) 0.0011(7) 0.000 0.000 Cd1 0.0159(3) 0.0129(3) 0.0156(3) -0.0013(3) -0.0019(3) 0.0018(2) Cd2 0.0135(3) 0.0148(4) 0.0171(4) 0.0032(4) 0.000 0.000 Cd3 0.0192(3) 0.0169(3) 0.0199(3) -0.0008(3) 0.0007(3) -0.0007(2) Cd4 0.0197(3) 0.0183(3) 0.0219(4) -0.0011(3) -0.0021(3) 0.0009(2) Cd5 0.0187(3) 0.0200(3) 0.0210(4) 0.0021(3) 0.0004(3) -0.0003(2) Cd6 0.0188(3) 0.0217(3) 0.0181(3) -0.0005(3) 0.0002(3) 0.0029(2) In1 0.0170(4) 0.0160(4) 0.0178(4) 0.0011(4) 0.000 0.000 In2 0.0181(3) 0.0223(3) 0.0170(3) -0.0009(3) -0.0006(3) -0.0002(2) In3 0.0204(3) 0.0187(3) 0.0217(3) -0.0005(3) 0.0004(3) 0.0028(2) In4 0.0242(3) 0.0179(3) 0.0169(3) 0.0006(3) -0.0005(3) 0.0014(2) In5 0.0225(3) 0.0178(3) 0.0174(3) 0.0000(3) 0.0011(3) 0.0001(2) Se1 0.0195(4) 0.0175(4) 0.0161(4) -0.0004(4) 0.0002(4) -0.0003(3) Se2 0.0191(4) 0.0154(4) 0.0169(5) -0.0008(4) -0.0015(4) 0.0014(3) Se3 0.0177(5) 0.0154(5) 0.0144(6) 0.0010(5) 0.000 0.000 Se4 0.0174(4) 0.0145(4) 0.0183(4) 0.0003(4) 0.0024(4) 0.0008(3) Se5 0.0192(4) 0.0138(4) 0.0149(4) -0.0011(3) -0.0006(3) 0.0010(3) Se6 0.0151(4) 0.0171(4) 0.0154(5) -0.0017(3) 0.0001(3) -0.0016(3) Se7 0.0174(4) 0.0161(4) 0.0150(4) -0.0005(3) -0.0016(3) 0.0028(3) Se8 0.0178(6) 0.0152(6) 0.0172(6) 0.0016(5) 0.000 0.000 Se9 0.0160(6) 0.0124(6) 0.0161(6) 0.0015(5) 0.000 0.000 Se10 0.0222(4) 0.0173(4) 0.0139(5) -0.0004(4) -0.0013(4) 0.0035(3) Se11 0.0173(4) 0.0203(4) 0.0174(5) 0.0014(4) 0.0008(4) -0.0010(3) Se12 0.0172(4) 0.0142(4) 0.0170(5) -0.0008(4) -0.0013(3) 0.0013(3) Se13 0.0148(4) 0.0135(4) 0.0134(5) -0.0007(4) 0.0005(3) -0.0014(3) Se14 0.0155(5) 0.0200(6) 0.0134(7) -0.0028(5) 0.000 0.000 Se15 0.0171(4) 0.0172(4) 0.0180(5) -0.0002(4) 0.0008(4) 0.0011(3) Cl1 0.0305(16) 0.0303(17) 0.0316(18) 0.0024(15) 0.000 0.000 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag In1 Rb1 Rb3 137.19(4) . 