Crystallography Open Database

Information card for entry 1577418

Preview

Coordinates	1577418.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C16 H18 F2 O Si
Calculated formula	C16 H18 F2 O Si
Title of publication	Rhodium-Catalyzed Enantioselective Intermolecular C–H Silylation of Simple Arenes: Synergistic Substituent Effects Overcome Silane Redistribution to Enable Synthesis of Si-Stereogenic Arylsilanes
Authors of publication	Liu, Lichuan; Chen, Xingliang; Guan, Guiyu; Su, Xinyue; Liu, Mengqing; Hu, Yuefei; He, Wei; Zhang, Linxing; Ma, Wenpeng; An, Kun
Journal of publication	Chemical Science
Year of publication	2026
a	7.212 ± 0.0001 Å
b	9.4888 ± 0.0001 Å
c	22.3464 ± 0.0002 Å
α	90°
β	90°
γ	90°
Cell volume	1529.24 ± 0.03 Å³
Cell temperature	180 ± 0.1 K
Ambient diffraction temperature	180 ± 0.1 K
Number of distinct elements	5
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0246
Residual factor for significantly intense reflections	0.0225
Weighted residual factors for significantly intense reflections	0.0617
Weighted residual factors for all reflections included in the refinement	0.0625
Goodness-of-fit parameter for all reflections included in the refinement	1.051
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
306593 (current)	2026-06-18	cif/ Adding structures of 1577417, 1577418 via cif-deposit CGI script.	1577418.cif