Crystallography Open Database

Information card for entry 1577417

Preview

Coordinates	1577417.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C17 H20 F2 O Si
Calculated formula	C17 H20 F2 O Si
Title of publication	Rhodium-Catalyzed Enantioselective Intermolecular C–H Silylation of Simple Arenes: Synergistic Substituent Effects Overcome Silane Redistribution to Enable Synthesis of Si-Stereogenic Arylsilanes
Authors of publication	Liu, Lichuan; Chen, Xingliang; Guan, Guiyu; Su, Xinyue; Liu, Mengqing; Hu, Yuefei; He, Wei; Zhang, Linxing; Ma, Wenpeng; An, Kun
Journal of publication	Chemical Science
Year of publication	2026
a	9.5297 ± 0.0002 Å
b	8.1356 ± 0.0002 Å
c	11.0854 ± 0.0003 Å
α	90°
β	108.274 ± 0.002°
γ	90°
Cell volume	816.11 ± 0.04 Å³
Cell temperature	180 ± 0.1 K
Ambient diffraction temperature	180 ± 0.1 K
Number of distinct elements	5
Space group number	4
Hermann-Mauguin space group symbol	P 1 21 1
Hall space group symbol	P 2yb
Residual factor for all reflections	0.0319
Residual factor for significantly intense reflections	0.0289
Weighted residual factors for significantly intense reflections	0.0784
Weighted residual factors for all reflections included in the refinement	0.0859
Goodness-of-fit parameter for all reflections included in the refinement	1.073
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
306593 (current)	2026-06-18	cif/ Adding structures of 1577417, 1577418 via cif-deposit CGI script.	1577417.cif