1_556 ? Se4 Rb1 Rb3 111.04(3) 7_465 1_556 ? Se4 Rb1 Rb3 111.04(3) 6_665 1_556 ? Se4 Rb1 In1 37.03(2) 6_665 . ? Se4 Rb1 In1 37.03(2) 7_465 . ? Se4 Rb1 Se4 60.18(3) 7_465 6_665 ? Se4 Rb1 Se7 161.66(4) 7_465 6_665 ? Se4 Rb1 Se7 117.47(2) 6_665 6_665 ? Se4 Rb1 Se7 117.47(2) 7_465 7_465 ? Se4 Rb1 Se7 161.66(4) 6_665 7_465 ? Se4 Rb1 Se10 116.98(4) 6_665 7_465 ? Se4 Rb1 Se10 116.98(4) 7_465 6_665 ? Se4 Rb1 Se10 57.57(2) 7_465 7_465 ? Se4 Rb1 Se10 57.57(2) 6_665 6_665 ? Se7 Rb1 Rb3 51.37(3) 6_665 1_556 ? Se7 Rb1 Rb3 51.37(3) 7_465 1_556 ? Se7 Rb1 In1 150.847(17) 6_665 . ? Se7 Rb1 In1 150.847(17) 7_465 . ? Se7 Rb1 Se7 58.23(3) 6_665 7_465 ? Se7 Rb1 Se10 60.72(2) 7_465 7_465 ? Se7 Rb1 Se10 118.14(4) 7_465 6_665 ? Se7 Rb1 Se10 60.72(2) 6_665 6_665 ? Se7 Rb1 Se10 118.14(4) 6_665 7_465 ? Se9 Rb1 Rb3 175.15(5) . 1_556 ? Se9 Rb1 In1 37.96(3) . . ? Se9 Rb1 Se4 64.89(3) . 7_465 ? Se9 Rb1 Se4 64.89(3) . 6_665 ? Se9 Rb1 Se7 132.35(4) . 6_665 ? Se9 Rb1 Se7 132.35(4) . 7_465 ? Se9 Rb1 Se10 96.24(3) . 6_665 ? Se9 Rb1 Se10 96.24(3) . 7_465 ? Se10 Rb1 Rb3 83.22(3) 7_465 1_556 ? Se10 Rb1 Rb3 83.22(3) 6_665 1_556 ? Se10 Rb1 In1 90.82(3) 6_665 . ? Se10 Rb1 In1 90.82(3) 7_465 . ? Se10 Rb1 Se10 161.72(5) 7_465 6_665 ? Se12 Rb1 Rb3 117.89(4) 6_665 1_556 ? Se12 Rb1 Rb3 117.89(4) 7_465 1_556 ? Se12 Rb1 In1 97.40(4) 6_665 . ? Se12 Rb1 In1 97.40(4) 7_465 . ? Se12 Rb1 Se4 130.76(5) 7_465 6_665 ? Se12 Rb1 Se4 96.01(3) 6_665 6_665 ? Se12 Rb1 Se4 130.76(5) 6_665 7_465 ? Se12 Rb1 Se4 96.01(3) 7_465 7_465 ? Se12 Rb1 Se7 66.52(3) 7_465 7_465 ? Se12 Rb1 Se7 97.67(4) 6_665 7_465 ? Se12 Rb1 Se7 97.67(4) 7_465 6_665 ? Se12 Rb1 Se7 66.52(3) 6_665 6_665 ? Se12 Rb1 Se9 65.95(3) 6_665 . ? Se12 Rb1 Se9 65.95(3) 7_465 . ? Se12 Rb1 Se10 65.756(18) 6_665 6_665 ? Se12 Rb1 Se10 131.97(4) 6_665 7_465 ? Se12 Rb1 Se10 131.97(4) 7_465 6_665 ? Se12 Rb1 Se10 65.756(18) 7_465 7_465 ? Se12 Rb1 Se12 66.27(4) 6_665 7_465 ? Cl1 Rb1 Rb3 36.16(7) 1_556 1_556 ? Cl1 Rb1 In1 101.02(8) 1_556 . ? Cl1 Rb1 Se4 79.94(6) 1_556 7_465 ? Cl1 Rb1 Se4 79.94(6) 1_556 6_665 ? Cl1 Rb1 Se7 81.76(7) 1_556 7_465 ? Cl1 Rb1 Se7 81.76(7) 1_556 6_665 ? Cl1 Rb1 Se9 138.99(9) 1_556 . ? Cl1 Rb1 Se10 80.91(2) 1_556 6_665 ? Cl1 Rb1 Se10 80.91(2) 1_556 7_465 ? Cl1 Rb1 Se12 141.96(4) 1_556 7_465 ? Cl1 Rb1 Se12 141.96(4) 1_556 6_665 ? Cd3 Rb2 Rb3 135.44(3) 6_664 6_665 ? Se2 Rb2 Rb3 119.65(3) . 6_665 ? Se2 Rb2 Cd3 97.85(3) . 6_664 ? Se2 Rb2 Se4 97.06(3) . . ? Se2 Rb2 Se5 67.11(3) . . ? Se2 Rb2 Se6 98.37(3) . 6_665 ? Se2 Rb2 Se8 130.22(4) . 6_664 ? Se2 Rb2 Se10 66.27(3) . . ? Se2 Rb2 Se14 131.03(3) . 6_664 ? Se2 Rb2 Se15 66.07(3) . 6_664 ? Se4 Rb2 Rb3 110.02(3) . 6_665 ? Se4 Rb2 Cd3 36.790(19) . 6_664 ? Se4 Rb2 Se8 60.32(3) . 6_664 ? Se4 Rb2 Se14 115.72(3) . 6_664 ? Se5 Rb2 Rb3 52.54(2) . 6_665 ? Se5 Rb2 Cd3 152.24(4) . 6_664 ? Se5 Rb2 Se4 119.04(3) . . ? Se5 Rb2 Se6 57.96(3) . 6_665 ? Se5 Rb2 Se8 162.23(3) . 6_664 ? Se5 Rb2 Se10 62.20(3) . . ? Se5 Rb2 Se14 118.02(4) . 6_664 ? Se6 Rb2 Rb3 51.87(3) 6_665 6_665 ? Se6 Rb2 Cd3 149.77(4) 6_665 6_664 ? Se6 Rb2 Se4 160.78(3) 6_665 . ? Se6 Rb2 Se8 116.00(3) 6_665 6_664 ? Se6 Rb2 Se10 119.24(4) 6_665 . ? Se6 Rb2 Se14 60.65(3) 6_665 6_664 ? Se8 Rb2 Rb3 109.96(3) 6_664 6_665 ? Se8 Rb2 Cd3 36.80(2) 6_664 6_664 ? Se10 Rb2 Rb3 84.10(3) . 6_665 ? Se10 Rb2 Cd3 90.67(3) . 6_664 ? Se10 Rb2 Se4 57.81(2) . . ? Se10 Rb2 Se8 117.56(4) . 6_664 ? Se10 Rb2 Se14 162.44(3) . 6_664 ? Se11 Rb2 Rb3 118.74(4) . 6_665 ? Se11 Rb2 Cd3 96.93(3) . 6_664 ? Se11 Rb2 Se2 66.53(2) . . ? Se11 Rb2 Se4 130.51(4) . . ? Se11 Rb2 Se5 97.80(3) . . ? Se11 Rb2 Se6 66.88(3) . 6_665 ? Se11 Rb2 Se8 94.06(3) . 6_664 ? Se11 Rb2 Se10 132.78(4) . . ? Se11 Rb2 Se14 64.54(2) . 6_664 ? Se11 Rb2 Se15 66.04(3) . 6_664 ? Se14 Rb2 Rb3 83.43(3) 6_664 6_665 ? Se14 Rb2 Cd3 89.58(3) 6_664 6_664 ? Se14 Rb2 Se8 56.20(3) 6_664 6_664 ? Se15 Rb2 Rb3 173.31(4) 6_664 6_665 ? Se15 Rb2 Cd3 37.89(2) 6_664 6_664 ? Se15 Rb2 Se4 64.68(3) 6_664 . ? Se15 Rb2 Se5 133.08(4) 6_664 . ? Se15 Rb2 Se6 132.75(3) 6_664 6_665 ? Se15 Rb2 Se8 64.16(3) 6_664 6_664 ? Se15 Rb2 Se10 95.79(3) 6_664 . ? Se15 Rb2 Se14 95.17(3) 6_664 6_664 ? Cl1 Rb2 Rb3 36.11(7) 6_665 6_665 ? Cl1 Rb2 Cd3 99.33(7) 6_665 6_664 ? Cl1 Rb2 Se2 144.32(7) 6_665 . ? Cl1 Rb2 Se4 79.09(7) 6_665 . ? Cl1 Rb2 Se5 83.67(6) 6_665 . ? Cl1 Rb2 Se6 81.69(7) 6_665 6_665 ? Cl1 Rb2 Se8 78.79(6) 6_665 6_664 ? Cl1 Rb2 Se10 82.47(6) 6_665 . ? Cl1 Rb2 Se11 140.83(7) 6_665 . ? Cl1 Rb2 Se14 80.16(6) 6_665 6_664 ? Cl1 Rb2 Se15 137.22(8) 6_665 6_664 ? Rb1 Rb3 Rb2 61.26(3) 1_554 7_464 ? Se1 Rb3 Rb1 145.36(3) . 1_554 ? Se1 Rb3 Rb1 145.36(3) 4_655 1_554 ? Se1 Rb3 Rb2 105.28(3) 4_655 7_464 ? Se1 Rb3 Rb2 144.52(5) . 7_464 ? Se1 Rb3 Se1 64.14(4) 4_655 . ? Se1 Rb3 Se3 64.77(3) . . ? Se1 Rb3 Se3 64.77(3) 4_655 . ? Se1 Rb3 Se5 64.73(2) . 6_664 ? Se1 Rb3 Se5 64.73(2) 4_655 7_464 ? Se1 Rb3 Se5 128.64(4) . 7_464 ? Se1 Rb3 Se5 128.64(4) 4_655 6_664 ? Se1 Rb3 Se6 96.16(4) 4_655 . ? Se1 Rb3 Se6 64.67(3) 4_655 4_655 ? Se1 Rb3 Se6 64.67(3) . . ? Se1 Rb3 Se6 96.16(4) . 4_655 ? Se1 Rb3 Se7 96.93(3) 4_655 7_464 ? Se1 Rb3 Se7 129.94(5) 4_655 6_664 ? Se1 Rb3 Se7 96.93(3) . 6_664 ? Se1 Rb3 Se7 129.94(5) . 7_464 ? Se3 Rb3 Rb1 106.36(5) . 1_554 ? Se3 Rb3 Rb2 144.47(3) . 7_464 ? Se3 Rb3 Se5 97.39(3) . 7_464 ? Se3 Rb3 Se5 97.39(3) . 6_664 ? Se3 Rb3 Se6 129.30(4) . . ? Se3 Rb3 Se6 129.30(4) . 4_655 ? Se3 Rb3 Se7 65.26(3) . 6_664 ? Se3 Rb3 Se7 65.26(3) . 7_464 ? Se5 Rb3 Rb1 84.62(3) 7_464 1_554 ? Se5 Rb3 Rb1 84.62(3) 6_664 1_554 ? Se5 Rb3 Rb2 113.14(4) 6_664 7_464 ? Se5 Rb3 Rb2 50.67(2) 7_464 7_464 ? Se5 Rb3 Se5 163.68(5) 7_464 6_664 ? Se6 Rb3 Rb1 112.66(4) 4_655 1_554 ? Se6 Rb3 Rb1 112.66(4) . 1_554 ? Se6 Rb3 Rb2 84.26(4) . 7_464 ? Se6 Rb3 Rb2 51.49(3) 4_655 7_464 ? Se6 Rb3 Se5 116.90(4) . 7_464 ? Se6 Rb3 Se5 56.98(2) . 6_664 ? Se6 Rb3 Se5 116.90(4) 4_655 6_664 ? Se6 Rb3 Se5 56.98(2) 4_655 7_464 ? Se6 Rb3 Se6 60.50(3) 4_655 . ? Se7 Rb3 Rb1 52.02(3) 6_664 1_554 ? Se7 Rb3 Rb1 52.02(3) 7_464 1_554 ? Se7 Rb3 Rb2 83.43(3) 7_464 7_464 ? Se7 Rb3 Rb2 113.25(4) 6_664 7_464 ? Se7 Rb3 Se5 119.60(4) 7_464 6_664 ? Se7 Rb3 Se5 61.45(2) 6_664 6_664 ? Se7 Rb3 Se5 61.45(2) 7_464 7_464 ? Se7 Rb3 Se5 119.60(4) 6_664 7_464 ? Se7 Rb3 Se6 117.81(2) 6_664 . ? Se7 Rb3 Se6 163.99(5) 6_664 4_655 ? Se7 Rb3 Se6 117.81(2) 7_464 4_655 ? Se7 Rb3 Se6 163.99(5) 7_464 . ? Se7 Rb3 Se7 58.80(3) 6_664 7_464 ? Cl1 Rb3 Rb1 36.39(7) . 1_554 ? Cl1 Rb3 Rb2 36.25(4) . 7_464 ? Cl1 Rb3 Se1 141.50(5) . . ? Cl1 Rb3 Se1 141.50(5) . 4_655 ? Cl1 Rb3 Se3 142.75(9) . . ? Cl1 Rb3 Se5 82.03(3) . 7_464 ? Cl1 Rb3 Se5 82.03(3) . 6_664 ? Cl1 Rb3 Se6 81.45(7) . 4_655 ? Cl1 Rb3 Se6 81.45(7) . . ? Cl1 Rb3 Se7 82.56(7) . 7_464 ? Cl1 Rb3 Se7 82.56(7) . 6_664 ? Se5 Cd1 Se7 103.11(3) . . ? Se5 Cd1 Se10 103.04(3) . . ? Se10 Cd1 Se7 102.68(3) . . ? Se15 Cd1 Se5 112.75(3) . . ? Se15 Cd1 Se7 115.33(4) . . ? Se15 Cd1 Se10 118.08(4) . . ? Se6 Cd2 Se6 101.53(5) 2_665 3_565 ? Se6 Cd2 Se14 102.50(3) 3_565 2_664 ? Se6 Cd2 Se14 102.50(3) 2_665 2_664 ? Se8 Cd2 Se6 114.45(3) . 3_565 ? Se8 Cd2 Se6 114.45(3) . 2_665 ? Se8 Cd2 Se14 119.11(5) . 2_664 ? Se1 Cd3 Rb2 175.51(3) . 6_665 ? Se1 Cd3 Se4 115.26(4) . 6_665 ? Se1 Cd3 Se8 114.67(4) . . ? Se1 Cd3 Se15 119.03(4) . . ? Se4 Cd3 Rb2 66.99(3) 6_665 6_665 ? Se4 Cd3 Se8 101.52(4) 6_665 . ? Se8 Cd3 Rb2 67.85(3) . 6_665 ? Se15 Cd3 Rb2 56.49(3) . 6_665 ? Se15 Cd3 Se4 102.16(3) . 6_665 ? Se15 Cd3 Se8 101.74(4) . . ? Se2 Cd4 Se5 104.02(3) . . ? Se2 Cd4 Se13 104.56(3) . . ? Se4 Cd4 Se2 120.72(4) 6_665 . ? Se4 Cd4 Se5 115.73(4) 6_665 . ? Se4 Cd4 Se13 107.02(4) 6_665 . ? Se5 Cd4 Se13 102.90(3) . . ? Se6 Cd5 Se13 104.59(3) 3_565 8_645 ? Se11 Cd5 Se6 104.44(3) 8_645 3_565 ? Se11 Cd5 Se13 104.95(3) 8_645 8_645 ? Se15 Cd5 Se6 114.79(3) . 3_565 ? Se15 Cd5 Se11 120.19(4) . 8_645 ? Se15 Cd5 Se13 106.46(3) . 8_645 ? Se10 Cd6 Se13 105.14(4) . 6_664 ? Se11 Cd6 Se10 120.23(4) 8_645 . ? Se11 Cd6 Se12 115.67(4) 8_645 . ? Se11 Cd6 Se13 104.83(3) 8_645 6_664 ? Se12 Cd6 Se10 104.70(3) . . ? Se12 Cd6 Se13 104.81(3) . 6_664 ? Se3 In1 Rb1 176.57(4) . . ? Se3 In1 Se4 114.89(3) . 6_665 ? Se3 In1 Se4 114.89(3) . 7_465 ? Se3 In1 Se9 119.24(5) . . ? Se4 In1 Rb1 66.98(3) 7_465 . ? Se4 In1 Rb1 66.98(3) 6_665 . ? Se4 In1 Se4 100.05(5) 7_465 6_665 ? Se9 In1 Rb1 57.33(4) . . ? Se9 In1 Se4 102.59(4) . 6_665 ? Se9 In1 Se4 102.59(4) . 7_465 ? Se1 In2 Se6 101.56(4) . . ? Se1 In2 Se14 111.09(4) . 2_664 ? Se6 In2 Se14 109.88(4) . 2_664 ? Se11 In2 Se1 119.77(4) 8_645 . ? Se11 In2 Se6 111.50(4) 8_645 . ? Se11 In2 Se14 103.06(4) 8_645 2_664 ? Se9 In3 Se7 108.33(4) 5_545 . ? Se9 In3 Se13 107.28(4) 5_545 8_645 ? Se12 In3 Se7 104.54(3) . . ? Se12 In3 Se9 112.32(4) . 5_545 ? Se12 In3 Se13 112.49(4) . 8_645 ? Se13 In3 Se7 111.87(3) 8_645 . ? Se1 In4 Se2 110.90(3) . . ? Se1 In4 Se5 101.90(4) . 6_664 ? Se1 In4 Se10 119.19(4) . . ? Se2 In4 Se5 109.64(4) . 6_664 ? Se2 In4 Se10 103.99(3) . . ? Se10 In4 Se5 111.18(3) . 6_664 ? Se2 In5 Se3 110.67(3) . . ? Se2 In5 Se7 108.97(4) . 6_664 ? Se3 In5 Se7 101.05(4) . 6_664 ? Se12 In5 Se2 112.85(3) 8_655 . ? Se12 In5 Se3 111.30(3) 8_655 . ? Se12 In5 Se7 111.37(4) 8_655 6_664 ? Cd3 Se1 Rb3 145.34(4) . . ? Cd3 Se1 In2 104.40(4) . . ? Cd3 Se1 In4 103.71(4) . . ? In2 Se1 Rb3 97.05(4) . . ? In2 Se1 In4 104.61(3) . . ? In4 Se1 Rb3 96.66(3) . . ? Cd4 Se2 Rb2 95.55(3) . . ? In4 Se2 Rb2 95.29(3) . . ? In4 Se2 Cd4 103.34(3) . . ? In5 Se2 Rb2 144.99(4) . . ? In5 Se2 Cd4 105.55(4) . . ? In5 Se2 In4 106.30(3) . . ? In1 Se3 Rb3 145.74(5) . . ? In1 Se3 In5 104.19(4) . 4_655 ? In1 Se3 In5 104.19(4) . . ? In5 Se3 Rb3 96.05(4) 4_655 . ? In5 Se3 Rb3 96.05(4) . . ? In5 Se3 In5 106.34(5) . 4_655 ? Rb1 Se4 Rb2 77.42(3) 6_664 . ? Cd3 Se4 Rb1 136.66(4) 6_664 6_664 ? Cd3 Se4 Rb2 76.22(3) 6_664 . ? Cd4 Se4 Rb1 122.74(3) 6_664 6_664 ? Cd4 Se4 Rb2 118.19(3) 6_664 . ? Cd4 Se4 Cd3 100.02(4) 6_664 6_664 ? Cd4 Se4 In1 103.82(4) 6_664 6_664 ? In1 Se4 Rb1 75.99(3) 6_664 6_664 ? In1 Se4 Rb2 137.71(4) 6_664 . ? In1 Se4 Cd3 102.25(4) 6_664 6_664 ? Rb2 Se5 Rb3 76.79(3) . 6_665 ? Cd1 Se5 Rb2 96.71(3) . . ? Cd1 Se5 Rb3 95.72(3) . 6_665 ? Cd1 Se5 Cd4 101.47(3) . . ? Cd1 Se5 In4 103.91(4) . 6_665 ? Cd4 Se5 Rb2 86.78(3) . . ? Cd4 Se5 Rb3 157.49(4) . 6_665 ? In4 Se5 Rb2 154.15(4) 6_665 . ? In4 Se5 Rb3 85.69(3) 6_665 6_665 ? In4 Se5 Cd4 103.92(4) 6_665 . ? Rb2 Se6 Rb3 76.64(3) 6_664 . ? Cd2 Se6 Rb2 98.90(4) 2_664 6_664 ? Cd2 Se6 Rb3 97.72(3) 2_664 . ? Cd2 Se6 Cd5 100.81(3) 2_664 3_564 ? Cd2 Se6 In2 104.22(4) 2_664 . ? Cd5 Se6 Rb2 85.41(3) 3_564 6_664 ? Cd5 Se6 Rb3 155.95(4) 3_564 . ? In2 Se6 Rb2 153.06(4) . 6_664 ? In2 Se6 Rb3 86.64(3) . . ? In2 Se6 Cd5 103.38(4) . 3_564 ? Rb3 Se7 Rb1 76.61(3) 6_665 6_664 ? Cd1 Se7 Rb1 97.71(3) . 6_664 ? Cd1 Se7 Rb3 97.03(3) . 6_665 ? Cd1 Se7 In3 105.73(3) . . ? Cd1 Se7 In5 104.34(4) . 6_665 ? In3 Se7 Rb1 83.98(3) . 6_664 ? In3 Se7 Rb3 151.83(3) . 6_665 ? In3 Se7 In5 102.64(4) . 6_665 ? In5 Se7 Rb1 154.08(3) 6_665 6_664 ? In5 Se7 Rb3 87.21(3) 6_665 6_665 ? Rb2 Se8 Rb2 77.51(4) 6_665 7_465 ? Cd2 Se8 Rb2 120.80(4) . 7_465 ? Cd2 Se8 Rb2 120.80(4) . 6_665 ? Cd2 Se8 Cd3 103.91(4) . . ? Cd2 Se8 Cd3 103.91(4) . 4_655 ? Cd3 Se8 Rb2 134.99(4) 4_655 6_665 ? Cd3 Se8 Rb2 134.98(4) . 7_465 ? Cd3 Se8 Rb2 75.36(3) . 6_665 ? Cd3 Se8 Rb2 75.36(3) 4_655 7_465 ? Cd3 Se8 Cd3 100.10(5) 4_655 . ? In1 Se9 Rb1 84.71(5) . . ? In1 Se9 In3 105.16(4) . 5_455 ? In1 Se9 In3 105.16(4) . 8_655 ? In3 Se9 Rb1 125.92(3) 8_655 . ? In3 Se9 Rb1 125.92(3) 5_455 . ? In3 Se9 In3 103.00(5) 8_655 5_455 ? Rb2 Se10 Rb1 77.49(3) . 6_664 ? Cd1 Se10 Rb1 96.22(4) . 6_664 ? Cd1 Se10 Rb2 95.35(3) . . ? Cd1 Se10 Cd6 102.68(4) . . ? Cd1 Se10 In4 105.36(3) . . ? Cd6 Se10 Rb1 85.37(3) . 6_664 ? Cd6 Se10 Rb2 156.34(4) . . ? In4 Se10 Rb1 153.72(4) . 6_664 ? In4 Se10 Rb2 85.62(3) . . ? In4 Se10 Cd6 103.91(3) . . ? Cd5 Se11 Rb2 95.75(3) 8_655 . ? Cd6 Se11 Rb2 145.65(4) 8_655 . ? Cd6 Se11 Cd5 102.18(4) 8_655 8_655 ? In2 Se11 Rb2 98.65(3) 8_655 . ? In2 Se11 Cd5 103.01(3) 8_655 8_655 ? In2 Se11 Cd6 105.41(4) 8_655 8_655 ? Cd6 Se12 Rb1 97.66(3) . 6_664 ? Cd6 Se12 In3 103.24(3) . . ? In3 Se12 Rb1 94.63(4) . 6_664 ? In5 Se12 Rb1 145.63(4) 8_645 6_664 ? In5 Se12 Cd6 104.39(3) 8_645 . ? In5 Se12 In3 105.36(4) 8_645 . ? Cd5 Se13 Cd4 112.37(3) 8_655 . ? Cd6 Se13 Cd4 109.33(4) 6_665 . ? Cd6 Se13 Cd5 109.15(3) 6_665 8_655 ? In3 Se13 Cd4 106.73(3) 8_655 . ? In3 Se13 Cd5 110.13(4) 8_655 8_655 ? In3 Se13 Cd6 109.05(3) 8_655 6_665 ? Rb2 Se14 Rb2 77.52(3) 6_665 7_465 ? Cd2 Se14 Rb2 95.56(3) 2_665 7_465 ? Cd2 Se14 Rb2 95.56(3) 2_665 6_665 ? Cd2 Se14 In2 105.54(3) 2_665 2_665 ? Cd2 Se14 In2 105.54(3) 2_665 3_565 ? In2 Se14 Rb2 153.78(4) 2_665 6_665 ? In2 Se14 Rb2 153.78(4) 3_565 7_465 ? In2 Se14 Rb2 84.99(2) 2_665 7_465 ? In2 Se14 Rb2 84.99(2) 3_565 6_665 ? In2 Se14 In2 103.67(5) 2_665 3_565 ? Cd1 Se15 Rb2 124.92(4) . 6_665 ? Cd1 Se15 Cd3 106.02(4) . . ? Cd1 Se15 Cd5 105.16(3) . . ? Cd3 Se15 Rb2 85.62(3) . 6_665 ? Cd5 Se15 Rb2 125.03(4) . 6_665 ? Cd5 Se15 Cd3 102.32(3) . . ? Rb2 Cl1 Rb1 110.22(8) 6_664 1_554 ? Rb2 Cl1 Rb1 110.22(8) 7_464 1_554 ? Rb2 Cl1 Rb2 113.44(11) 7_464 6_664 ? Rb3 Cl1 Rb1 107.44(11) . 1_554 ? Rb3 Cl1 Rb2 107.64(8) . 7_464 ? Rb3 Cl1 Rb2 107.64(8) . 6_664 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rb1 Rb3 4.928(2) 1_556 ? Rb1 In1 4.203(2) . ? Rb1 Se4 3.9870(18) 7_465 ? Rb1 Se4 3.9870(18) 6_665 ? Rb1 Se7 3.9932(18) 6_665 ? Rb1 Se7 3.9932(18) 7_465 ? Rb1 Se9 3.553(2) . ? Rb1 Se10 4.0565(8) 7_465 ? Rb1 Se10 4.0565(8) 6_665 ? Rb1 Se12 3.5277(15) 7_465 ? Rb1 Se12 3.5277(15) 6_665 ? Rb1 Cl1 3.065(4) 1_556 ? Rb2 Rb3 4.9291(18) 6_665 ? Rb2 Cd3 4.2666(15) 6_664 ? Rb2 Se2 3.5396(14) . ? Rb2 Se4 4.0437(15) . ? Rb2 Se5 3.9160(16) . ? Rb2 Se6 3.9642(16) 6_665 ? Rb2 Se8 4.0844(16) 6_664 ? Rb2 Se10 3.9683(14) . ? Rb2 Se11 3.5157(14) . ? Rb2 Se14 4.0838(14) 6_664 ? Rb2 Se15 3.5680(15) 6_664 ? Rb2 Cl1 3.058(2) 6_665 ? Rb3 Se1 3.5449(16) . ? Rb3 Se1 3.5449(16) 4_655 ? Rb3 Se3 3.563(2) . ? Rb3 Se5 4.0189(9) 7_464 ? Rb3 Se5 4.0189(9) 6_664 ? Rb3 Se6 3.9853(17) . ? Rb3 Se6 3.9852(17) 4_655 ? Rb3 Se7 3.9576(17) 7_464 ? Rb3 Se7 3.9576(17) 6_664 ? Rb3 Cl1 3.048(4) . ? Cd1 Se5 2.5977(10) . ? Cd1 Se7 2.6059(10) . ? Cd1 Se10 2.6048(12) . ? Cd1 Se15 2.5692(10) . ? Cd2 Se6 2.5921(10) 2_665 ? Cd2 Se6 2.5921(10) 3_565 ? Cd2 Se8 2.5677(14) . ? Cd2 Se14 2.6196(15) 2_664 ? Cd3 Se1 2.5792(11) . ? Cd3 Se4 2.6309(11) 6_665 ? Cd3 Se8 2.6414(10) . ? Cd3 Se15 2.6283(10) . ? Cd4 Se2 2.6089(12) . ? Cd4 Se4 2.5956(10) 6_665 ? Cd4 Se5 2.6352(10) . ? Cd4 Se13 2.6566(11) . ? Cd5 Se6 2.6324(10) 3_565 ? Cd5 Se11 2.6040(11) 8_645 ? Cd5 Se13 2.6540(10) 8_645 ? Cd5 Se15 2.5975(11) . ? Cd6 Se10 2.6302(11) . ? Cd6 Se11 2.5869(10) 8_645 ? Cd6 Se12 2.6001(10) . ? Cd6 Se13 2.6536(10) 6_664 ? In1 Se3 2.5683(15) . ? In1 Se4 2.6085(10) 6_665 ? In1 Se4 2.6085(10) 7_465 ? In1 Se9 2.5967(14) . ? In2 Se1 2.5946(10) . ? In2 Se6 2.6266(10) . ? In2 Se11 2.5811(10) 8_645 ? In2 Se14 2.6371(9) 2_664 ? In3 Se7 2.6373(11) . ? In3 Se9 2.6098(9) 5_545 ? In3 Se12 2.6014(11) . ? In3 Se13 2.6233(10) 8_645 ? In4 Se1 2.6054(10) . ? In4 Se2 2.6073(11) . ? In4 Se5 2.6340(10) 6_664 ? In4 Se10 2.6210(10) . ? In5 Se2 2.6037(10) . ? In5 Se3 2.6333(9) . ? In5 Se7 2.6380(11) 6_664 ? In5 Se12 2.5896(10) 8_655 ? loop_ _twin_individual_id _twin_individual_mass_fraction_refined 1 0.962(7) 2 0.038(7)